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In this study we use non-equilibrium thermodynamics to systematically derive a phase-field model of a polyelectrolyte gel coupled to a hydrodynamic model for a salt solution surrounding the gel. The governing equations for the gel account…

Soft Condensed Matter · Physics 2022-03-02 Giulia L. Celora , Matthew G. Hennessy , Andreas Münch , Barbara Wagner , Sarah L. Waters

We study two-dimensional electron systems in the hydrodynamic regime. We show that a geometrical Berry curvature modifies the effective Navier-Stokes equation for viscous electron flow in topological materials. For small electric fields,…

Mesoscale and Nanoscale Physics · Physics 2021-03-10 Eddwi H. Hasdeo , Johan Ekström , Edvin G. Idrisov , Thomas L. Schmidt

We consider the hydrodynamic flow of an electron fluid in a channel formed in a two-dimensional electron gas (2DEG) with no-slip boundary conditions. To generate vorticity in the fluid the flow is influenced by an array of micromagnets on…

Mesoscale and Nanoscale Physics · Physics 2024-05-06 Jack N. Engdahl , Aydın Cem Keser , Thomas Schmidt , Oleg P. Sushkov

The construction of a generalized (higher-order) nonlinear thermo-hydrodynamics, based on a nonequilibrium ensemble formalism has been presented in the preceding article. The working of such theory is illustrated in the present one. We…

Statistical Mechanics · Physics 2007-05-23 J. Galvão Ramos , Áurea R. Vasconcellos , Roberto Luzzi

In nonlinear systems, small perturbations are conventionally attributed to negligible nonlinearity, justifying linear approximations. Here, we uncover a notable exception to this paradigm in an electrokinetic (EK) flow. Using a novel dual…

Fluid Dynamics · Physics 2026-04-16 Jin'an Pang , Guangyin Jing , Xiaoqiang Feng , Kaige Wang , Wei Zhao

Understanding the nature of solvated electrons is important in studying a range of chemical and biological phenomena. This study investigates the structural and dynamical behavior of an excess electron in water, examining different…

Computational Physics · Physics 2025-06-10 Ritama Kar , Nisanth N. Nair

In models of Pt 111 and Pt 100 surfaces in water, motions of molecules in the first hydration layer are spatially and temporally correlated. To interpret these collective motions, we apply quantitative measures of dynamic heterogeneity that…

Materials Science · Physics 2015-06-15 Adam P. Willard , David T. Limmer , Paul A. Madden , David Chandler

Nonlinear behavior of electro-osmosis in dilute non-adsorbing polymer solutions with low salinity is investigated with Brownian dynamics simulations and a kinetic theory. In the Brownian simulations, the hydrodynamic interaction between the…

Soft Condensed Matter · Physics 2015-06-19 Yuki Uematsu

We formulate and study computationally the low Mach number fluctuating hydrodynamic equations for electrolyte solutions. We are interested in studying transport in mixtures of charged species at the mesoscale, down to scales below the Debye…

This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

The non-exponential shape of the $\alpha$-process observed in supercooled liquids is considered as one of the hallmarks of glassy dynamics and has thus been under study for decades, but is still poorly understood. For a polar van der Waals…

Soft Condensed Matter · Physics 2020-08-05 Florian Pabst , Andreas Helbling , Jan Gabriel , Peter Weigl , Thomas Blochowicz

A small amplitude perturbation analysis is developed to describe the effect of a uniform electric field on the dynamics of a lipid bilayer vesicle in a simple shear flow. All media are treated as leaky dielectrics and fluid motion is…

Fluid Dynamics · Physics 2015-05-20 Jonathan T. Schwalbe , Petia M. Vlahovska , Michael J. Miksis

We regularize the potential distribution framework to calculate the excess free energy of liquid water simulated with the BLYP-D density functional. The calculated free energy is in fair agreement with experiments but the excess internal…

Chemical Physics · Physics 2015-05-19 Valéry Weber , D. Asthagiri

We present a general scheme to approach the space - time evolution of deformations, currents, and the electric field in charge density waves related to appearance of intrinsic topological defects: dislocations, their loops or pairs, and…

Strongly Correlated Electrons · Physics 2021-03-02 Serguei Brazovskii , Natasha Kirova

Applying an electric field to an aqueous colloidal dispersion establishes a complex interplay of forces among the highly mobile simple ions, the more highly charged but less mobile colloidal spheres, and the surrounding water. This…

Soft Condensed Matter · Physics 2007-05-23 Yilong Han , David G. Grier

This work presents an ab initio exploration of fundamental mechanisms with direct relevance to dendrite formation at lithium-electrolyte interfaces. Specifically, we explore surface diffusion barriers and solvated surface energies of…

Materials Science · Physics 2015-04-23 Yalcin Ozhabes , Deniz Gunceler , T. A. Arias

The interaction between two adjacent charged surfaces immersed in aqueous solution is known to be affected by charge regulation - the modulation of surface charge as two charged surfaces approach each other. This phenomenon is particularly…

Soft Condensed Matter · Physics 2022-07-26 Tal Obstbaum , Uri Sivan

Ethanol-water mixtures are a classic example of thermodynamic non-ideality, yet the structural origin of their pronounced anomalies, such as volume contraction and a large negative excess entropy, has remained a long-standing puzzle. Here,…

Soft Condensed Matter · Physics 2026-05-26 Xinyue Jiang , Yating Shang , Jianhui Li , Zhaoyong Zou , Yanxia Zuo , Yuqun Xie

Alternative approach for description of the non-equilibrium phenomena arising in solids at a severe external loading is analyzed. The approach is based on the new form of kinetic equations in terms of the internal and modified free energy.…

Statistical Mechanics · Physics 2014-08-27 L. S. Metlov

Electrohydrodynamic instabilities of fluid-fluid interfaces can be exploited in various microfluidic applications in order to enhance mixing, replicate well-controlled patterns or generate drops of a particular size. In this work, we study…

Fluid Dynamics · Physics 2021-06-29 Mohammadhossein Firouznia , David Saintillan
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