Related papers: Polymerization with Freezing
We investigate a system of interacting clusters evolving through mass exchange and supplemented by input of small clusters. Three possibilities depending on the rate of exchange generically occur when input is homogeneous: continuous…
We consider a random process on recursive trees, with three types of events. Vertices give birth at a constant rate (growth), each edge may be removed independently (fragmentation of the tree) and clusters (or trees) are frozen with a rate…
A diffusion-limited aggregation process, in which clusters coalesce by means of 3-particle reaction, A+A+A->A, is investigated. In one dimension we give a heuristic argument that predicts logarithmic corrections to the mean-field asymptotic…
We introduce and study a model of percolation with constant freezing (PCF) where edges open at constant rate 1, and clusters freeze at rate \alpha independently of their size. Our main result is that the infinite volume process can be…
Colloidal gels are widely applied in industry due to their rheological character -- no flow takes place below the yield stress. Such property enables gels to maintain uniform distribution in practical formulations; otherwise, solid…
We study aggregation-fragmentation processes in which pairs of clusters can aggregate, and each cluster can break into two fragments. If the rates of aggregation and fragmentation do not depend on the masses, detailed balance does not hold,…
Aggregation processes with an arbitrary number of conserved quantities are investigated. On the mean-field level, an exact solution for the size distribution is obtained. The asymptotic form of this solution exhibits nontrivial ``double''…
The nucleation and growth of clusters in a progressively cooled vapor is studied. The chemical-potential of the vapor increases, resulting in a rapidly increasing nucleation rate. The growth of the newly created clusters depletes monomers,…
We present large-scale molecular dynamics simulations to study the free evolution of granular gases. Initially, the density of particles is homogeneous and the velocity follows a Maxwell-Boltzmann (MB) distribution. The system cools down…
We consider one-dimensional systems of self-gravitating sticky particles with random initial data and describe the process of aggregation in terms of the largest cluster size L_n at any fixed time prior to the critical time. The asymptotic…
We propose a dynamical scheme for the combined processes of fragmentation and merging as a model system for cluster dynamics in nature and society displaying scale invariant properties. The clusters merge and fragment with rates…
We study the dynamics and structure of clusters in the inhomogeneous clustered regime of a freely cooling granular gas of point particles in one dimension. The coefficient of restitution is modeled as $r_0<1$ or 1 depending on whether the…
We use molecular dynamics simulations of a simple model to show that dispersions of slightly elongated colloidal particles with long-range dipolar interactions, like ferrofluids, can form a physical (reversible) gel at low volume fractions.…
We study the equilibrium behavior of one-dimensional granular clusters and one-particle granular gases for a variety of velocity dependent coefficients of restitution $r$. We obtain equations describing of the long time behavior for the…
We report event-driven molecular dynamics simulations of the irreversible gelation of hard ellipsoids of revolution containing several associating groups, characterizing how the cluster size distribution evolves as a function of the extent…
Aggregation of ice crystals is a key process governing precipitation. Individual ice crystals exhibit considerable diversity of shape, and a wide range of physical processes could influence their aggregation; despite this we show that a…
We present a kinetic model of crystal growth of polymers of finite molecular weight. Experiments help to classify polymer crystallization broadly into two kinetic regimes. One is observed in melts or in high molar mass polymer solutions and…
The scaling theory of irreversible aggregation is discussed in some detail. First, we review the general theory in the simplest case of binary reactions. We then extend consideration to ternary reactions, multispecies aggregation,…
Governing equations are derived for the kinetics of physical aging in polymeric glasses. An amorphous polymer is treated as an ensemble of cooperatively rearranged regions (CRR). Any CRR is thought of as a string of elementary clusters…
We present an approximation scheme to the master kinetic equations for aggregation and gelation with thermal breakup in colloidal systems with variable attraction energy. With the cluster fractal dimension $d_{f}$ as the only…