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We study the spatial and orientational distribution of rodlike counterions (such as mobile nanorods) as well as the effective interaction mediated by them between two plane-parallel surfaces that carry fixed (quenched) heterogeneous charge…

Soft Condensed Matter · Physics 2020-10-01 Ali Naji , Kasra Hejazi , Elnaz Mahgerefteh , Rudolf Podgornik

We report new attractive force between ions that are shielded by degenerate electrons in quantum plasmas. Specifically, we show that the electric potential around an isolated ion has a hard core negative part that resembles the…

Plasma Physics · Physics 2012-08-13 Padma Kant Shukla , Bengt Eliasson

Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…

Soft Condensed Matter · Physics 2025-02-04 Ali Behjatian , Ralf Blossey , Madhavi Krishnan

It will be shown that for a solution of salt dissolved in water in contact with a metallic wall, the concentration of salt ions (both positive and negative) within a few Angstroms of the wall can be large enough to exceed the solubility…

Soft Condensed Matter · Physics 2020-02-05 J. B. Sokoloff

We investigate the phenomenon of multilayer formation via layer-by-layer deposition of alternating charge polyelectrolytes. Using mean-field theory, we find that a strong short-range attraction between the two types of polymer chains is…

Soft Condensed Matter · Physics 2012-01-31 Adi Shafir , David Andelman

In this paper, we theoretically study the electrostatic interaction between a pair of identical colloids with constant surface potentials sitting in close vicinity of each other at a fluid interface. By employing a simplified yet reasonable…

Soft Condensed Matter · Physics 2020-07-29 Rick Bebon , Arghya Majee

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

We compare the recent experimentally measured forces between charged colloidal particles, as well as their effective surface potentials (surface charge) in the presence of multivalent counterions in a bathing monovalent salt solution, with…

Soft Condensed Matter · Physics 2017-05-24 Matej Kanduč , Mohsen Moazzami Gudarzi , Valentina Valmacco , Rudolf Podgornik , Gregor Trefalt

Small angle neutron scattering intensity distributions taken from cytochrome C and lysozyme protein solutions show a rising intensity at very small wave vector, Q, which can be interpreted in terms of the presence of a weak long-range…

Soft Condensed Matter · Physics 2009-11-11 Yun Liu , Emiliano Fratini , Piero Baglioni , Wei-Ren Chen , Sow-Hsin Chen

Recent measurements of microsphere interactions in diverse media suggest that the standard dielectric-continuum models of solution-phase interactions are fundamentally incomplete. Experiments indicate that the interactions of charged…

Soft Condensed Matter · Physics 2026-05-12 Ali Behjatian , Madhavi Krishnan

We review works on screening of a macroion, such as colloidal particle or double helix DNA, by multivalent counterions. Multivalent metal ions, charged micelles, short or long polyelectrolytes can play the role of multivalent counterions.…

Soft Condensed Matter · Physics 2007-05-23 T. T. Nguyen , A. Yu. Grosberg , B. I. Shklovskii

The long range attractive force between two hydrophobic surfaces immersed in water is observed to decrease exponentially with their separation -- this distance-dependence of effective force is known as the hydrophobic force law (HFL). We…

Soft Condensed Matter · Physics 2015-06-24 Saikat Banerjee , Rakesh S. Singh , Biman Bagchi

The phase behavior of colloid-polymer mixtures, and of solutions of globular proteins, is often interpreted in terms of a simple model of hard spheres with short-ranged attraction. While such a model yields a qualitative understanding of…

Soft Condensed Matter · Physics 2009-10-31 M. G. Noro , N. Kern , D. Frenkel

A highly-charged spherical colloid in a salt-free environment exerts such a powerful attraction on its counterions that a certain fraction condenses onto the surface of a particle. The degree of condensation depends on the curvature of the…

We consider the effect of atomic hydrogen exposure to a system of two undoped sheets of graphene grown near a silica surface (the first adsorbed to the surface and the second freestanding near the surface). In the absence of atomic hydrogen…

Materials Science · Physics 2012-01-26 Mathias Boström , Bo E. Sernelius

We study, using Monte Carlo simulations, the interaction between charged colloidal particles confined to the air-water interface. The dependence of force on ionic strength and counterion valence is explored. For 1:1 electrolyte, we find…

Soft Condensed Matter · Physics 2018-02-05 Matheus Girotto , Alexandre P. dos Santos , Yan Levin

In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin

Soft matter materials, such as polymers, membranes, proteins, are often electrically charged. This makes them water soluble, which is of great importance in technological application and a prerequisite for biological function. We discuss a…

Soft Condensed Matter · Physics 2007-05-23 H. Boroudjerdi , Y. -W. Kim , A. Naji , R. R. Netz , X. Schlagberger , A. Serr

The adsorption of anions from aqueous solution on the air/water interface controls important heterogeneous chemistry in the atmosphere and is thought to have similar physics to anion adsorption at hydrophobic interfaces more generally.…

Chemical Physics · Physics 2018-05-09 Yujin Tong , Igor Ying Zhang , R. Kramer Campen

We reformulate the theory of strong electrostatic coupling in order to describe an asymmetric electrolyte solution of monovalent salt ions and polyvalent counterions using field-theoretical techniques and Monte-Carlo simulations. The theory…

Soft Condensed Matter · Physics 2015-05-14 Matej Kanduc , Ali Naji , Jan Forsman , Rudolf Podgornik
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