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The role of particle shape in evaporation-induced auto-stratification in dispersed colloidal suspensions is explored with molecular dynamics simulations of mixtures of solid spheres, aspherical particles, and hollow spheres. A unified…

Soft Condensed Matter · Physics 2025-02-25 Binghan Liu , Gary S. Grest , Shengfeng Cheng

In numerous solution-processed thin films, a complex morphology resulting from liquid-liquid phase separation (LLPS) or from polycrystallization arises during the drying or subsequent processing steps. The morphology has a strong influence…

Applied Physics · Physics 2022-06-28 Olivier J. J. Ronsin , Jens Harting

We consider thin fluid films placed on thermally conductive substrates and exposed to time-dependent spatially uniform heat source. The evolution of the films is considered within the long-wave framework in the regime such that both…

Soft Condensed Matter · Physics 2016-06-16 Nanyi Dong , Lou Kondic

Lubrication equations allow to describe many structurin processes of thin liquid films. We develop and apply numerical tools suitable for their analysis employing a dynamical systems approach. In particular, we present a time integration…

Pattern Formation and Solitons · Physics 2010-09-03 Ph. Beltrame , U. Thiele

We present experiments to study the relaxation of a nano-scale cylindrical perturbation at one of the two interfaces of a thin viscous free-standing polymeric film. Driven by capillarity, the film flows and evolves towards equilibrium by…

Soft Condensed Matter · Physics 2020-05-13 Vincent Bertin , John Niven , Howard A. Stone , Thomas Salez , Elie Raphael , Kari Dalnoki-Veress

Drying suspensions often leave behind complex patterns of particulates, as might be seen in the coffee stains on a table. Here we consider the dynamics of periodic band or uniform solid film formation on a vertical plate suspended partially…

Soft Condensed Matter · Physics 2014-12-05 C. Nadir Kaplan , Ning Wu , Shreyas Mandre , Joanna Aizenberg , L. Mahadevan

We have studied the approach to equilibrium of islands and pores in two dimensions. The two-regime scenario observed when islands evolve according to a set of particular rules, namely relaxation by steps at low temperature and smooth at…

Materials Science · Physics 2009-11-10 Jose L. Iguain , Laurent J. Lewis

We review recent experiments on dewetting thin films of evaporating colloidal nanoparticle suspensions (nanofluids) and discuss several theoretical approaches to describe the ongoing processes including coupled transport and phase changes.…

We explain theoretically peculiarities of the smectic A -- hexatic B equilibrium phase coexistence in a finite temperature range recently observed experimentally in free standing smectic films [I.A.Zaluzhnyy et al., Physical Review E,…

Soft Condensed Matter · Physics 2019-09-04 E. I. Kats , V. V. Lebedev , E. S. Pikina

Phase separation in a low-density gas-like phase and a high-density liquid-like one is a common trait of biological and synthetic self-propelling particles' systems. The competition between motility and stochastic forces is assumed to fix…

Soft Condensed Matter · Physics 2020-04-15 Pin Nie , Joyjit Chattoraj , Antonio Piscitelli , Patrick Doyle , Ran Ni , Massimo Pica Ciamarra

Experiments of particle-laden inclined film flow [Zhou, Dupuy, Bertozzi, and Hosoi, Phys. Rev. Lett. 94 (2005)] have displayed different settling behaviors depending on the particle concentration $\phi$ and angle of inclination $\theta$, in…

Fluid Dynamics · Physics 2009-11-13 Benjamin P. Cook

We develop a dynamical density functional theory based model for the drying of colloidal films on planar surfaces. We consider mixtures of two different sizes of hard-sphere colloids. Depending on the solvent evaporation rate and the…

Soft Condensed Matter · Physics 2021-01-28 Boshen He , Ignacio Martin-Fabiani , Roland Roth , Gyula I. Tóth , Andrew J. Archer

We consider two thin layers of immiscible liquids on a heated solid horizontal substrate. The free liquid-liquid and liquid-gas interfaces of such a two-layer (or bilayer) liquid film may be unstable due to effective molecular interactions…

Pattern Formation and Solitons · Physics 2007-05-23 Andrey Pototsky , Michael Bestehorn , Domnic Merkt , Uwe Thiele

The equilibrium phase diagram of a 1:1 symmetrical mixture composed of oppositely charged colloids is calculated using Monte Carlo simulations. We model the system by the DLVO effective interaction potential. The phase diagram is similar to…

Soft Condensed Matter · Physics 2007-05-23 José B. Caballero , Antonio M. Puertas

We investigate the formation and the coarsening dynamics of islands in a strained epitaxial semi-conductor film. These islands are commonly observed in thin films undergoing a morphological instability due to the presence of the elasto…

Materials Science · Physics 2016-11-02 Guido Schifani , Thomas Frisch , Mederic Argentina , Jean-Noël Aqua

We report on a new type of experiment that enables us to monitor spatially and temporally heterogeneous dynamic properties in complex fluids. Our approach is based on the analysis of near-field speckles produced by light diffusely reflected…

Soft Condensed Matter · Physics 2012-08-10 P. Zakharov , F. Scheffold

Particle-stabilised emulsions are a cornerstone of soft matter science due to their broad application and fundamental relevance. Computer simulations provide key insights into the formation and behaviour of these emulsions, yet current…

Soft Condensed Matter · Physics 2026-02-19 Elisabeth C. Eij , Joost de Graaf , Martin F. Haase , Jesse M. Steenhoff

The kinetics of phase transition processes often governs the resulting material microstruc-ture. Using optical microscopy, we here investigate the formation and stabilization of a po-rous crystalline microstructure forming in low-salt…

Soft Condensed Matter · Physics 2023-06-23 Nina Lorenz , Christopher Wittenberg , Thomas Palberg

The systems of molecules with a permanent dipole moment have solid phases with various crystal symmetries. In particular, the solid phases of the simplest of these systems, the dipolar hard sphere model, have been extensively studied in the…

Statistical Mechanics · Physics 2017-10-04 D. Levesque

We investigate sedimentation of model hard sphere-like colloidal dispersions confined in horizontal capillaries using laser scanning confocal microscopy, dynamical density functional theory, and Brownian dynamics computer simulations. For…

Soft Condensed Matter · Physics 2009-11-13 C. Patrick Royall , Joachim Dzubiella , Matthias Schmidt , Alfons van Blaaderen
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