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We compute the low-temperature configurational entropy of a two-dimensional supercooled liquid. Our method, based on a higher-dimensional version of the Grassberger--Procaccia algorithm, can be implemented in a manner that is entirely…

Statistical Mechanics · Physics 2026-05-29 Nina Javerzat , Gerhard Jung , Jorge Kurchan , Misaki Ozawa

We revisit textbook claims that entropy must increase and show that, under time-reversal invariant microscopic dynamics, no universal trajectory-wise or statistical assertion that the coarse-grained entropy $S(t)$ is non-decreasing can…

Statistical Mechanics · Physics 2026-03-06 Ting Peng

Quantum field theory of equilibrium and nonequilibrium Bose-Einstein condensates is formulated so as to satisfy three basic requirements: the Hugenholtz-Pines relation; conservation laws; identities among vertices originating from…

Quantum Gases · Physics 2021-01-08 Takafumi Kita

Bekenstein's conjectured entropy bound for a system of linear size $R$ and energy $E$, namely $S \leq 2 \pi E R$, has counterexamples for many of the ways in which the "system," $R$, $E$, and $S$ may be defined. One consistent set of…

High Energy Physics - Theory · Physics 2018-05-01 Don N. Page

In earlier work we presented a foundation for the Second Law of Classical Thermodynamics in terms of the Entropy Principle. More precisely, we provided an empirically accessible axiomatic derivation of an entropy function defined on all…

Mathematical Physics · Physics 2015-06-16 Elliott H. Lieb , Jakob Yngvason

A complete mathematical theory of nonequilibrium thermodynamics of stochastic systems in terms of master equations is presented. As generalizations of isothermal entropy and free energy, two functions of states play central roles: the Gibbs…

Statistical Mechanics · Physics 2010-05-28 Hao Ge , Hong Qian

We derive a non-equilibrium finite-temperature kinetic theory for a binary mixture of two interacting atomic Bose-Einstein condensates and use it to explore the degree of hydrodynamicity attainable in realistic experimental geometries.…

Quantum Gases · Physics 2015-12-08 M. J. Edmonds , K. L. Lee , N. P. Proukakis

The cornerstones of Boltzmann-Gibbs and nonextensive statistical mechanics respectively are the entropies $S_{BG} \equiv -k \sum_{i=1}^W p_i \ln p_i $ and $S_{q}\equiv k (1-\sum_{i=1}^Wp_i^{q})/(q-1) (q\in{\mathbb R} ; S_1=S_{BG})$. Through…

Statistical Mechanics · Physics 2017-08-23 Constantino Tsallis

We present an analysis of two thermodynamic techniques for determining equilibria of self-gravitating systems. One is the Lynden-Bell entropy maximization analysis that introduced violent relaxation. Since we do not use the Stirling…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-03 Eric I. Barnes , Liliya L. R. Williams

At finite temperatures below the phase transition point, the Bose-Einstein condensation, the macroscopic occupation of a single quantum state by particles of integer spin, is not complete. In the language of superfluid helium, this means…

Mathematical Physics · Physics 2015-09-16 Dionisios Margetis

High-entropy oxides (HEOs) offer a unique platform for exploring the thermodynamic interaction between configurational entropy and enthalpy in stabilizing complex solid solutions. In this study, a series of rock-salt structured oxides with…

Materials Science · Physics 2025-10-13 Ashutosh Kumar , Adrien Moll , Jitendra Kumar , Diana Dragoe , David Bérardan , Nita Dragoe

Statistical mechanics is based on interplay between energy minimization and entropy maximization. Here we formalize this interplay via axioms of cooperative game theory (Nash bargaining) and apply it out of equilibrium. These axioms capture…

Statistical Mechanics · Physics 2020-10-14 S. G. Babajanyan , K. H. Cheong , A. E. Allahverdyan

In this work, we demonstrate the inappropriateness of the Boltzmann-Gibbs log-formulation of the physical Clausius entropy $S$ in connecting thermodynamics and phase space statistics. To achieve our goal, we study thermodynamically the…

Statistical Mechanics · Physics 2014-04-08 Thomas Oikonomou

The shallow water flow model is widely used to describe water flows in rivers, lakes, and coastal areas. Accounting for uncertainty in the corresponding transport-dominated nonlinear PDE models presents theoretical and numerical challenges…

Numerical Analysis · Mathematics 2023-10-11 Dihan Dai , Yekaterina Epshteyn , Akil Narayan

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any…

Statistical Mechanics · Physics 2009-10-31 R. K. P. Zia , L. B. Shaw , B. Schmittmann , R. J. Astalos

We show through a nonlinear Fokker-Planck formalism, and confirm by molecular dynamics simulations, that the overdamped motion of interacting particles at T=0, where T is the temperature of a thermal bath connected to the system, can be…

Statistical Mechanics · Physics 2011-02-08 J. S. Andrade , G. F. T. da Silva , A. A. Moreira , F. D. Nobre , E. M. F. Curado

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

We present a theory for the description of energy relaxation in a nonequilibrium condensate of bosonic particles. The approach is based on coupling to a thermal bath of other particles (e.g., phonons in a crystal, or noncondensed atoms in a…

Mesoscale and Nanoscale Physics · Physics 2013-03-20 I. G. Savenko , T. C. H. Liew , I. A. Shelykh

Recently, Gross claims that Boltzmann entropy $S=k\ln W$ is valid for any system at equilibrium, so that Tsallis entropy is useless in this case. I comment on some arguments forwarded to reach this conclusion and argue that the additive…

Statistical Mechanics · Physics 2007-05-23 Q. A. Wang