Related papers: Orbital Glass in FeCr2S4
Broadband dielectric spectroscopy has been performed on single-crystalline FeCr2S4 revealing a transition into a low-temperature orbital glass phase and on polycrystalline FeCr2S4 where long-range orbital order is established via a…
We report structural, susceptibility and specific heat studies of stoichiometric and off-stoichiometric poly- and single crystals of the A-site spinel compound FeSc2S4. In stoichiometric samples no long-range magnetic order is found down to…
The ferrimagnetic spinel $\mathrm{CoV_2O_4}$ has been a topic of intense recent interest, both as a frustrated insulator with unquenched orbital degeneracy and as a near-itinerant magnet which can be driven metallic with moderate applied…
We report on a thorough dielectric investigation of the glass-like freezing of the orbital reorientation-dynamics, recently found for the crystalline sulpho-spinels FeCr2S4 and FeSc2S4. As the orbital reorientations are coupled to a…
We explore orbital dynamics in the spin liquid candidate Ba3CuSb2O9 using multi-frequency electron spin resonance. We prepared two high quality single crystals. The crystal with a slight copper deficiency shows a structural phase transition…
CuAl2O4 is a normal spinel oxide having quantum spin, S=1/2 for Cu2+. It is a rather unique feature that the Cu2+ ions of CuAl2O4 sit at a tetrahedral position, not like the usual octahedral position for many oxides. At low temperatures, it…
Crystal structure, magnetic susceptibility, and specific heat were measured in the normal cubic spinel compounds MnSc_2S_4 and FeSc_2S_4. Down to the lowest temperatures, both compounds remain cubic and reveal strong magnetic frustration.…
We present neutron scattering measurements on powder samples of the spinel FeSc2S4 that reveal a previously unobserved magnetic ordering transition occurring at 11.8(2)~K. Magnetic ordering occurs subsequent to a subtle cubic-to-tetragonal…
In FeSc2S4 spin-orbital exchange competes with strong spin-orbit coupling, suppressing long-range spin and orbital order and, hence, this material represents one of the rare examples of a spin-orbital liquid ground state. Moreover, it is…
Despite possessing a local spin $2$ moment on the iron site and a Curie-Weiss temperature of $45K$, the A site spinel FeSc$_2$S$_4$ does not magnetically order down to 50mK. Previous theoretical work by Chen and Balents advanced an…
Strain, magnetization, and unpolarized and polarized neutron diffraction measurements were performed to study the magnetic and structural properties of spinel CoV$_{2}$O$_{4}$. Magnetostriction measurements indicate that a subtle distortion…
The cubic spinel FeCr2S4 has been receiving immense research interest because of its emergent phases and the interplay of spin, orbital and lattice degrees of freedom. Despite the intense research, several fundamental questions are yet to…
The recent discovery of a local fluctuating t2g orbital-degeneracy-lifted (ODL) state in CuIr2S4 as a high temperature precursor to the metal-insulator transition (MIT) opens the door to a possible widespread presence of precursor states in…
Motivated by recent experiments, we present a comprehensive theoretical study of the geometrically frustrated strongly correlated magnetic insulator Mn$_3$O$_4$ spinel oxide based on a microscopic Hamiltonian involving lattice, spin and…
Glass states of superfluid A-like phase of 3He in aerogel induced by random orientations of aerogel strands are investigated theoretically and experimentally. In anisotropic aerogel with stretching deformation two glass phases are observed.…
We report on neutron diffraction, thermal expansion, magnetostriction, dielectric, and specific heat measurements on polycrystalline FeCr2S4 in external magnetic fields. The ferrimagnetic ordering temperatures $T_{\mathrm{C}}\approx 170$ K…
We present a neutron diffraction study of FeV2O4, which is rare in exhibiting spin and orbital degrees of freedom on both cation sublattices of the spinel structure. Our data confirm the existence of three structural phase transitions…
At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$…
The lacunar spinel GeV4S8 undergoes orbital and ferroelectric ordering at the Jahn-Teller transition around 30 K and exhibits antiferromagnetic order below about 14 K. In addition to this orbitally driven ferroelectricity, lacunar spinels…
Using density-functional theory calculations and experimental investigations on structural, magnetic and dielectric properties, we have elucidated a unique tetragonal ground state for MnTi2O4, a Ti^{3+} (3d^1)-ion containing spinel-oxide.…