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We determined the zero-temperature phase diagram of D$_2$ physisorbed on graphane using the diffusion Monte Carlo method. The substrate used was C-graphane, an allotropic form of the compound that has been experimentally obtained through…

Materials Science · Physics 2014-03-05 C Carbonell-Coronado , F De Soto , C Cazorla , J Boronat , MC Gordillo

The second layer of He-4 adsorbed on a graphite substrate is studied by Quantum Monte Carlo simulations. We make use of a microscopic model of the substrate fully accounting for its corrugation, and compare the results to those obtained…

Statistical Mechanics · Physics 2022-12-22 Massimo Boninsegni , Saverio Moroni

We discuss Molecular Dynamics (MD) computer simulations of tetracosane (C24H50) monolayer physisorbed onto a graphite surface. The alkane molecules are simulated with explicit hydrogens, and the graphite substrate is represented as an…

Materials Science · Physics 2008-10-29 L. Firlej , B. Kuchta , M. W. Roth , M. J. Connolly , Carlos Wexler

We have measured surface morphology and gas adsorption characteristics of uncompressed pyrolytic graphite sheet (uPGS) which is a candidate substrate for AC and DC superflow experiments on monolayers of 4He below T = 1 K. The PGS is a…

Materials Science · Physics 2018-09-20 Sachiko Nakamura , Daisuke Miyafuji , Ryo Toda , Tomohiro Matsui , Hiroshi Fukuyama

The ability of atomic hydrogen to chemisorb on graphene makes the latter a promising material for hydrogen storage. Based on scanning tunneling microscopy techniques, we report on site-selective adsorption of atomic hydrogen on convexly…

The discovery of fullerenes has stimulated extensive exploration of the resulting behavior of adsorbed films. Our study addresses the planar substrates graphene-fluoride (GF) and graphane (GH) in comparison to graphene. We present initial…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 L. Reatto , M. Nava , D. E. Galli , C. Billman , J. O. Sofo , M. W. Cole

A quantum Monte Carlo approach, considering all the corrugation effects, was used to calculate the complete phase diagram of the second $^3$He layer adsorbed on graphite. We found that a first-layer triangular solid was in equilibrium with…

Other Condensed Matter · Physics 2018-06-13 M. C. Gordillo , J. Boronat

We present results of a theoretical study of 4He films adsorbed on graphite, based on the continuous space worm algorithm. In the first layer, we find a domain-wall phase and a (7/16) registered structure between the commensurate (1/3) and…

Statistical Mechanics · Physics 2009-11-13 P. Corboz , M. Boninsegni , L. Pollet , M. Troyer

Using realistic helium-helium and helium-graphite interactions and the path integral Monte Carlo method, we are able to identify the gas, superfluid liquid, commensurate-solid, and incommensurate-solid phases, and the coexistence regions…

Condensed Matter · Physics 2009-10-31 Marlon Pierce , Efstratios Manousakis

Chemical adsorption of atomic hydrogen on a negatively charged single layer graphene sheet has been analyzed with ab-initio Density Functional Theory calculations. We have simulated both finite clusters and infinite periodic systems to…

Materials Science · Physics 2015-05-18 J. A. Verges , P. L. de Andres

We investigate 1D aperiodic multilayer microstructures in order to achieve near total absorption in preselected wavelengths in a graphene monolayer. Our structures are designed by a genetic optimization algorithm coupled to a transfer…

Optics · Physics 2018-03-14 Iman Zand , Hamed Dalir , Ray T. Chen , Jonathan P. Dowling

Lubricants can affect quasicrystalline coatings surfaces by modifying commensurability of the interfaces. We report results of the first computer simulation studies of physically adsorbed hydrocarbons on a quasicrystalline surface: methane,…

Materials Science · Physics 2014-12-24 Wahyu Setyawan , Renee D. Diehl , Stefano Curtarolo

The electronic properties of a graphene sheet with attached hydrogen atoms is studied using a modified Falicov-Kimball model on the honeycomb lattice. It is shown that in the ground state this system separates into two phases: fully…

Mesoscale and Nanoscale Physics · Physics 2012-11-30 A. L. Rakhmanov , A. V. Rozhkov , A. O. Sboychakov , Franco Nori

Using extensive Monte Carlo simulations, we investigate the surface adsorption of self-avoiding trails on the triangular lattice with two- and three-body on-site monomer-monomer interactions. In the parameter space of two-body, three-body,…

Statistical Mechanics · Physics 2020-01-01 Nathann T. Rodrigues , Tiago J. Oliveira , Thomas Prellberg , Aleksander L. Owczarek

We propose a simplified description of fluid adsorption on heterogenenous micropatterned substrates. Using this approach, we are able to rederive results obtained earlier using effective interfacial Hamiltonian methods and predict a number…

Condensed Matter · Physics 2009-11-07 C. Rascon , A. O. Parry

The adsorption of hydrogen at nonpolar GaN(1-100) surfaces and its impact on the electronic and vibrational properties is investigated using surface electron spectroscopy in combination with density functional theory (DFT) calculations. For…

Materials Science · Physics 2017-06-28 L. Lymperakis , J. Neugebauer , M. Himmerlich , S. Krischok , M. Rink , J. Kröger , V. M. Polyakov

By using the diffusion Monte Carlo method, we obtained the full phase diagram of $^3$He on top of graphite preplated with a solid layer of $^4$He. All the $^4$He atoms of the substrate were explicitly considered and allowed to move during…

Other Condensed Matter · Physics 2016-11-23 M. C. Gordillo , J. Boronat

The behavior of a polyelectrolyte adsorbed on a charged substrate of high-dielectric constant is studied by both Monte-Carlo simulation and analytical methods. It is found that in a low enough ionic strength medium, the adsorption…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

We investigate the adsorption of molecular hydrogen on pristine zinc oxide (ZnO) platelets. The volumetric and gravimetric hydrogen storage capacities of the ZnO monolayers are evaluated in a broad range of thermodynamic conditions (i.e.,…

1.8 micrometer-thick magnesium hydride films were synthesized in a single-step process by reactive plasma-assisted sputtering. The MgH2 thin films, which were deposited on two types of flexible surfaces (namely graphite and polyimide foils)…

Applied Physics · Physics 2023-11-03 Huy Le-Quoc , Marie Coste , Ana Lacoste , L. Laversenne