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The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability…

Materials Science · Physics 2014-11-07 Abdesalem Houari , Samir F. Matar , Volker Eyert

After years of research into colossal magnetoresistant (CMR) manganites using bulk techniques, there has been a recent upsurge in experiments directly probing the electronic states at or near the surface of the bilayer CMR materials…

Strongly Correlated Electrons · Physics 2009-03-13 S. de Jong , Y. Huang , I. Santoso , F. Massee , R. Follath , O. Schwarzkopf , L. Patthey , M. Shi , M. S. Golden

Structure of monolayers built during adsorption process is strongly related to the properties of adsorbed particles. The most important factor is their shape. For example, adsorption of elongated molecules on patterned surfaces may produce…

Materials Science · Physics 2013-06-28 Jakub Barbasz , Michał Cieśla

C60 and C60 based molecules are efficient acceptor and electron transport layers for planar perovskite solar cells. While properties of these molecules are well studied by ab initiomethods, those of solid C60, specifically its optical…

Materials Science · Physics 2018-06-13 Amrita Pal , Saeid Arabnejad , Koichi Yamashita , Sergei Manzhos

Monolayers (ML) of Group-6 transition-metal dichalcogenides (TMDs) are semiconducting two-dimensional materials with direct bandgap, showing promising applications in various fields of science and technology, such as nanoelectronics and…

Computational Physics · Physics 2020-06-24 Mohammad Bahmani , Mahdi Faghihnasiri , Michael Lorke , Agnieszka-Beata Kuc , Thomas Frauenheim

The electronic structures of the Heusler type compounds Fe$_{3-x}V$_x$Si in the concentration range between x = 0 and x = 1 have been probed by photoemission spectroscopy (PES). The observed shift of Si 2p core- level and the main valence…

Using $He@C_{60}$ as an example, we demonstrate that static potential of the fullerene core essentially alters the cross section of the two-electron ionization differential in one-electron energy $d\sigma ^{++}(\omega )/d\epsilon $. We…

Atomic Physics · Physics 2009-11-11 M. Ya. Amusia , E. Z. Liverts , V. B. Mandelzweig

We present angle-resolved photoemission studies of (La1-zPrz)2-2xSr1+2xMn2O7 with x=0.4 and z=0.1,0.2 and 0.4 along with density functional theory calculations and x-ray scattering data. Our results show that the bilayer splitting in the…

Building upon traditional quantum chemistry calculations, we have implemented an {\em ab-initio} method to study the electrical transport in nanocontacts. We illustrate our technique calculating the conductance of C$_{60}$ molecules…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. J. Palacios , A. J. Perez-Jimenez , E. Louis , J. A. Verges

Using first-principles calculations, we demonstrate that an Fe monolayer can assume very different magnetic phases on hexagonal hcp (0001) and fcc (111) surfaces of 4d- and 5d-transition metals. Due to the substrates' d-band filling, the…

Materials Science · Physics 2008-11-07 B. Hardrat , A. Al-Zubi , P. Ferriani , S. Blügel , G. Bihlmayer , S. Heinze

We report photoemission experiments revealing the valence electron spectral function of Mn, Fe, Co and Ni atoms on the Ag(100) surface. The series of spectra shows splittings of higher energy features which decrease with the filling of the…

Strongly Correlated Electrons · Physics 2015-06-12 S. Gardonio , M. Karolak , T. O. Wehling , L. Petaccia , S. Lizzit , A. Goldoni , A. I. Lichtenstein , C. Carbone

A transformation between the magnetically ordered CeCoGe$_3$ and heavy fermion CeFeGe$_3$ is isostructural but not isoelectronic, therefore the characterization of the electronic structure of the CeCo$_{1-x}$Fe$_x$Ge$_3$ series is of…

Materials Science · Physics 2025-03-25 P. Skokowski , K. Synoradzki , M. Werwiński , A. Bajorek , G. Chełkowska , T. Toliński

We study the geometric and electronic structures of silicene monolayer using density functional theory based calculations. The electronic structures of silicene show that it is a semi-metal and the charge carriers in silicene behave like…

Mesoscale and Nanoscale Physics · Physics 2012-05-23 Kamal Chinnathambi

Natural oxidation is a common degradation mechanism of both mechanical and electronic properties for most of the new two-dimensional materials. From another perspective, controlled oxidation is an option to tune material properties,…

Mesoscale and Nanoscale Physics · Physics 2016-12-21 I. S. S. de Oliveira , R. Longuinhos

The models of endofullerenes C60 and C82 with silver atom or diatomic silver are calculated with ab initio SCF Hartree-Fock methods including the full geometry optimization. Ag@C60 is a bound system with positive binding energy while…

Materials Science · Physics 2007-05-23 V. S. Gurin

The departure from perfect spherical symmetry in the case of fullerenes, C60 being the sole exception, induces instabilities due to the stresses generated by the pentagonal protrusions in the sigma-bonded surfaces. By assuming sigma and pi…

Mesoscale and Nanoscale Physics · Physics 2016-09-06 Shoaib Ahmad , Sabih D Khan , Sadia Manzoor

Photoionization from atom-C60 hybrid levels in halogen endufullerene molecules, Cl@C60, Br@C60 and I@C60, are calculated using a linear response density functional method. Both the ordinary electron-configuration where the open shell…

Atomic and Molecular Clusters · Physics 2021-06-08 Dakota Shields , Ruma De , Esam Ali , Mohamed E Madjet , Steven T Manson , Himadri S. Chakraborty

Coupled colloidal quantum dot molecules composed of two fused CdSe/CdS core/shell sphere monomers were recently presented. Upon fusion, the potential energy landscape is changing into two quantum dots separated by a pre-tuned potential…

Mesoscale and Nanoscale Physics · Physics 2019-12-11 Yossef E. Panfil , Doaa Shamalia , Jiabin Cui , Somnath Koley , Uri Banin

We report first-principles results on the electronic structure of various silicene structures. For planar and simply buckled silicenes, we confirm their zero-gap nature and show a significant renormalization of their Fermi velocity by…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Shouting Huang , Wei Kang , Li Yang

Surface adsorption of C$_{60}$ affects its chemical and electronic properties. Numerous studies have reported observation of bright and dark fullerenes on metal surfaces that suggest extensive surface reconstruction, however, the…

Materials Science · Physics 2021-12-01 Leonardo Forcieri , Simon Taylor , Philip Moriarty , Samuel P Jarvis