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The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. Schinabeck , R. Härtle , H. B. Weber , M. Thoss

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 R. Härtle , M. Butzin , M. Thoss

Vibrationally inelastic electron transport through a flexible molecular junction is investigated. The study is based on a mechanistic model for a biphenyl molecule between two metal electrodes. Employing methods from electron-molecule…

Mesoscale and Nanoscale Physics · Physics 2023-07-26 Martin Cizek , Michael Thoss , Wolfgang Domcke

Nanoscale molecular-electronic devices and machines are emerging as promising functional elements, naturally flexible and efficient, for next generation technologies. A deeper understanding of carrier dynamics in molecular junctions is…

Mesoscale and Nanoscale Physics · Physics 2018-04-04 K. Beltako , F. Michelini , N. Cavassilas , L. Raymond

We present first-principles calculations of the dI/dV characteristics of an H2 molecule sandwiched between Au and Pt electrodes in the presence of electron-phonon interactions. The conductance is found to decrease by a few percentage at…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 I. S. Kristensen , M. Paulsson , K. S. Thygesen , K. W. Jacobsen

We study inelastic vibration-assisted charge transfer effects in two-site molecular junctions, focusing on signatures of vibrational anharmonicity on the electrical characteristics and the thermoelectric response of the junction. We…

Statistical Mechanics · Physics 2017-12-27 Hava Meira Friedman , Bijay Kumar Agarwalla , Dvira Segal

We induce superconductivity by proximity effect in thin layers of gold and study the number of conduction channels which contribute to the current in one-atom contacts and atomic wires. The atomic contacts and wires are fabricated with a…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 G. Rubio-Bollinger , C. de las Heras , E. Bascones , N. Agrait , F. Guinea , S. Vieira

We theoretically study the current-voltage relation, $I-V$ characteristic, of the photovoltaics due to the shift current, i.e., the photocurrent generated ${\it without}$ the external dc electric field in noncentrosymmetric crystals through…

Mesoscale and Nanoscale Physics · Physics 2019-01-01 Takahiro Morimoto , Masao Nakamura , Masashi Kawasaki , Naoto Nagaosa

Understanding the formation of metal-molecule contact at the microscopic level is the key towards controlling and manipulating atomic scale devices. Employing two isomers of bipyridine, $4, 4^\prime$ bipyridine and $2, 2^\prime$ bipyridine…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Biswajit Pabi , Debayan Mondal , Priya Mahadevan , Atindra Nath Pal

It was recently predicted [Phys. Rev. B 75, 193301 (2007)] that spin blockade may develop at nonmagnetic semiconductor/perfect ferromagnet junctions when the electron flow is directed from the semiconductor into the ferromagnet. Here we…

Mesoscale and Nanoscale Physics · Physics 2008-03-23 Yu. V. Pershin , M. Di Ventra

Transport properties of metal-molecule-metal junctions containing monolayer of conjugated and saturated molecules with characteristic dimensions in the range of 30-300 nm are correlated with microscopic topography, stress and chemical…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Nikolai B. Zhitenev , Weirong Jiang , Artur Erbe , Zhenan Bao , Eric Garfunkel , Donald M. Tennant , Raymond A. Cirelli

In this article we present a novel semi-analytical approach to calculate first-order electron-vibration coupling constants within the framework of density functional theory. It combines analytical expressions for the first-order derivative…

Mesoscale and Nanoscale Physics · Physics 2013-11-12 Marius Bürkle , Janne K. Viljas , Thomas J. Hellmuth , Elke Scheer , Florian Weigend , Gerd Schön , Fabian Pauly

We investigate the effect on molecular transport due to the different structural aspects of metal-molecule interfaces. The example system chosen is the prototypical molecular device formed by sandwiching the phenyl dithiolate molecule (PDT)…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark Ratner

We demonstrate large rectification ratios (> 100) in single-molecule junctions based on a metal-oxide cluster (polyoxometalate), using a scanning tunneling microscope (STM) both at ambient conditions and at low temperature. These…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Siya Sherif , G Rubio-Bollinger , E. Pinilla-Cienfuegos , E. Coronado , J. C. Cuevas , Nicolas Agrait

Starting from the quasiclassical equations for non-equilibrium Green's functions we derive a simple kinetic equation that governs ac Josephson effect in a superconducting quantum point contact at small bias voltages. In contrast to existing…

Condensed Matter · Physics 2009-10-28 D. Averin , A. Bardas

We present a numerically exact study of charge transport and its fluctuations through a molecular junction driven out of equilibrium by a bias voltage, using the Inchworm quantum Monte Carlo (iQMC) method. After showing how the technique…

Chemical Physics · Physics 2019-06-27 Michael Ridley , Emanuel Gull , Guy Cohen

We propose a model for a molecular junction with internal anharmonic torsional vibrations interacting with an electric current. The Wangsness-Bloch-Redfield master equation approach is used to determine the stationary reduced density matrix…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ivan A. Pshenichnyuk , Martin Čížek

Spectral weights and current-voltage characteristics of an artificial diatomic molecule are calculated, considering cases where the dots connected in series are in general different. The spectral weights allow us to understand the effects…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 F. Ramirez , E. Cota , S. E. Ulloa

The influence of the charging effects on the transport characteristics of a molecular wire bridging two metallic electrodes in the limit of weak contacts is studied by generalized Breit-Wigner formula. Molecule is modeled as a quantum dot…

Chemical Physics · Physics 2009-11-10 Kamil Walczak

Understanding electrical characteristics and corresponding transport models at single molecular junctions is crucial. There have been many reports on organic compounds-based single molecular junctions. However, organometallic…

Materials Science · Physics 2024-09-04 Rajwinder Kaur , Savas Kaya , Konstantin P. Katin , Prakash Chandra Mondal