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Chemical modifications such as intercalation can be used to modify surface properties or to further functionalize the surface states of topological insulators. Using ambient pressure X-ray photoelectron spectroscopy, we report copper…

X-ray photoemission and x-ray absorption spectroscopy are important techniques to characterize chemical bonding at surfaces and are often used to identify the strength and nature of adsorbate-substrate interactions. In this study, we judge…

Materials Science · Physics 2023-02-09 Samuel J. Hall , Benedikt P. Klein , Reinhard J. Maurer

We report the results of an x-ray scattering study that reveals oxidation kinetics and formation of a previously unreported crystalline phase of SnO at the liquid-vapour interface of Sn. Our experiments reveal that the pure liquid Sn…

We present a first-principles atomistic thermodynamics framework to describe the structure, composition and segregation profile of an alloy surface in contact with a (reactive) environment. The method is illustrated with the application to…

Materials Science · Physics 2009-11-13 John Kitchin , Karsten Reuter , Matthias Scheffler

The ordered structure of binary alloy nanoparticles determines their magnetic and catalytic characteristics. In the alloys after annealing, one of the components preferentially segregates on the surface to reduce surface energy. This…

Using large-scale molecular dynamics simulations, we investigate the surface properties of lithium, sodium, and potassium silicate glasses containing 25 mole % of alkali oxide. The comparison of two types of surfaces, a melt-formed surface…

Disordered Systems and Neural Networks · Physics 2023-07-12 Zhen Zhang , Simona Ispas , Walter Kob

We systematically investigated various types of surfaces on which rubidium (Rb) atoms were deposited by X-ray photoelectron spectroscopy (XPS) and measured the light-induced atom desorption (LIAD) from those surfaces. The main surfaces of…

The changes of surface structure, induced by electron beam irradiation (EBI) on the surface of poly(aryl-ether-ether-ketone) (PEEK), were investigated by using a range of various experimental techniques, such as tribology, Raman, AFM, NMR,…

Materials Science · Physics 2021-12-07 Zh. Alsar , B. Rakhadilov , N. Almasov , N. Serik , C. Spitas , K. Kostas , Z. Insepov

High-pressure powder x-ray diffraction experiments have revealed that sodium and gold react at room temperature and form new Na-Au intermetallic compounds under high pressure. We have identified four intermetallic phases up to 60 GPa. The…

Materials Science · Physics 2015-05-28 K. Takemura , H. Fujihisa

Atomistic simulations are used to study segregation-induced intergranular film formation in Cu-Zr and Cu-Nb alloys. While Cu-Zr forms structurally disordered or amorphous films, ordered films comprised of a second phase usually precipitate…

Materials Science · Physics 2016-11-09 Zhiliang Pan , Timothy J. Rupert

Structural stability and electronic properties of alkaline-earth metals (Ca, Sr, Ba) induced Si(111)-3x2 surfaces have been comprehensively studied by means of ab initio calculations. Adsorption energy and charge density difference…

Materials Science · Physics 2018-11-20 Jun-Shuai Chai , Zhen-Zhen Li , Lifang Xu , Jian-Tao Wang

A pi-conjugated {C}3h-oligomer involving three dithienylethylene branches bridged at the meta positions of a central benzenic core has been synthesized and deposited either on the Si(100) surface or on the HOPG surface. On the silicon…

Strained coherent heteroepitaxy of III-V semiconductor films such as In$_x$Ga$_{1-x}$As/GaAs has potential for electronic and optoelectronic applications such as high density logic, quantum computing architectures, laser diodes, and other…

Materials Science · Physics 2009-11-13 Lawrence H. Friedman

We studied the surface properties of Ga-Cu based liquid metal alloys, a promising material system for supported catalytically active liquid metal solutions (SCALMS). The impact of Cu dilution in the (liquid) Ga matrix is in-detail…

Effects of steel alloying elements on the formation of the surface oxide layer of hot-dip galvanized press hardened steel after austenitization annealing were examined with various advanced microscopy and spectroscopy techniques. The main…

Microscopic description in the study of immiscibility and segregating properties of liquid metallic binary alloys has gained a renewed scientific and technological interests during the last eight years for the physicists, metallurgists and…

Other Condensed Matter · Physics 2021-01-01 G M Bhuiyan

The spectacular physical properties of quantum materials based on transition metal, rare earth, and actinide elements continue to challenge our comprehension of solid state physics and chemistry. The electronic states of these materials are…

Evolution of composition patterns in the annealed, single-crystal surface alloy film is considered in the presence of the spinodal decomposition, the compositional stress and the diffusion anisotropy. While the former two effects contribute…

Materials Science · Physics 2020-12-02 Mikhail Khenner , Victor Henner

GaSbBi alloys have recently emerged as attractive materials for mid-infrared optoelectronics owing to strong band gap reduction enabled by Bi incorporation into the GaSb matrix. The fundamental understanding of the epitaxial process…

Applied Physics · Physics 2019-04-16 Joonas Hilska , Eero Koivusalo , Janne Puustinen , Soile Suomalainen , Mircea Guina

Anomalous x-ray diffraction studies show that the charge ordering in $\alpha^\prime$-NaV$_2$O$_5$ is of zig-zag type in all vanadium ladders. We have found that there are two models of the stacking of layers along \emph{c-}direction, each…

Strongly Correlated Electrons · Physics 2019-08-17 S. Grenier , A. Toader , J. E. Lorenzo , Y. Joly , B. Grenier , S. Ravy , L. P. Regnault , H. Renevier , J. Y. Henry , J. Jegoudez , A. Revcolevschi