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Adsorption of ortho-deuterium and para-hydrogen films on a graphite substrate, pre-plated with a single atomic layer of krypton, is studied theoretically by means of quantum Monte Carlo simulations at low temperature. Our model explicitly…

Statistical Mechanics · Physics 2007-09-28 Joseph Turnbull , Massimo Boninsegni

We study the low temperature properties of a single layer of parahydrogen adsorbed on graphene, by means of Quantum Monte Carlo simulations. The computed phase diagram is very similar to that of helium on the same substrate, featuring…

Mesoscale and Nanoscale Physics · Physics 2018-05-02 Marisa Dusseault , Massimo Boninsegni

Adsorption of para-Hydrogen on the outer surface of a single fullerene is studied theoretically, by means of ground state Quantum Monte Carlo simulations. We compute energetics and radial density profiles of para-Hydrogen for various…

Statistical Mechanics · Physics 2009-11-10 Joseph D. Turnbull , Massimo Boninsegni

Adsorption of para-hydrogen films on Alkali metals substrates at low temperature is studied theoretically by means of Path Integral Monte Carlo simulations. Realistic potentials are utilized to model the interaction between two…

Statistical Mechanics · Physics 2009-11-11 M. Boninsegni

The low-temperature properties of one and two layers of parahydrogen adsorbed on graphite are investigated theoretically through Quantum Monte Carlo simulations. We adopt a microscopic model that explicitly includes the corrugation of the…

Other Condensed Matter · Physics 2024-05-14 Jie-Ru Hu , Massimo Boninsegni

We report our results on the adsorption of noble gases such as argon, krypton and xenon on a graphene sheet, using Grand Canonical Monte Carlo (GCMC) simulations. We calculated the two-dimensional gas-liquid critical temperature for each…

Materials Science · Physics 2016-09-08 Sidi M. Maiga , Silvina M. Gatica

We calculated the phase diagram of the second layer of $para$-H$_2$ adsorbed on graphite using quantum Monte Carlo methods. The second layer shows an incommensurate triangular crystal structure. By using a symmetric wave function, that…

Other Condensed Matter · Physics 2022-03-14 M. C. Gordillo , J. Boronat

We revisit the problem of adsorption of a single He-4 layer on graphene, focusing on the commensurate C1/3 crystalline phase, specifically on whether it may possess a nonzero superfluid response, and on the existence of superfluid phases,…

Strongly Correlated Electrons · Physics 2024-08-26 Siyuan Yu , Massimo Boninsegni

Recent heat-capacity experiments show quite unambiguously the existence of a liquid $^3$He phase adsorbed on graphite. This liquid is stable at an extremely low density, possibly one of the lowest found in Nature. Previous theoretical…

Other Condensed Matter · Physics 2016-04-20 M. C. Gordillo , J. Boronat

The study of the adsorption phenomenon of helium began many decades ago with the discovery of graphite as a homogeneous substrate for investigation of physically adsorbed monolayer films. In particular, helium monoatomic layers on graphite…

Materials Science · Physics 2016-02-17 R. Burganova , Y. Lysogorskiy , O. Nedopekin , D. Tayurskii

The low temperature phase diagram of $^4$He adsorbed on a single graphene sheet is studied by computer simulation of a system comprising nearly thousand helium atoms. In the first layer, two commensurate solid phases are observed, with…

Other Condensed Matter · Physics 2015-06-12 Jodok Happacher , Philippe Corboz , Massimo Boninsegni , Lode Pollet

The phase diagram of the first layer of H$_2$ adsorbed on top of a single graphene sheet has been calculated by means of a series of diffusion Monte Carlo (DMC) simulations. We have found that, as in the case of $^4$He, the ground state of…

Materials Science · Physics 2015-05-18 M. C. Gordillo , J. Boronat

Using a path-integral Monte Carlo method for simulating superfluid quantum films, we investigate helium layers adsorbed on a substrate consisting of graphite plus two solid helium layers. Our results for the promotion densities and the…

Statistical Mechanics · Physics 2009-10-31 Marlon Pierce , Efstratios Manousakis

Chemisorption of hydrogen on graphene is studied using atomistic simulations with the second generation of reactive empirical bond order Brenner inter-atomic potential. The lowest energy adsorption sites and the most important metastable…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 Abdiravuf A. Dzhurakhalov , Francois M. Peeters

The use of a novel three-dimensional graphene structure allows circumventing the limitations of the two-dimensional nature of graphene and its application in hydrogen absorption. Here we investigate hydrogen-bonding on monolayer graphene…

Using quantum Monte Carlo we have studied the superfluid density of the first layer of $^4$He and H$_2$ adsorbed on graphene and graphite. Our main focus has been on the equilibrium ground state of the system, which corresponds to a…

Other Condensed Matter · Physics 2015-05-27 M. C. Gordillo , C. Cazorla , J. Boronat

We have computed the adsorption of Krypton in a closed single-walled carbon nanotube using the method of Grand Canonical Monte Carlo. Our results indicate evidence of an incommensurate solid formed at high pressure and low temperature…

Materials Science · Physics 2015-05-19 Oludotun B. Ode , Silvina M. Gatica

First principle computer simulations of a thin parahydrogen film adsorbed on a silica substrate at low temperature (below 6 K) yield no evidence that the top layer is liquid and/or in the proximity of a superfluid transition, as claimed in…

Statistical Mechanics · Physics 2021-02-02 Massimo Boninsegni

Quantum Monte Carlo simulations at zero temperature of a $^3$He monolayer adsorbed on graphite, either clean or preplated with $^4$He, unexpectedly point to a gas-liquid phase transition at a very low areal density of the order of…

Statistical Mechanics · Physics 2016-03-23 Michele Ruggeri , Ettore Vitali , Davide Emilio Galli , Massimo Boninsegni , Saverio Moroni

The process of hydrogen desorption from graphane (graphene sheet saturated by hydrogen adsorbed from both sides) has been studied using the method of molecular dynamics. The temperature dependences of the time of desorption onset for…

Mesoscale and Nanoscale Physics · Physics 2010-01-08 L. A. Openov , A. I. Podlivaev
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