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We investigated the kinetics of H(II) centers (=Ge'-H) in natural silica under repeated 266nm UV irradiations performed by a Nd:YAG pulsed laser. UV photons temporarily destroy these paramagnetic defects, their reduction being complete…

Materials Science · Physics 2009-11-10 F. Messina , M. Cannas , R. Boscaino

We investigated various types of commercial silica irradiated with a pulsed Nd:YAG laser radiation (4.66 eV), with exposure time ranging up to 10000 s. Transient E' centers were probed in situ by measuring the amplitude of the optical…

Materials Science · Physics 2016-08-31 M. Cannas , F. Messina

The conversion processes of Ge-related point defects triggered in amorphous SiO2 by 4.7eV laser exposure were investigated. Our study has focused on the interplay between the (=Ge•-H) H(II) center and the twofold coordinated Ge defect…

Materials Science · Physics 2009-11-11 F. Messina , M. Cannas

Diffusion limited reactions of point defects were investigated in amorphous SiO2 exposed to UV laser light. Electron spin resonance and in situ absorption measurements at room temperature evidenced the annealing of E' centers and the growth…

Materials Science · Physics 2009-11-10 F. Messina , M. Cannas , R. Boscaino

The kinetics of E' centers induced in silica by 4.7eV laser irradiation was investigated observing in situ their optical absorption band at 5.8 eV. After exposure the defects decay due to reaction with diffusing molecular hydrogen of…

Materials Science · Physics 2009-11-10 F. Messina , M. Cannas

We studied the optical absorption induced by 4.7eV pulsed laser radiation on Ge-doped a-SiO2 synthesized by a sol-gel technique. The absorption spectra in the ultraviolet spectral range were measured during and after the end of irradiation…

Materials Science · Physics 2015-06-25 F. Messina , M. Cannas , R. Boscaino , S. Grandi , P. Mustarelli

This experimental PhD work deals with the generation and transformation processes of point defects induced by UV laser irradiation on amorphous silicon dioxide (silica). The investigation relies on several spectroscopic techniques used to…

Materials Science · Physics 2007-05-23 F. Messina

The photo-luminescence features of Ge-oxygen defect centers in a 100nm thick Ge-doped silica film on a pure silica substrate were investigated by looking at the emission spectra and time decay detected under synchrotron radiation excitation…

Materials Science · Physics 2009-11-13 F. Messina , S. Agnello , R. Boscaino , M. Cannas , S. Grandi , E. Quartarone

The kinetics of E' centers (silicon dangling bonds) induced by 4.7eV pulsed laser irradiation in dry fused silica was investigated by in situ optical absorption spectroscopy. The stability of the defects, conditioned by reaction with mobile…

Materials Science · Physics 2009-11-13 F. Messina , M. Cannas

Fused Silica is the material of choice for UV optical systems such as the projection optics in microlithography systems. Unfortunately fused silica is not stable under UV irradition and undergoes compaction and color center formation. The…

mtrl-th · Physics 2008-02-03 G. Gallatin

A rapid and efficient photo-bleaching process was demonstrated with a high-energy nanosecond pulse to recover existing and/or revealed color centers on 10 kGy Gamma-irradiated Yb-doped optical fiber. Multi-mJ pulsed laser based on an…

Optics · Physics 2023-04-06 Esra Kendir Tekgül , Bülend Ortaç

The optical properties of point defects in as-grown natural silica are reviewed. Two emissions peaked at 4.2 eV ($\alpha_E$ band) and at 3.1 eV ($\beta$ band), related to an absorption band at 5.1 eV ($B_{2\beta}$), have been experimentally…

Materials Science · Physics 2007-05-23 Marco Cannas

A previous inelastic UV scattering experiment on silica glass is reproduced using a high grade superpolished sample. In the pristine sample condition, surface scattering is not observable compared to Rayleigh scattering from the bulk.…

Materials Science · Physics 2011-10-21 B. Rufflé , E. Courtens , M. Foret

Bismuth-Gallium co-doped silica glass fiber preform was prepared from nano-porous silica xerogels using a conventional solution doping technique with a heterotrinuclear complex and subsequent sintering. Ga-connected optical Bismuth active…

Materials Science · Physics 2015-06-15 Igor Razdobreev , Hicham El Hamzaoui , Vladimir B. Arion , Mohamed Bouazaoui

Bare reverse biased silicon photodiodes were exposed to 3eV He+, Ne+, Ar+, N2+, N+ and H2O+ ions. In all cases an increase of the reverse current through the diode was observed. This effect and its dependence on the ionization energy of the…

Materials Science · Physics 2017-04-05 S. Shchemelinin , A. Breskin

Irradiation damage is a key physics issue for semiconductor devices under extreme environments. For decades, the ionization-irradiation-induced damage in transistors with silica-silicon structures under constant dose rate is modeled by a…

Applied Physics · Physics 2025-05-20 Yu Song , Guanghui Zhang , Xue-Fen Cai , Yang Liu , Hang Zhou , Le Zhong , Gang Dai , Xu Zuo , Su-Huai Wei

Laboratory measurements of unpolarized and polarized absorption spectra of various samples and crystal stuctures of silicon carbide (SiC) are presented from 1200--35,000 cm$^{-1}$ ($\lambda \sim$ 8--0.28 $\mu$m) and used to improve the…

Instrumentation and Methods for Astrophysics · Physics 2011-02-11 A. M. Hofmeister , K. M. Pitman , A. F. Goncharov , A. K. Speck

Assuming a spherical symmetry, the extreme UV emitted by a very hot source ionizes low pressure molecular hydrogen making a transparent bubble of H II (Protons and electrons). For an increase of radius, intensity of extreme UV and…

General Physics · Physics 2007-07-23 Jacques Moret-Bailly

The relationship between paramagnetic defect centers and UV absorption bands simultaneously generated by ionizing radiation in Ge-doped SiO2 glass is investigated using magneto-optical techniques. A sample of 7.0 mol% Ge-doped SiO2 was…

Materials Science · Physics 2007-05-23 D. Poulios , N. P. Bigelow , J. P. Spoonhower

The generation of organic particle beams is studied in combination with photoionization using uv radiation at 266 nm and vuv light at 157 nm. Single-photon ionization with pulsed vuv light turns out to be sensitive enough to detect various…

Atomic and Molecular Clusters · Physics 2014-02-12 M. Marksteiner , P. Haslinger , M. Sclafani , H. Ulbricht , M. Arndt
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