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Origins of elastic properties in ordered nanocomposites

Materials Science 2007-05-23 v1

Abstract

We predict a diblock copolymer melt in the lamellar phase with added spherical nanoparticles that have an affinity for one block to have a lower tensile modulus than a pure diblock copolymer system. This weakening is due to the swelling of the lamellar domain by nanoparticles and the displacement of polymer by elastically inert fillers. Despite the overall decrease in the tensile modulus of a polydomain sample, the shear modulus for a single domain increases dramatically.

Keywords

Cite

@article{arxiv.cond-mat/0402539,
  title  = {Origins of elastic properties in ordered nanocomposites},
  author = {R. B. Thompson and K. O. Rasmussen and T. Lookman},
  journal= {arXiv preprint arXiv:cond-mat/0402539},
  year   = {2007}
}