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We compute the thermodynamic phase diagram of seventeen elemental metals with hexagonal close-packed (hcp), face-centered cubic (fcc), and body-centered cubic (bcc) crystal structures using finite-temperature density functional theory.…

Materials Science · Physics 2026-04-15 S. Azadi , S. M. Vinko , A. Principi , T. D. Kuehne , M. S. Bahramy

Two novel three-dimensional (3D) crystal structures of carbon (C) and germanium carbide (GeC2) were predicted using first-principles density-functional theory (DFT) calculations. These newly discovered 3D carbon allotrope and GeC2 are in…

Materials Science · Physics 2020-12-15 Ying Yang , Guang Yang , Xihong Peng

The energy differences between the face-centered cubic (FCC) and hexagonal closed packed (HCP) structures of the argon (Ar) crystal are studied using the first-principles electronic-structure approach at the level of random phase…

Materials Science · Physics 2022-04-13 Sixian Yang , Xinguo Ren

We study the phase ordering colloids suspended in a thermotropic nematic liquid crystal below the clearing point Tni and the resulting aggregated structure. Small (150nm) PMMA particles are dispersed in a classical liquid crystal matrix,…

Soft Condensed Matter · Physics 2007-05-23 V. J. Anderson , E. M. Terentjev , S. P. Meeker , J. Crain , W. C. K. Poon

We follow the structural transformation in solid C$_{70}$ from the high temperature hcp to a low temperature monoclinic phase using x-ray diffraction studies at controlled cooling-rates from 0.0033 to 0.42 K/min. Rapid cooling of the sample…

Materials Science · Physics 2009-10-31 G. Ghosh , V. S. Sastry , C. S. Sundar , Surajit Sengupta , T. S. Radhakrishnan

Classical hard spheres crystallize at equilibrium at high enough density. Crystals made up of stackings of 2-dimensional hexagonal close-packed layers (e.g. fcc, hcp, etc.) differ in entropy by only about $10^{-3}k_B$ per sphere (all…

Statistical Mechanics · Physics 2009-10-31 Siun-Chuon Mau , David A. Huse

Atomic structures of Al-Co-Cu decagonal quasicrystals (QCs) are investigated using empirical oscillating pair potentials (EOPP) in molecular dynamic (MD) simulations that we enhance by Monte Carlo (MC) swapping of chemical species and…

Materials Science · Physics 2024-04-23 Y. Huang , M. Widom , M. Mihalkovič

We report a molecular dynamics simulation demonstrating that a columnar liquid crystal, commonly formed by disc-shaped molecules, can be formed by identical particles interacting via a spherically symmetric potential. Upon isochoric cooling…

Soft Condensed Matter · Physics 2015-03-20 Alfredo Metere , Tomas Oppelstrup , Sten Sarman , Mikhail Dzugutov

The ground state of a two-dimensional, harmonically confined mesoscopic assembly of up to thirty polar molecules is studied by computer simulations. As the strength of the confining trap is increased, clusters evolve from superfluid, to…

Mesoscale and Nanoscale Physics · Physics 2013-06-07 Massimo Boninsegni

The electronic band structure and elastic properties of the Cd${}_{16}$Se${}_{15}$Te solid state solution in the framework of the density functional theory calculations are investigated. The structure of the sample is constructed on the…

Materials Science · Physics 2021-06-28 A. I. Kashuba , B. Andriyevsky , H. A. Ilchuk , R. Yu. Petrus , T. S. Malyi , I. V. Semkiv

The structural, electronic and magnetic properties of single layers of Iron Dichloride (FeCl$_{2}$) were calculated using first principles calculations. We found that the 1T phase of the single layer FeCl$_{2}$ is 0.17 eV/unit cell more…

Materials Science · Physics 2015-07-31 E. Torun , H. Sahin , S. K. Singh , F. M. Peeters

Solid CS$_{2}$ is superficially similar to CO$_{2}$, with the same $Cmca$ molecular crystal structure at low pressures, which has suggested similar phases also at high pressures. We carried out an extensive first principles evolutionary…

Materials Science · Physics 2015-06-23 S. Shahab Naghavi , Yanier Crespo , Roman Martonak , Erio Tosatti

We report simulations on the homogeneous liquid-fcc nucleation of charged colloids for both low and high contact energy values. As a precursor for crystal formation, we observe increased local order at the position where the crystal will…

Soft Condensed Matter · Physics 2014-11-03 Kai Kratzer , Axel Arnold

The phase diagram of colloidal hard superballs, of which the shape interpolates between cubes and octahedra via spheres, is determined by free-energy calculations in Monte Carlo simulations. We discover not only a stable face-centered cubic…

Soft Condensed Matter · Physics 2012-08-21 Ran Ni , Anjan Prasad Gantapara , Joost de Graaf , René van Roij , Marjolein Dijkstra

Stable or metastable crystal structures of assembled atoms can be predicted by finding the global or local minima of the energy surface within a broad space of atomic configurations. Generally, this requires repeated first-principles energy…

We present results predicting experimentally measurable structural quantities from molecular dynamics studies of hydrogen. In doing this, we propose a paradigm shift for experimentalists -- that the predictions from such calculations should…

Materials Science · Physics 2020-03-25 Graeme J. Ackland , John S. Loveday

The solid diffusive phase transformation involving the nucleation and growth of one nucleus is universal and frequently employed but has not yet been fully understood at the atomic level. Here, our first-principles calculations reveal a…

Materials Science · Physics 2023-09-12 Junyuan Bai , Hongbo Xie , Xueyong Pang , Min Jiang , Gaowu Qin

Monolayer fullerene (C$_{60}$) networks combine molecular-level rigidity with crystalline connectivity, offering a promising platform for numerous applications. In this Feature article, we review the physical and chemical properties of…

Materials Science · Physics 2025-09-01 Bo Peng , Michele Pizzochero

Well-ordered organic molecular layers on oxide surfaces are key for organic electronics. Using a combination of scanning tunneling microscopy (STM) and non-contact atomic force microscopy (nc-AFM) we probe the structures of copper…

Molecular clouds (MCs) are highly structured and ``turbulent''. Colliding gas streams of atomic hydrogen have been suggested as a possible source of MCs, imprinting the filamentary structure as a consequence of dynamical and thermal…

Astrophysics · Physics 2009-11-13 F. Heitsch , A. Burkert , L. Hartmann , A. D. Slyz , J. E. G. Devriendt