Related papers: Kovacs Effect in a Fragile Glass Model
We investigate the memory effect in a simple model for glassy relaxation, a trap model with a Gaussian density of states. In this model thermal equilibrium is reached at all finite temperatures and therefore we can consider jumps from low…
The dynamic behaviour of glassy materials displays strong nonequilibrium effects, such as ageing in simple protocols, memory, rejuvenation and Kovacs effects in more elaborated experiments. We show that this phenomenology may be easily…
We analyse the emergence of Kovacs-like memory effects in athermal systems within the linear response regime. This is done by starting from both the master equation for the probability distribution and the equations for the physically…
Dynamical properties of a Vicsek-like gas of self-propelled particles are investigated by means of kinetic theory and agent based simulations. While memory effects have been observed in disordered systems, we show that they also occur in…
We study the viscoelastic response of amorphous polymers using theory and simulations. By accounting for internal stresses and considering instantaneous normal modes (INMs) within athermal non-affine theory, we make parameter-free…
The standard model of glasses is an ensemble of two-level systems interacting with a thermal bath. The general origin of memory effects in this model is a quasi-stationary but non-equilibrium state of a single two-level system, which is…
Soft matter materials and polymers are widely used in the controlled delivery of drugs. Simulation and modeling provide insight at the atomic scale enabling a level of control unavailable to experiments. We present a workflow protocol for…
We propose a novel computational strategy to study the glass transition of molecular fluids. Our approach combines the construction of simple yet realistic models with the development of Monte Carlo algorithms to accelerate equilibration…
Temperature Modulated calorimetry is widely used but still raises some fundamental questions. In this paper we study a model system as a test sample to address some of them. The model has a nontrivial spectrum of relaxation times. We…
Glass-forming liquids have been extensively studied in recent decades, but there is still no theory that fully describes these systems, and the diversity of treatments is in itself a barrier to understanding. Here we introduce a new simple…
The understanding of thermodynamic glass transition has been hindered by the lack of proper models beyond mean-field theories. Here, we propose a three-dimensional lattice glass model on a simple cubic lattice that exhibits the typical…
The cage effect is widely accepted as the basic microscopic mechanism underlying the physics of supercooled liquids in contrast with usual liquids which are governed by molecular interactions only. In this work we implement a new toy model…
Effects of temperature changes on the nonequilibrium spin-glass dynamics of a strongly interacting ferromagnetic nanoparticle system (superspin glass) are studied. In contrary to atomic spin glasses, strong cooling rate effects are…
We evidence a Kovacs-like memory effect in a uniformly driven granular gas. A system of inelastic hard particles, in the low density limit, can reach a non-equilibrium steady state when properly forced. By following a certain protocol for…
Despite extensive research, the fundamental physical mechanisms underlying the Mpemba effect, a phenomenon where a substance cools faster after initially being heated, remain elusive. Although historically linked with water, the Mpemba…
The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…
We analyze a simple dynamical model of glasses, based on the idea that each particle is trapped in a local potential well, which itself evolves due to hopping of neighbouring particles. The glass transition is signalled by the fact that the…
A new approach is theoretically proposed to study the glass transition of active pharmaceutical ingredients and a glass-forming anisotropic molecular liquid at high pressures. We describe amorphous materials as a fluid of hard spheres.…
Glassy, nonexponential relaxations in globular proteins are typically attributed to conformational behaviors that are missing from intrinsically disordered proteins. Yet, we show that single molecules of a disordered-protein construct…
We review the use of kinetically constrained models (KCMs) for the study of dynamics in glassy systems. The characteristic feature of KCMs is that they have trivial, often non-interacting, equilibrium behaviour but interesting slow dynamics…