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We derive a general form of eigenvalue self-consistency for $GW_{0}$ in the time domain and use it to obtain a simplified postprocessing eigenvalue self-consistency, which we label $\bar{\Delta}GW_{0}$. The method costs the same as a…

Chemical Physics · Physics 2018-11-14 Vojtěch Vlček , Roi Baer , Eran Rabani , Daniel Neuhauser

Self-energy corrections to the energy levels of bound electrons are calculated in the framework of path integrals. We arrive at the full fermion propagator, using methods of functional integrals, in the form of Schwinger-Dyson equation…

Atomic Physics · Physics 2023-09-28 Sreya Banerjee , Zoltán Harman

A self-consistent calculation scheme for correlated electron systems is created based on the density-functional theory (DFT). Our scheme is a multi-reference DFT (MR-DFT) calculation in which the electron charge density is reproduced by an…

Strongly Correlated Electrons · Physics 2009-11-13 Koichi Kusakabe , Naoshi Suzuki , Shusuke Yamanaka , Kizashi Yamaguchi

Density functional theory has become the workhorse of quantum physics, chemistry, and materials science. Within these fields, a broad range of applications needs to be covered. These applications range from solids to molecular systems, from…

Chemical Physics · Physics 2025-01-20 Christof Holzer , Yannick J. Franzke

We present an efficient and accurate method for calculating electronic structure and related properties of random alloys with a proper treatment of local environment effects. The method is a generalization of the locally self-consistent…

Materials Science · Physics 2012-05-15 Oleg E. Peil , Andrei V. Ruban , Börje Johansson

We present an exact calculation of the single-electron energies and wave-functions for any bound state in a realistic Si-SiO2 spherical quantum dot, including the material dependence of the electron effective mass. The influence of dot…

Materials Science · Physics 2007-05-23 Nguyen Hong Quang , Tran The Trung , Johann See , Philippe Dollfus

We present an implementation of the $GW$ space-time approach that allows cubic-scaling all-electron calculations with standard Gaussian basis sets without exploiting any localization nor sparsity considerations. The independent-electron…

Computational Physics · Physics 2021-04-29 Ivan Duchemin , Xavier Blase

We present a set of efficient techniques in first-principles electronic-structure calculations utilizing the real-space finite-difference method. These techniques greatly reduce the overhead for performing integrals that involve…

Materials Science · Physics 2009-11-10 Tomoya Ono , Kikuji Hirose

Two self-consistent schemes involving Hedin's $GW$ approximation are studied for a set of sixteen different atoms and small molecules. We compare results from the fully self-consistent $GW$ approximation (SC$GW$) and the quasi-particle…

Materials Science · Physics 2015-06-19 Peter Koval , Dietrich Foerster , Daniel Sánchez-Portal

State-specific approximations can provide an accurate representation of challenging electronic excitations by enabling relaxation of the electron density. While state-specific wave functions are known to be local minima or saddle points of…

Chemical Physics · Physics 2022-01-06 Hugh G. A. Burton

We present the method of the self-consistent calculation of thermodynamical and correlation functions. This approach is based on the GRPA (generalized random phase approximation) scheme with the inclusion of the mean field corrections.…

Statistical Mechanics · Physics 2016-08-31 I. V. Stasyuk , A. M. Shvaika , K. V. Tabunshchyk

We propose a new method for calculating total energies of systems of interacting electrons, which requires little more computational resources than standard density-functional theories. The total energy is calculated within the framework of…

Condensed Matter · Physics 2009-10-31 Paula Sanchez-Friera , R. W. Godby

The electronic structures of several actinide solid systems are calculated using the self-interaction corrected local spin density approximation. Within this scheme the $5f$ electron manifold is considered to consist of both localized and…

Strongly Correlated Electrons · Physics 2007-05-23 L. Petit , A. Svane , Z. Szotek , W. M. Temmerman

A new iterative solver is proposed to efficiently calculate the ground state electronic structure in Density Functional Theory calculations. This algorithm is particularly useful for simulating physical systems considered difficult to…

Computational Physics · Physics 2021-11-24 Jean-Luc Fattebert

A novel low complexity method to perform self-consistent electronic-structure calculations using the Kohn-Sham formalism of density functional theory is presented. Localization constraints are neither imposed nor required thereby allowing…

Computational Physics · Physics 2007-05-23 M. J. Rayson

We present a method to calculate the electronic charge density of periodic solids in the GW approximation, using the space-time method. We investigate for the examples of silicon and germanium to what extent the GW approximation is…

Condensed Matter · Physics 2009-10-31 Martin M. Rieger , R. W. Godby

The family of Green's function methods based on the $GW$ approximation has gained popularity in the electronic structure theory thanks to its accuracy in weakly correlated systems combined with its cost-effectiveness. Despite this,…

Chemical Physics · Physics 2023-08-31 Antoine Marie , Pierre-François Loos

In this paper, we propose an efficient implementation of combining Dynamical Mean field theory (DMFT) with electronic structure calculation based on the local density approximation (LDA). The pseudo-potential-plane-wave method is used in…

Strongly Correlated Electrons · Physics 2015-06-03 Jian-Zhou Zhao , Jia-Ning Zhuang , Xiao-Yu Deng , Yan Bi , Ling-Cang Cai , Zhong Fang , Xi Dai

We present two new developments for computing excited state energies within the $GW$ approximation. First, calculations of the Green's function and the screened Coulomb interaction are decomposed into two parts: one is deterministic while…

Computational Physics · Physics 2020-10-28 Mariya Romanova , Vojtěch Vlček

We propose accurate computable error bounds for quantities of interest in plane-wave electronic structure calculations, in particular ground-state density matrices and energies, and interatomic forces. These bounds are based on an…

Numerical Analysis · Mathematics 2022-10-20 Eric Cancès , Geneviève Dusson , Gaspard Kemlin , Antoine Levitt
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