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The cost of the exact solution of the many-electron problem is believed to be exponential in the number of degrees of freedom, necessitating approximations that are controlled and accurate but numerically tractable. In this paper, we show…

Strongly Correlated Electrons · Physics 2017-03-02 Dominika Zgid , Emanuel Gull

An enhanced static approximation for the electron self energy operator is proposed for efficient calculation of quasiparticle energies. Analysis of the static COHSEX approximation originally proposed by Hedin shows that most of the error…

Materials Science · Physics 2010-11-18 Wei Kang , Mark S. Hybertsen

We solve the Dyson equation for atoms and diatomic molecules within the GW approximation, in order to elucidate the effects of self-consistency on the total energies and ionization potentials. We find GW to produce accurate energy…

Materials Science · Physics 2015-03-30 Adrian Stan , Nils Erik Dahlen , Robert van Leeuwen

We present an approach to solid-state electronic-structure calculations based on the finite-element method. In this method, the basis functions are strictly local, piecewise polynomials. Because the basis is composed of polynomials, the…

Condensed Matter · Physics 2009-10-31 J. E. Pask , B. M. Klein , C. Y. Fong , P. A. Sterne

We present a method for calculating the kinetic energy of localised functions represented on a regular real space grid. This method uses fast Fourier transforms applied to restricted regions commensurate with the simulation cell and is…

Materials Science · Physics 2009-11-07 Chris-Kriton Skylaris , Arash A. Mostofi , Peter D. Haynes , Chris J. Pickard , Mike C. Payne

We present a simple implementation of the dynamical mean-field theory approach to the electronic structure of strongly correlated materials. This implementation achieves full self-consistency over the charge density, taking into account…

Strongly Correlated Electrons · Physics 2009-11-13 L. V. Pourovskii , B. Amadon , S. Biermann , A. Georges

We report extensive self-consistent calculations of jellium surface energies, by going beyond the local-density approximation. The density-response function of a bounded free-electron gas is evaluated within the random-phase approximation,…

Materials Science · Physics 2009-10-31 J. M. Pitarke , A. G. Eguiluz

Self-energy-functional theory is a formal framework which allows to derive non-perturbative and thermodynamically consistent approximations for lattice models of strongly correlated electrons from a general dynamical variational principle.…

Strongly Correlated Electrons · Physics 2011-12-08 Michael Potthoff

We present results on the self-energy correction to the energy levels of hydrogen and hydrogenlike ions. The self energy represents the largest QED correction to the relativistic (Dirac-Coulomb) energy of a bound electron. We focus on the…

An exchange-correlation energy functional beyond the local density approximation, based on the exchange-correlation kernel of the homogeneous electron gas and originally introduced by Kohn and Sham, is considered for electronic structure…

Condensed Matter · Physics 2016-08-31 Maurizia Palummo , Giovanni Onida , Rodolfo Del Sole

We present a theory of local electric polarization in crystalline solids and apply it to study the case of wurtzite group-III nitrides. We show that a local value of the electric polarization, evaluated at the atomic sites, can be cast in…

Materials Science · Physics 2013-12-06 Miguel A. Caro , Stefan Schulz , Eoin P. O'Reilly

An alternative to Density Functional Theory are wavefunction based electronic structure calculations for solids. In order to perform them the Exponential Wall (EW) problem has to be resolved. It is caused by an exponential increase of the…

Chemical Physics · Physics 2017-06-07 Peter Fulde , Hermann Stoll

We revisit the three-body problem in quantum mechanics in two and three dimensions, generating both exact eigenvalues and eigenvectors of the Hamiltonian and a series of approximate solutions as calculated with a variety of different…

The quantum properties of localized finite energy solutions to classical Euler-Lagrange equations are investigated using the method of collective coordinates. The perturbation theory in terms of inverse powers of the coupling constant $g$…

High Energy Physics - Theory · Physics 2008-11-26 A. V. Shurgaia , H. J. W. Mueller-Kirsten

We propose a hybrid approach which employs the dynamical mean-field theory (DMFT) self-energy for the correlated, typically rather localized orbitals and a conventional density functional theory (DFT) exchange-correlation potential for the…

Strongly Correlated Electrons · Physics 2021-06-16 Sumanta Bhandary , Karsten Held

Over the years, Hedin's $GW$ self-energy has been proven to be a rather accurate and simple approximation to evaluate electronic quasiparticle energies in solids and in molecules. Attempts to improve over the simple $GW$ approximation, the…

Computational Physics · Physics 2024-01-24 Fabien Bruneval , Arno Förster

Calculations of electronic and optical properties of solids at finite temperature including electron-phonon interactions and quantum zero-point renormalization have enjoyed considerable progress during the past few years. Among the emerging…

Materials Science · Physics 2020-04-01 Marios Zacharias , Feliciano Giustino

This paper generalizes the earlier work on the energy-based discontinuous Galerkin method for second-order wave equations to fourth-order semilinear wave equations. We first rewrite the problem into a system with a second-order spatial…

Numerical Analysis · Mathematics 2022-07-25 Lu Zhang

The Hubbard model is implemented in real-space Green's function calculations of x-ray spectra using an effective self-energy adapted from the LSDA+U method of Anisimov et al. This self-energy consists of an energy-dependent many-pole…

Strongly Correlated Electrons · Physics 2011-07-12 Towfiq Ahmed , J. J. Kas , J. J. Rehr

Supercell models are often used to calculate the electronic structure of local perturbations from the ideal periodicity in the bulk or on the surface of a crystal or in wires. When the defect or adsorbent is charged, a jellium counter…