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Theory is presented for the phase stability of mixtures containing nanospheres and non-adsorbing reversible supramolecular polymers. This was made possible by incorporating the depletion thickness and osmotic pressure of reversible…

Soft Condensed Matter · Physics 2011-06-09 Remco Tuinier

Although there are theoretical predictions [\textit{Eur.~Phys.~J.~E} \textbf{41} (2018) 110] for the rich phase behaviour of colloidal cubes mixed with non-adsorbing polymers, a thorough verification of this phase behaviour is still…

Soft Condensed Matter · Physics 2020-06-04 Frans Dekker , Alvaro Gonzalez Garcia , Albert P. Philipse , Remco Tuinier

Crystallization within the discrete spheres of a block copolymer mesophase was studied by time-resolved x-ray scattering. The cubic packing of microdomains, established by self-assembly in the melt, is preserved throughout crystallization…

Soft Condensed Matter · Physics 2009-10-31 Yueh-Lin Loo , Richard A. Register , Anthony J. Ryan

The polymer systems are discussed in the framework of the Landau-Ginzburg model. The model is derived from the mesoscopic Edwards hamiltonian via the conditional partition function. We discuss flexible, semiflexible and rigid polymers. The…

Condensed Matter · Physics 2007-05-23 Robert Holyst , T. A. Vilgis

I report the results of a series of works on the phase diagram of theories with a different number of colors and/or quarks in a different representation than in QCD. Similarities as well as differences as compared to the real world are…

High Energy Physics - Phenomenology · Physics 2011-06-15 Tomas Brauner

Self-consistent field theory (SCFT) and strong segregation theory (SST) are used to explore the parameter space governing the self-assembly of cylinder forming block copolymers (BCPs) on a modulated substrate. The stability of in-plane…

Materials Science · Physics 2018-11-16 Karim Gadelrab , Alfredo Alexander-Katz

We predict a diblock copolymer melt in the lamellar phase with added spherical nanoparticles that have an affinity for one block to have a lower tensile modulus than a pure diblock copolymer system. This weakening is due to the swelling of…

Materials Science · Physics 2007-05-23 R. B. Thompson , K. O. Rasmussen , T. Lookman

In this work, we investigate how the assumption of chemical equilibrium with leptons affects the deconfinement phase transition to quark matter. This is done within the framework of the Chiral Mean Field model (CMF) allowing for non-zero…

Confinement can have a dramatic effect on the behavior of all sorts of particulate systems and it therefore is an important phenomenon in many different areas of physics and technology. Here, we investigate the role played by the softness…

We discuss in this paper the phase diagram of a diblock polyampholyte solution in the limit of high ionic strength as a function of concentration and charge asymmetry. This system is shown to be very similar to solutions of so-called…

Soft Condensed Matter · Physics 2009-11-07 Martin Castelnovo , J. F. Joanny

The superfluid phase diagrams of a two-dimensional cold polarized Fermi gas in the BCS-BEC crossover are systematically and analytically investigated. In the BCS-Leggett mean field theory, the transition from unpolarized superfluid phase to…

Superconductivity · Physics 2016-09-08 Lianyi He , Pengfei Zhuang

We study a d-dimensional lattice model of diffusing coalescing massive particles, with two parameters controlling deposition and evaporation of monomers. The unique stationary distribution for the system exhibits a phase transition in all…

Probability · Mathematics 2016-08-09 Colm Connaughton , R. Rajesh , Roger Tribe , Oleg Zaboronski

In frameworks of the phenomenological approach we analyze of the phase diagram of mixed compounds. We obtain space groups of symmetry of the real structures as result of phase transition from close-packed degenerate structure. The theory of…

Statistical Mechanics · Physics 2007-05-23 B. R. Gadjiev

A phenomenological mean-field theory is used to investigate the properties of solvent-diluted di-block copolymers (BCP), in which the two BCP components (A and B) form a variety of phases that are diluted by a solvent (S). Using this…

Soft Condensed Matter · Physics 2014-04-22 Shai Cohen , David Andelman

Block copolymer (BCP) melt assembly has been the subject of decades of study, with focus largely on self-organized spatial patterns of periodically-ordered segment density. In this study, we demonstrate that underlying these otherwise…

Soft Condensed Matter · Physics 2017-06-21 Ishan Prasad , Youngmi Seo , Lisa M. Hall , Gregory M. Grason

The structure of lamellar phases of symmetric $AB$ diblock copolymers in a thin film is investigated. We quantitatively compare the composition profiles and profiles of individual segments in self-consistent field calculations with Monte…

Statistical Mechanics · Physics 2009-10-31 Thorsten Geisinger , Marcus Mueller , Kurt Binder

We investigate two-dimensional (2d) melting in the presence of a one-dimensional (1d) periodic potential as, for example, realized in recent experiments on 2d colloids subjected to two interfering laser beams. The topology of the phase…

Soft Condensed Matter · Physics 2009-10-31 Leo Radzihovsky , Erwin Frey , David R. Nelson

In this work we investigated the phase behavior of melts of block-copolymers with one charged block by means of dissipative particle dynamics with explicit electrostatic interactions. We assumed that all the Flory-Huggins \c{hi} parameters…

Soft Condensed Matter · Physics 2019-06-12 Alexey A. Gavrilov , Alexander V. Chertovich , Igor I. Potemkin

Equilibration of polymer melts containing highly entangled long polymer chains in confinement or with free surfaces is a challenge for computer simulations. We approach this problem by first studying polymer melts based on the soft-sphere…

Soft Condensed Matter · Physics 2020-10-14 Hsiao-Ping Hsu , Kurt Kremer

Using self-consistent field and density-functional theories, we first investigate colloidal self-assembling of colloid/polymer films confined between two soft surfaces grafted by polymers. With the increase of colloidal concentrations, the…

Soft Condensed Matter · Physics 2007-05-23 Chun-lai Ren , Yu-qiang Ma
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