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The role of ionic interactions between sodium dodecyl sulfate, SDS, and sapphire surfaces have been studied using specular neutron reflection to determine the structure and composition of adsorbed surfactant layers. Increasing the pH of the…

Soft Condensed Matter · Physics 2012-05-02 Ningning Li , Robert K. Thomas , Adrian R. Rennie

Density functional theory has been employed to study graphene on the (111), (100) and (110) surfaces of silicon (Si) substrates. There are several interesting findings. First, carbon atoms in graphene form covalent bonds with Si atoms, when…

Materials Science · Physics 2021-07-14 Y. W. Sun , D. Holec , D. Gehringer , L. Li , O. Fenwick , D. J. Dunstan , C. J. Humphreys

The first principles density functional theory (DFT) calculations have been used to investigate the atomic and electronic properties of thiadiazole adsorption on the Si(001) surface. A (2x2) reconstructed clean substrate surface has been…

Materials Science · Physics 2018-05-07 Cagil Kaderoglu

We have studied diffusion pathways of a silyl radical adsorbed on the hydrogenated Si (100)-(2x1) surface by density-functional theory. The process is of interest for the growth of crystalline silicon by plasma-enhanced chemical vapor…

Materials Science · Physics 2008-03-31 Michele Ceriotti , Marco Bernasconi

The effect of oxygen adsorption on the local structure and electronic properties of monolayer graphene grown on SiC(0001) has been studied by means of Low Energy Electron Microscopy (LEEM), microprobe Low Energy Electron Diffraction…

Materials Science · Physics 2015-06-05 C. Mathieu , B. Lalmi , T. O. Mentes , E. Pallecchi , A. Locatelli , S. Latil , R. Belkhou , A. Ouerghi

Electron stimulated desorption of cyclopentene from the Si(100)-2x1 surface is studied experimentally with cryogenic UHV STM and theoretically with transport, electronic structure, and dynamical calculations. Unexpectedly for a saturated…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 N. L. Yoder , N. P. Guisinger , M. C. Hersam , R. Jorn , C. -C. Kaun , T. Seideman

A single-walled carbon nanotube presents a seamless cylindrical graphene surface and is thus an ideal adsorption substrate for investigating the physics of atoms and molecules in two dimensions and approaching the one-dimensional limit.…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Boris Dzyubenko , Hao-Chun Lee , Oscar E. Vilches , David H. Cobden

While the small sticking coefficient for molecular hydrogen on the Si(001) surface apparently requires a large energy barrier of adsorption, no such barrier is observed in desorption experiments. We have calculated the potential-energy…

mtrl-th · Physics 2009-10-28 E. Pehlke , M. Scheffler

The configuration of graphene (GE) sheet conforming to the spherical surface substrate is studied through theoretical model and molecular simulations. Two basic configurations are observed: fully conformation and wrinkling. The final…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Yanguang Zhou , Yuli Chen , Bin Liu , Zhenyu Yang , Ming Hu , Shengtao Wang , Zeshuai Yuan

We have performed ab initio electronic structure calculations of C and S adsorption on two vicinal surfaces of Pd with different terrace geometry and width. We find both adsorbates to induce a significant perturbation of the surface…

Materials Science · Physics 2009-11-11 Faisal Mehmood , Sergey Stolbov , Talat S. Rahman

Ab initio calculations within the density-functional theory formalism are performed to investigate the chemical functionalization of a graphene-like monolayer of silicon - silicene - with B, N, Al or P atoms. The structural, electronic,…

Materials Science · Physics 2014-09-05 Jozef Sivek , Hasan Şahin , Bart Partoens , François M. Peeters

We have performed an {\it ab initio} theoretical investigation of graphene sheet adsorbed on amorphous SiO$_2$ surface (G/a-SiO$_2$). We find that graphene adsorbs on the a-SiO$_2$ surface through van der Waals interactions. The…

Materials Science · Physics 2015-05-28 R. H. Miwa , T. M. Schmidt , A. Fazzio

We study ground states of a hybrid system consisting of a polymer and an attractive nanowire by means of computer simulations. Depending on structural and energetic properties of the substrate, we find different adsorbed polymer…

Soft Condensed Matter · Physics 2011-03-10 Thomas Vogel , Michael Bachmann

The interaction of the strong electron-acceptor tetracyanoethylene (TCNE) with the Cu(100) surface has been studied with scanning tunneling microscopy experiments and first-principles density functional theory calculations. We compare two…

Materials Science · Physics 2008-11-24 Stéphane Bedwani , Daniel Wegner , Michael F. Crommie , Alain Rochefort

The adsorption of hydrogen on the polar Zn-ended ZnO(0001) surface has been investigated by density functional {\it ab-initio} calculations. An on top H(1x1) ordered overlayer with genuine H-Zn chemical bonds is shown to be energetically…

Materials Science · Physics 2015-05-13 N. Sanchez , S. Gallego , J. Cerdá , M. C. Muñoz

We have studied the electronic properties, in relation to their structural properties, of monolayers of 1-octadecene attached on a hydrogen-terminated (111) silicon surface. The molecules are attached using the free-radical reaction between…

Materials Science · Physics 2009-11-10 Corinne Miramond , Dominique Vuillaume

Surface adsorption of C$_{60}$ affects its chemical and electronic properties. Numerous studies have reported observation of bright and dark fullerenes on metal surfaces that suggest extensive surface reconstruction, however, the…

Materials Science · Physics 2021-12-01 Leonardo Forcieri , Simon Taylor , Philip Moriarty , Samuel P Jarvis

The electromagnetic interaction between Ag nanoparticles on the top of the Si substrate and the incident light has been studied by numerical simulations. It is found that the presence of a dielectric layer with different thickness leads to…

Materials Science · Physics 2011-09-22 Xu Rui , Wang Xiao-Dong , Liu Wen , Xu Xiao-Na , Li Yue-Qiang , Ji An , Yang Fu-Hua , Li Jin-Min

Adsorption in nanoporous materials is one strategy that can be used to store hydrogen at conditions of temperature and pressure that are economically viable. Adsorption capacity of nanoporous materials depends on surface area which can be…

Materials Science · Physics 2024-05-28 Siddharth Gautam , David R. Cole , Zoltán Imre Dudás , Indu Dhiman

The geometric and electronic properties of Bi-adsorbed monolayer graphene, enriched by the strong effect of substrate, are investigated by first-principles calculations. The six-layered substrate, corrugated buffer layer, and slightly…

Materials Science · Physics 2016-08-24 S. Y. Lin , S. L. Chang , H. H. Chen , S. H. Su , J. C. A. Huang , M. -F. Lin