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Entropy Has No Direction: A Mirror-State Paradox Against Universal Monotonic Entropy Increase and a First-Principles Proof that Constraints Reshape the Entropy Distribution $P_{\infty}(S;\lambda)$

Statistical Mechanics 2026-03-06 v4

Abstract

We revisit textbook claims that entropy must increase and show that, under time-reversal invariant microscopic dynamics, no universal trajectory-wise or statistical assertion that the coarse-grained entropy S(t)S(t) is non-decreasing can hold. The core is a mirror-state construction: for any microstate AA one constructs its time-reversed partner BB (momenta inverted); requiring S(t)S(t) to be non-decreasing for both AA and BB forces every time to be a local minimum of SS and hence makes S(t)S(t) constant along the trajectory. The consistent picture is that entropy is a stochastic variable described by a probability distribution P(S)P(S) whose shape depends on constraints and boundary conditions; entropy-based regularities are emergent summaries of constraint-dependent microscopic dynamics, and in practice it is constraints and boundaries -- not entropy itself -- that one manipulates to achieve mixing, separation, or self-organization. Working with Boltzmann (coarse-grained) entropy on the energy shell, we then derive from first principles how constraints reshape the long-time entropy distribution P(S;λ)P_{\infty}(S;\lambda) by altering the invariant measure through changes in the Hamiltonian and/or the accessible phase space. In the microcanonical setting we obtain a sharp criterion: the \emph{only} way P(E)(S;λ)P_{\infty}^{(E)}(S;\lambda) can remain the same up to translation is when all accessible macrostate volumes are scaled by a common factor; otherwise the distribution changes structurally. We connect this framework to experiments on asymmetric nanopores and molecular gates, to macroscopic examples from civil engineering (windbreak forests, dikes, vortex suppression, traffic-flow control), and to natural phenomena such as lightning guided to lightning rods, snowflake and mineral-veil growth, and the sudden crystallisation of supercooled water.

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Cite

@article{arxiv.2602.15369,
  title  = {Entropy Has No Direction: A Mirror-State Paradox Against Universal Monotonic Entropy Increase and a First-Principles Proof that Constraints Reshape the Entropy Distribution $P_{\infty}(S;\lambda)$},
  author = {Ting Peng},
  journal= {arXiv preprint arXiv:2602.15369},
  year   = {2026}
}

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