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The conductance-voltage spectrum of molecular nanostructures measured by scanning tunneling spectroscopy (STS) is generally assumed to reflect the local density of states of the molecule. This excludes the possibility of observing negative…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Yongqiang Xue , Supriyo Datta , Seunghun Hong , R. Reifenberger , Jason I. Henderson , Cliff P. Kubiak

We report electronic transport measurements of single-molecule transistor devices incorporating bipyridyl-dinitro oligophenylene-ethynylene dithiol (BPDN-DT), a molecule known to exhibit conductance switching in other measurement…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Z. K. Keane , J. W. Ciszek , J. M. Tour , D. Natelson

We present the multilevel fabrication and measurement of a Coulomb-blockade device displaying tunable negative differential resistance (NDR). Applications for devices displaying NDR include amplification, logic, and memory circuits. Our…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 C. P. Heij , D. C. Dixon , P. Hadley , J. E. Mooij

Computational methods are fast becoming an integral part of nanoelectronics design process. With increasing computational power, electron transport simulation methods such as Non-equilibrium Greens function (NEGF) methods now hold promise…

Materials Science · Physics 2021-09-28 A. Ramazani , F. Shayeganfar , V. Sundararaghavan , Nicholas Xuanlai Fang

We demonstrate, based on low-temperature scanning tunneling microscopy (STM) and spectroscopy, a pronounced negative differential resistance (NDR) in spin-crossover (SCO) molecular devices, where a Fe$^{\text{II}}$ SCO molecule is deposited…

We have observed tunable negative differential resistance (NDR) in scanning tunneling spectroscopy measurements of a double layer of C60 molecules on a metallic surface. Using a simple model we show that the observed NDR behavior is…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Grobis , A. Wachowiak , R. Yamachika , M. F. Crommie

We determine the conditions in which negative differential resistance (NDR) appears in the C$_{60}$-based molecular device of [Phys. Rev. Lett. {\bf 100}, 036807 (2008)] by means of ab-initio electron-transport simulations. Our calculations…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Frederico D. Novaes , Manuel Cobian , Alberto Garcia , Pablo Ordejon , Hiromu Ueba , Nicolas Lorente

We have carried out a preliminary design and simulation of a single-electron resistive switch based on a system of two linear, parallel, electrostatically-coupled molecules: one implementing a single-electron transistor and another serving…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Nikita Simonian , Andreas Mayr , Konstantin K. Likharev

In single electron tunneling through clean, suspended carbon nanotube devices at low temperature, distinct switching phenomena have regularly been observed. These can be explained via strong interaction of single electron tunneling and…

Mesoscale and Nanoscale Physics · Physics 2015-09-24 D. R. Schmid , P. L. Stiller , C. Strunk , A. K. Hüttel

While Single Molecule Transistors have been employed in laboratory research for a number of years, there remain many details related to charge transport that have yet to be delineated. We have used the technique of electromigration to…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Gavin D. Scott , Kelly S. Chichak , Andrea J. Peters , Stuart J. Cantrill , J. Fraser Stoddart , H. W. Jiang

We report two examples of transport phenomena based on sharp features in the effective density of states of molecular-scale transistors: Kondo physics in C$_{60}$-based devices, and gate-modulated negative differential resistance (NDR) in…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. H. Yu , D. Natelson

We measure the current vs voltage (I-V) characteristics of a diodelike tunnel junction consisting of a sharp metallic tip placed at a variable distance d from a planar collector and emitting electrons via electric-field assisted emission.…

We report the creation and characterization of a molecular-scale negative differential conductance (NDC) device by assembling a triangular trimer of 4,5,9,10-tetrabromo-1,3,6,8-tetraazapyrene (TBTAP) molecules on a superconducting Pb(111)…

Mesoscale and Nanoscale Physics · Physics 2025-08-08 Chao Li , Vladislav Pokorný , Prokop Hapala , Martin Žonda , Ping Zhou , Silvio Decurtins , Shi-Xia Liu , Fengqi Song , Rémy Pawlak , Ernst Meyer

The transport properties of unsubstituted and amino-substituted butanethiol molecules sandwiched between Au electrodes are investigated by using first-principles approaches. New states are observed around the Fermi levels when -NH2 is…

Mesoscale and Nanoscale Physics · Physics 2009-04-06 Chun-Lan Ma , Diu Nghiem , Yu-Chang Chen

Low-temperature transport spectroscopy measurements on a quantum dot lithographically defined in a multiwall $\mathrm{MoS}_2$ nanotube are demonstrated. At $T=300\,\mathrm{mK}$, clear Coulomb blockade is observed, with charging energies in…

Mesoscale and Nanoscale Physics · Physics 2019-11-12 Simon Reinhardt , Luka Pirker , Christian Bäuml , Maja Remškar , Andreas K. Hüttel

We have fabricated a variety of novel molecular tunnel junctions based on self-assembled-monolayers (SAM) of two-component solid-state mixtures of molecular wires (1,4 methane benzene-dithiol; Me-BDT with two thiol anchoring groups), and…

Materials Science · Physics 2009-11-11 Vladimir Burtman , Alexander S. Ndobe , Valy Z. Vardeny

We studied charge transport phenomena through a core substituted naphthalenediimide (NDI) single-molecule junctions using the electrochemical STM-based break junction technique in combination with DFT calculations. The conductance switch…

Mesoscale and Nanoscale Physics · Physics 2016-11-10 Y. Li , M. Baghernejad , Q. Al-Galiby , D. Manrique , G. Zhang , J. Hamill , Y. Fu , P. Broekmann , W. Hong , T. Wandlowski , D. Zhang , C. J. Lambert

Density-functional calculations are used to clarify the role of an ultrathin LiF layer on Al electrodes used in molecular electronics. The LiF layer creates a sharp density of states (DOS), as in a scanning-tunneling microscope (STM) tip.…

Materials Science · Physics 2007-05-23 Z. H. Lu , M. W. C. Dharma-wardana , R. S. Khangura , Marek Z. Zgierski , Douglas Ritchie

It was observed in recent experiments that the current-voltage characteristics (IV) of BPDN-DT (bipyridyl- dinitro- oligophenylene- ethynylene- dithiol) can be switched in a very controlled manner between "on" and "off" traces by applying a…

Mesoscale and Nanoscale Physics · Physics 2009-06-26 Velimir Meded , Alexei Bagrets , Andreas Arnold , Ferdinand Evers

Nanomagnetometry using the nitrogen-vacancy (NV) centre in diamond has attracted a great deal of interest because of the combined features of room temperature operation, nanoscale resolution and high sensitivity. One of the important goals…

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