English

Orbital and spin ordering physics of the Mn$_3$O$_4$ spinel

Strongly Correlated Electrons 2017-08-23 v1 Materials Science

Abstract

Motivated by recent experiments, we present a comprehensive theoretical study of the geometrically frustrated strongly correlated magnetic insulator Mn3_3O4_4 spinel oxide based on a microscopic Hamiltonian involving lattice, spin and orbital degrees of freedom. Possessing the physics of degenerate eg_g orbitals, this system shows a strong Jahn-Teller effect at high temperatures. Further, careful attention is paid to the special nature of the superexchange physics arising from the 90o^o Mn-O-Mn bonding angle. The Jahn-Teller and superexchange-based orbital-spin Hamiltonians are then analysed in order to track the dynamics of orbital and spin ordering. We find that a high-temperature structural transition results in orbital ordering whose nature is mixed with respect to the two originally degenerate ege_{g} orbitals. This ordering of orbitals is shown to relieve the intrinsic geometric frustration of the spins on the spinel lattice, leading to ferrimagnetic Yafet-Kittel ordering at low-temperatures. Finally, we develop a model for a magnetoelastic coupling in Mn3_3O4_4, enabling a systematic understanding of the experimentally observed complexity in the low-temperature structural and magnetic phenomenology of this spinel. Our analysis predicts that a quantum fluctuation-driven orbital-spin liquid phase may be stabilised at low temperatures upon the application of pressure.

Keywords

Cite

@article{arxiv.1704.06026,
  title  = {Orbital and spin ordering physics of the Mn$_3$O$_4$ spinel},
  author = {Santanu Pal and Siddhartha Lal},
  journal= {arXiv preprint arXiv:1704.06026},
  year   = {2017}
}

Comments

11 pages, 8 figures