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In this work we theoretically study the differential capacitance of an aqueous electrolyte in contact with a planar electrode, using classical Density Functional Theory, and show how this measurable quantity can be used as a probe to better…

Soft Condensed Matter · Physics 2021-09-16 Peter Cats , René van Roij

In the present work, we study an electrolyte solution confined between planar surfaces with nonopatterned charged domains, which has been connected to a bulk ionic reservoir. The system is investigated through an improved Monte Carlo (MC)…

Soft Condensed Matter · Physics 2020-09-29 Amin Bakhshandeh , Maximiliano Segala , Thiago Colla

Electric-field-driven electrolyte transport through nanoporous membranes is important for applications including osmotic power generation, sensing and iontronics. We derive an analytical equation in the Debye--H\"uckel regime and a…

Soft Condensed Matter · Physics 2026-05-01 Holly C. M. Baldock , David M. Huang

In this paper, on the basis of the Onsager--Wilson theory of strong binary electrolyte solutions we completely work out the solutions of the governing equations (Onsager-Fuoss equations and Poisson equations) for nonequilibrium pair…

Chemical Physics · Physics 2012-07-06 Byung Chan Eu , Hui Xu , Kyunil Rah

We consider laminar flow of incompressible electrolytes in long, straight channels driven by pressure and electro-osmosis. We use a Hilbert space eigenfunction expansion to address the general problem of an arbitrary cross section and…

Fluid Dynamics · Physics 2007-05-23 N. A. Mortensen , L. H. Olesen , H. Bruus

A phenomenological theory of electric double layer polarization of blocking electrode is presented solving modified Debye-Falkenhagen (MDF) equation for potential, under the impedance boundary condition. The dynamic impedance and…

Materials Science · Physics 2011-03-04 Maibam Birla Singh , Rama Kant

We investigate the possibility that electrically neutral porous spheres electrophorese in electrolyte solutions with asymmetric affinity of ions to spheres on the basis of electrohydrodynamics and the Poisson-Boltzmann and…

Soft Condensed Matter · Physics 2015-06-23 Yuki Uematsu

Using molecular dynamics simulations with recently developed importance sampling methods, we show that the differential capacitance of a model ionic liquid based double-layer capacitor exhibits an anomalous dependence on the applied…

The electrohydrodynamics of vesicle suspensions is characterized by studying their pairwise interactions in applied DC electric fields in two dimensions. In the dilute limit, the rheology of the suspension is shown to vary nonlinearly with…

Soft Condensed Matter · Physics 2019-05-01 Bowei Wu , Shravan Veerapaneni

We investigate the dynamics of spin-nonequilibrium electron systems for the case when normal electron collisions prevail over the other scattering processes and the "hydrodynamic flow" regime is realized. The hydrodynamic equations for the…

Mesoscale and Nanoscale Physics · Physics 2011-09-12 R. N. Gurzhi , A. N. Kalinenko , A. I. Kopeliovich , P. V. Pyshkin , A. V. Yanovsky

The propagation of axisymmetric waves on the surface of a liquid jet under the action of a radial electric field is considered. The jet is assumed to be inviscid and perfectly conducting, and a field is set up by placing the jet…

Fluid Dynamics · Physics 2020-07-08 Qiming Wang , Demetrios T. Papageorgiou , Jean-Marc Vanden-Broeck

We present semi-classical and quantized hydrodynamic models to obtain the quadratic electronic response of a plane-bounded electron gas. Explicit expressions for the dynamic image potential experienced by charged particles moving near a…

Materials Science · Physics 2009-10-31 A. Bergara , J. M. Pitarke , R. H. Ritchie

We study the response of a model micro-electrochemical cell to a large ac voltage of frequency comparable to the inverse cell relaxation time. To bring out the basic physics, we consider the simplest possible model of a symmetric binary…

Fluid Dynamics · Physics 2013-12-12 Laurits H. Olesen , Martin Z. Bazant , Henrik Bruus

We develop an analytical theory to explain the experimentally-observed morphological transitions of giant vesicles induced by AC electric fields (1). The model treats the inner and suspending media as lossy dielectrics, while the membrane…

Biological Physics · Physics 2015-05-13 Petia Vlahovska , Ruben Serral Gracia , Said Aranda , Rumiana Dimova

We show that when particles are suspended in an electrolyte confined between corrugated charged surfaces, electrokinetic flows lead to a new set of phenomena such as particle separation, mixing for low-Reynolds micro- and nano-metric…

Soft Condensed Matter · Physics 2015-06-22 Paolo Malgaretti , Ignacio Pagonabarraga , J. Miguel Rubi

We investigate a system of dense polyelectrolytes in solution. The Langevin dynamics of the system with linearized hydrodynamics is formulated in the functional integral formalism and a transformation made to collective coordinates. Within…

Soft Condensed Matter · Physics 2015-06-25 Kristian K. M"uller-Nedebock , Thomas A. Vilgis

Delivering the full benefits of first principles calculations to battery materials demands the development of accurate and computationally-efficient electronic structure methods that incorporate the effects of the electrolyte environment…

Using molecular dynamics simulations, we reveal emergent properties of hydrated electrode interfaces that while molecular in origin are integral to the behavior of the system across long times scales and large length scales. Specifically,…

Materials Science · Physics 2015-05-20 David T. Limmer , Adam P. Willard

The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-H\"{u}ckel-Onsager theory to provide a detailed description of the electrical conductivity in strong electrolyte solutions. The theory…

Soft Condensed Matter · Physics 2024-09-27 N. N. Kalikin , Yu. A. Budkov

A recent experiment driving colloids electromagnetically, by B\'erut et al. [2014 Europhys. Lett. 107, 60004], is an ideal paradigm for illustrating a linear response theory for nonequilibrium overdamped systems including hydrodynamic…

Statistical Mechanics · Physics 2016-03-22 Cem Yolcu , Marco Baiesi