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The shape of a polymer plays an important role in determining its interactions with other molecules and with the environment, and is in turn affected by both of them. As a consequence, in the literature the shape properties of a chain in…

Soft Condensed Matter · Physics 2017-07-26 Alberto S. Sassi , Salvatore Assenza , Paolo De Los Rios

A toy model of particles packings is presented, which consists in arranging hexagons on a triangular lattice according to local stability rules. The number of stable packings is analytically computed and found to grow exponentially with the…

Statistical Mechanics · Physics 2015-06-25 R. Monasson , O. Pouliquen

Two-dimensional monodisperse linear polymer chains are known to adopt for sufficiently large chain lengths $N$ and surface fractions $\phi$ compact configurations with fractal perimeters. We show here by means of Monte Carlo simulations of…

Soft Condensed Matter · Physics 2025-08-04 J. P. Wittmer , A. Cavallo , A. Johner

We consider the flow-driven translocation of single polymer chains through nanochannels. Using analytical calculations based on the de Gennes blob model and mesoscopic numerical simulations, we estimate the threshold flux for the…

Soft Condensed Matter · Physics 2011-10-26 Rodrigo Ledesma-Aguilar , Takahiro Sakaue , Julia M. Yeomans

The properties of a particle diffusing on a one-dimensional lattice where at each site a random barrier and a random trap act simultaneously on the particle are investigated by numerical and analytical techniques. The combined effect of…

Condensed Matter · Physics 2009-10-28 Achille Giacometti , K. P. N. Murthy

A model of two interacting polymer chains has been proposed to study the effect of penetration of one chain in to the other. We show that small chain penetrates more in comparison to the long chain. We also find a condition in which both…

Statistical Mechanics · Physics 2009-10-31 Sanjay Kumar

Linear polymers are represented as chains of hopping reptons and their motion is described as a stochastic process on a lattice. This admittedly crude approximation still catches essential physics of polymer motion, i.e. the universal…

Statistical Mechanics · Physics 2015-05-18 J. M. J. van Leeuwen , Andrzej Drzewinski

We study the influence of some quenched disorder in the sequence of monomers on the entropic elasticity of long polymeric chains. Starting from the Kratky-Porod model, we show numerically that some randomness in the favoured angles between…

Statistical Mechanics · Physics 2009-10-30 D. Bensimon , D. Dohmi , M. Mezard

We write exact equations for the thermodynamic properties of a linear polymer molecule confined to walk on a lattice of finite size. The dimension of the space in which the lattice resides can be arbitrary. We also calculate polymer…

General Physics · Physics 2011-10-04 Esdmund A. Di Marzio , Charles M. Guttman

A lattice model of the directed self-avoiding walk is used to estimate the possibility on the formation of an infinitely long linear semi-flexible copolymer chain. The copolymer chain is assumed to composed of four different types of the…

Statistical Mechanics · Physics 2021-04-28 Pramod Kumar Mishra

The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. Here we investigate the dynamics…

Soft Condensed Matter · Physics 2013-05-29 J. M. Deutsch

The effect of network chain distribution on the mechanical behavior of elastomers is one of the long-standing problems in rubber mechanics. The classical theory of rubber elasticity is built upon the assumption of entropic elasticity of…

Soft Condensed Matter · Physics 2017-10-24 Mohammad Tehrani

We study a model of "elastic" lattice polymer in which a fixed number of monomers $m$ is hosted by a self-avoiding walk with fluctuating length $l$. We show that the stored length density $\rho_m = 1 - <l>/m$ scales asymptotically for large…

Statistical Mechanics · Physics 2010-06-16 Marco Baiesi , Gerard T. Barkema , Enrico Carlon

We study the problem of adsorption and collapse transition of a linear polymer chain situated in a fractal container represented by a 4-simplex lattice and interacting with a surface adsorbed linear polymer chain. The adsorbed chain…

Statistical Mechanics · Physics 2009-10-31 Sanjay Kumar , Yashwant Singh

In this paper, we employ Molecular Dynamics computer simulations to study and compare the statics and dynamics of linear and circular (ring) polymer chains in entangled solutions of different densities. While we confirm that linear chain…

Soft Condensed Matter · Physics 2016-02-17 Negar Nahali , Angelo Rosa

Herein, we describe new methods to produce colloidal particle chains of three stiffness regimes that can be observed on a single-particle level, that is, on the level of the monomers that make up the chain; the chains can even be observed…

Lattice model of directed self avoiding walk is used to investigate adsorption properties of a semiflexible sequential copolymer chain on an impenetrable curved surface on a hexagonal lattice in two dimensions. Walks of the copolymer chains…

Statistical Mechanics · Physics 2010-06-02 Pramod Kumar Mishra

We consider the lattice model for an ideal-linear polymer chain to mimic the conformations of the semi-flexible homo-polymer chain. The polymer chain is assumed to confine in the fairly small area, such that the flexible chain conformations…

Soft Condensed Matter · Physics 2020-10-23 Pramod Kumar Mishra

We present here the systematic development of quantitative lattice simulations of dense polymers through a novel computational technique that allows for an efficient accounting of the chain conformations. Our approach is based on the…

Soft Condensed Matter · Physics 2008-05-06 Jaydeep A. Kulkarni , Joydeep Mukherjee , Ryan C. Snyder , Timothy W. King , Antony N. Beris

Taking into account the nonequivalence of fixed-force and fixed-length ensembles in the weak-force regime, equations of state are derived that describe the equilibrium extension or compression of an ideal Gaussian polymer chain in response…

Soft Condensed Matter · Physics 2007-05-23 Richard M. Neumann