Related papers: The influence of droplet size on line tension
The effects of line tension on the morphology of a sessile droplet placed on top of a convex spherical substrate are studied. The morphology of the droplet is determined from the global minimum of the Helmholtz free energy. The contact…
The size-dependent contact angle and the drying and wetting morphological transition are studied with respect to the volume change for a spherical cap-shaped droplet placed on a spherical substrate. The line-tension effect is included using…
The size dependence of the equilibrium droplet contact angle is governed by line tension. In this work, we identify a contribution to line tension arising from gravitational effects and pressure-induced changes in volume-fraction-dependent…
Using an interface displacement model we calculate the shapes of nanometer-size liquid droplets on homogeneous cylindrical surfaces. We determine effective contact angles and line tensions, the latter defined as excess free energies per…
The effects of line tension on the morphology of a lens-shaped droplet and bubble placed on the inner wall of a spherical cavity are studied. The contact angle between the lens-shaped droplet and the concave spherical substrate is expressed…
The interfacial tension of a liquid droplet surrounded by another liquid in the presence of microscopic ions is studied as a function of the droplet radius. An analytical expression for the interfacial tension is obtained within a linear…
Results from Monte Carlo simulations of wall-attached droplets in the three-dimensional Ising lattice gas model and in a symmetric binary Lennard-Jones fluid, confined by antisymmetric walls, are analyzed, with the aim to estimate the…
We perform a thermodynamic analysis of various contributions to the size dependence of the contact-angle cosine for both axisymmetric and cylindrical sessile droplets. This shows that a commonly used method to determine the line tension…
Adsorption of liquid on a planar wall decorated by a hydrophilic stripe of width $L$ is considered. Under the condition, that the wall is only partially wet (or dry) while the stripe tends to be wet completely, a liquid drop is formed above…
Line tension in wetting processes is of high scientific and technological relevance, but its understanding remains vague, mainly because of its difficult determination. A widely used method to extract the line tension relies on the…
We present a molecular dynamics study of the motion of cylindrical polymer droplets on striped surfaces. We first consider the equilibrium properties of droplets on different surfaces, we show that for small stripes the Cassie-Baxter…
The contact line (CL) is where solid, liquid and vapor phases meet, and Young's equation describes the macroscopic force balance of the interfacial tensions between these three phases. These interfacial tensions are related to the nanoscale…
We study the adsorption of a fluid in the grand canonical ensemble occurring at a planar heterogeneous wall which is decorated with a chemical stripe of width $L$. We suppose that the material of the stripe strongly preferentially adsorbs…
One of the long standing challenges in molecular simulation is the description of interfaces. On the molecular length scale, finite size effects significantly influence the properties of the interface such as its interfacial tension, which…
We study adsorption of liquid at a one-dimensional substrate composed of a single chemical inhomogeneity of width $2L$ placed on an otherwise homogeneous, planar, solid surface. The excess point free energy $\eta (L,T)$ associated with the…
The impact of a heavier droplet into a deep pool of lighter liquid is investigated using three-dimensional numerical simulations. Unprecedented to any numerical simulations, we demonstrate that the heavier droplets can hang from the surface…
We consider the equilibrium of liquid droplets sitting on thin elastic sheets that are subject to a boundary tension and/or are clamped at their edge. We use scaling arguments, together with a detailed analysis based on the…
We report on the size dependence of the surface tension of a free surface of an isotropic fluid. The size dependence of the surface tension is evaluated based on the Gibbs-Tolman-Koenig-Buff equation for positive and negative values of…
We study the flow close to an advancing contact line in the limit of small capillary number. To take into account wetting effects, both long and short-ranged contributions to the disjoining pressure are taken into account. In front of the…
A stress-induced stripe phase of submonolayer Pd on W(110) is observed by low-energy electron microscopy. The temperature dependence of the pattern is explained by the change both in the boundary free energy and elastic relaxation energy…