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We report a comprehensive Raman study of the phonon behaviour in PdSe$_2$ in the temperature range of 5 K to 300 K. A remarkable change in the Raman spectrum is observed at 120 K: a significant enhancement of the out-of-plane phonon…

We report a Raman study of the effect of temperature on the self-energies of optical phonons in a number of transition metals with hexagonal-close-packed structure. Anisotropic softening of phonon energies and narrowing of phonon linewidths…

Materials Science · Physics 2017-01-04 Yu. S. Ponosov , S. V. Streltsov

The effect of pressure on optical phonon frequencies of MgB$_2$ has been calculated using the frozen-phonon approach based on a pseudopotential method. Gr\"uneisen parameters of the harmonic mode frequencies are reported for the…

Superconductivity · Physics 2009-11-07 K. Kunc , I. Loa , K. Syassen , R. K. Kremer , K. Ahn

Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…

We report the first experiments on the high pressure phonon spectra of transition-metal nitrides HfN, ZrN, and NbN, obtained by Raman scattering measurements. Two pronounced bands, which are related to the acoustic part at low frequency…

We report the evolution of the Raman active A_g phonon modes in the charge-ordered manganite Pr_{0.63}Ca_{0.37}MnO_{3} as a function of temperature from 300K to 25K. Our studies reveal that the linewidths of A_g(2) and A_g(4) phonons…

Strongly Correlated Electrons · Physics 2009-11-07 Rajeev Gupta , G. Venketeswara Pai , A. K. Sood , T. V. Ramakrishnan , C. N. R. Rao

Resonance Raman scattering, a very effective and sensitive technique for atomically thin semiconducting transition metal dichalcogenide, can be used to observe the phonons from the entire Brillouin zone. In addition to the significance of…

Materials Science · Physics 2023-02-06 Deepu Kumar , Nasaru Khan , Rahul Kumar , Mahesh Kumar , Pradeep Kumar

We report interesting anomalies in the temperature dependent Raman spectra of FeSe$_{0.82}$ measured from 3K to 300K in the spectral range from 60 to 1800 cm$^{-1}$ and determine their origin using complementary first-principles density…

Raman spectra of the MgB2 ceramic samples were measured as a function of pressure up to 32 GPa at room temperature. The spectrum at normal conditions contains a very broad peak at ~590 cm-1 related to the E2g phonon mode. The frequency of…

Materials Science · Physics 2009-11-07 K. P. Meletov , J. Arvanitidis , M. P. Kulakov , N. N. Kolesnikov , G. A. Kourouklis

The effects of phonon anharmonicity, phonon-magnon and electron-phonon interactions on the temperature dependence of Raman optical phonon modes are theoretically investigated. Besides of the Klemens result for the phonon width due to…

Strongly Correlated Electrons · Physics 2015-06-16 L. A. Falkovsky

The theory of Raman scattering in half-metals by optical phonons interacting with conduction electrons is developed. We evaluate the effect of electron-phonon interactions at ferromagnetic ordering in terms of the Boltzmann equation for…

Materials Science · Physics 2014-03-25 L. A. Falkovsky

The effect of pressure on the zone-center optical phonon modes of antimony in the A7 structure has been investigated by Raman spectroscopy. The A_g and E_g frequencies exhibit a pronounced softening with increasing pressure, the effect…

Other Condensed Matter · Physics 2009-11-11 X. Wang , K. Kunc , I. Loa , U. Schwarz , K. Syassen

Temperature-dependent (5 K to 300 K) Raman scattering study of A$_{1g}$/A'$_1$ phonon modes in mono-layer (1L), bilayer (2L), trilayer (3L), and tetralayer (4L) MoTe$_2$ is reported. The temperature evolution of the modes' intensity…

Mesoscale and Nanoscale Physics · Physics 2017-09-19 K. Gołasa , M. Grzeszczyk , M. R. Molas , M. Zinkiewicz , Ł. Bala , K. Nogajewski , M. Potemski , A. Wysmołek , A. Babiński

The pressure-induced changes in the optical properties of $\beta$-Na$_{0.33}$V$_2$O$_5$ single crystals at room temperature were studied by polarization-dependent Raman and far-infrared reflectivity measurements under high pressure. From…

Strongly Correlated Electrons · Physics 2018-02-02 Simone Frank , Christine A. Kuntscher , Ivan Gregora , Touru Yamauchi , Yutaka Ueda

Temperature-dependent Raman spectra of TbMnO$_3$ from 5 K to 300 K in the spectral range of 200 to 1525 cm$^{-1}$ show five first-order Raman allowed modes and two high frequency modes. The intensity ratio of the high frequency Raman band…

Strongly Correlated Electrons · Physics 2010-04-12 Pradeep Kumar , Surajit Saha , D. V. S. Muthu , J. R. Sahu , A. K. Sood , C. N. R. Rao

Raman spectra from silicon nanostructures, recorded using excitation laser power density of 1.0 kW/cm^2, is employed here to reveal the dominance of thermal effects at temperatures higher than the room temperature. Room temperature Raman…

Mesoscale and Nanoscale Physics · Physics 2012-01-25 Rajesh Kumar , Vivek Kumar , A. K. Shukla

We have performed polarized Raman scattering measurements on the newly discovered superconductor Ta$_{4}$Pd$_{3}$Te$_{16}$ ($T_c = 4.6$ K). We observe twenty-eight out of thirty-three Raman active modes, with frequencies in good accordance…

Superconductivity · Physics 2015-11-25 D. Chen , P. Richard , Z. -D. Song , W. -L. Zhang , S. -F. Wu , W. H. Jiao , Z. Fang , G. -H. Cao , H. Ding

Polarized Raman scattering spectra of superconducting K$_x$Fe$_{2-y}$Se$_2$ and nonsuperconducting K$_{0.8}$Fe$_{1.8}$Co$_{0.2}$Se$_2$ single crystals were measured in a temperature range from 10 K up to 300 K. Two Raman active modes from…

Materials Science · Physics 2016-09-20 M. Opačić , N. Lazarević , M. Šćepanović , Hyejin Ryu , Hechang Lei , C. Petrovic , Z. V. Popović

We examine anharmonic contributions to the optical phonon modes in bulk $T_d$-MoTe$_2$ through temperature-dependent Raman spectroscopy. At temperatures ranging from 100 K to 200 K, we find that all modes redshift linearly with temperature…

Materials Science · Physics 2016-07-20 Jaydeep Joshi , Iris Stone , Ryan Beams , Sergiy Krylyuk , Irina Kalish , Albert Davydov , Patrick Vora

We present a Raman study of ZrAs_{2} single crystals, a nodal line semimetal with symmetry-enforced Dirac-like band crossings. We identified the symmetry of phonon modes by polarized light measurements and comparison with calculated phonon…

Materials Science · Physics 2024-05-16 R. Bacewicz , C. Jastrzębski , K. Zberecki , A. S. Wadge , D. Jastrzębski , A. Wiśniewski
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