Related papers: Negative heat capacity at phase-separation in macr…
The energetics of the stochastic process has shown the balance of energy on the mesoscopic level. The heat and the energy defined there are, however, generally different from their macroscopic counterpart. We show that this discrepancy can…
We study first-order phase transitions in a two-temperature system, where due to the time-scale separation all the basic thermodynamical quantities (free energy, entropy, etc) are well-defined. The sign of the latent heat is found to be…
The negative nature of the heat capacity $C_V$ of thermodynamically isolated self-gravitating systems is rediscussed in the framework of a non-extensive kinetic theory. It is found that the dependence of $C_V$ on the non-extensive parameter…
Thermodynamics dictates that the specific heat of a system is strictly non-negative. However, in finite classical systems there are well known theoretical and experimental cases where this rule is violated, in particular finite atomic…
Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…
Equilibrium statistics of finite Hamiltonian systems is fundamentally described by the microcanonical ensemble (ME). Canonical, or grand-canonical partition functions are deduced from this by Laplace transform. Only in the thermodynamic…
We consider a soluble model of multifragmentation which is similar in spirit to many models which have been used to fit intermediate energy heavy ion collision data. In this model $c_v$ is always positive but for finite nuclei $c_p$ can be…
The present work extends the well-known thermodynamic relation $C=\beta ^{2}< \delta {E^{2}}>$ for the canonical ensemble. We start from the general situation of the thermodynamic equilibrium between a large but finite system of interest…
Anomalous negative heat capacities have been claimed as indicators of first order phase transitions in finite systems in general, and fornuclear systems in particular. A thermodynamic approach allowing for all Q value terms is used to…
Phase transitions of first and second order can easily be distinguished in small systems in the microcanonical ensemble. Configurations of phase coexistence, which are suppressed in the canonical formulation, carry important information…
The microcanonical entropy $S=\ln[W(E)]$ is the {\em geometrical measure} of the microscopic redundancy or ignorance about the N-body system. {\em Even for astronomical large systems} is the microcanonical entropy everywhere {\em single…
An experimental indication of negative heat capacity in excited nuclear systems is inferred from the event by event study of energy fluctuations in $Au$ quasi-projectile sources formed in $Au+Au$ collisions at 35 A.MeV. The excited source…
According to thermodynamics, the specific heat of Boltzmannian short-range interacting systems is a positive quantity. Less intuitive properties are instead displayed by systems characterized by long-range interactions. In that case, the…
Recent theoretical studies of statistical mechanical properties of systems with long range interactions are briefly reviewed. In these systems the interaction potential decays with a rate slower than 1/r^d at large distances r in d…
Steady nonequilibria dissipate energy and, when changing external parameters, an extra or excess heat accompanies the relaxation to the new nonequilibrium condition. For nonequilibrium systems in contact with a thermal bath, the heat…
We show that the vacuum (zero-point) energy of a low-temperature quantum liquid is a variable property which changes with the state of the system, in notable contrast to the static vacuum energy in solids commonly considered. We further…
The microcanonical properties of a two dimensional system of N classical particles interacting via a smoothed Newtonian potential as a function of the total energy E and the total angular momentum L are discussed. In order to estimate…
We demonstrate that the presence of entanglement in macroscopic bodies (e.g. solids) in thermodynamical equilibrium could be revealed by measuring heat-capacity. The idea is that if the system were in a separable state, then for certain…
The microcanonical ensemble is in important physical situations different from the canonical one even in the thermodynamic limit. In contrast to the canonical ensemble it does not suppress spatially inhomogeneous configurations like phase…
The validity of the Second Law of thermodynamics, indisputable in the macroscopic world, is challenged at the mesoscopic level: a mesoscopic isolated system, possessing spatial dimensions of the order of a few microns, is capable, as shown…