English

Spin--orbital physics in transition metal oxides

Strongly Correlated Electrons 2022-01-25 v1

Abstract

We present the main features of the spin-orbital superexchange which describes the magnetic and optical properties of Mott insulators with orbital degrees of freedom. In contrast to the SU(2) symmetry of spin superexchange, the orbital part of the superexchange obeys the lower cubic symmetry of the lattice and is intrinsically frustrated. This intrinsic frustration and spin-orbital entanglement induce enhanced quantum fluctuations, and we point out a few situations where this leads to disordered states. Strong coupling between the spin and orbital degrees of freedom is discussed on the example of the RRVO3_3 perovskites, with RR standing for rare-earth ion, La,...,Lu. We explain the observed evolution of the orbital TOOT_{\rm OO} and N\'eel TN1T_{N1} transition temperature in the RRVO3_3 series with decreasing ionic radius rRr_R. A few open problems and the current directions of research in the field of spin-orbital physics are pointed out.

Keywords

Cite

@article{arxiv.0904.1297,
  title  = {Spin--orbital physics in transition metal oxides},
  author = {Andrzej M. Oles},
  journal= {arXiv preprint arXiv:0904.1297},
  year   = {2022}
}

Comments

19 pages, 5 figures

R2 v1 2026-06-21T12:49:23.355Z