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We discuss the factors that determine the overall shape and magnitude of the current-voltage (I-V) characteristics of a variety of molecular conductors sandwiched between two metallic contacts. We analyze the individual influences of the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 A. W. Ghosh , S. Datta

In recent years, several experimental groups have reported measurements of the current-voltage (I-V) characteristics of individual or small numbers of molecules. Our purpose in this chapter is to provide an intuitive explanation for the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Magnus Paulsson , Ferdows Zahid , Supriyo Datta

In the present work, the current-voltage (I-V) characteristics in a coupled long Josephson junction based on magnesium diboride are studied by establishing a system of equations of phase differences of various inter- and intra-band channels…

Soft Condensed Matter · Physics 2021-03-30 S. P. Chimouriya , B. R. Ghimire , J. H. Kim

We investigate the origin of asymmetry in various measured current-voltage (I-V) characteristics of molecules with no inherent spatial asymmetry, with particular focus on a recent break junction measurement. We argue that such asymmetry…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 F. Zahid , A. W. Ghosh , M. Paulsson , E. Polizzi , S. Datta

We identify experimental signatures in the current-voltage (I-V) characteristics of weakly contacted molecules directly arising from excitations in their many electron spectrum. The current is calculated using a multielectron master…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 B. Muralidharan , A. W. Ghosh , S. Datta

We present current-voltage (I-V) curves computed using all-electron basis sets on the conducting molecule. The all-electron results are very similar to previous results obtained using effective core potentials (ECP). A hybrid integration…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Charles W. Bauschlicher, , John W. Lawson

We develop a theory of current-voltage (I-U) characteristics for superconductor-normal metal-superconductor (SNS) junctions. At small voltages and sufficiently low temperatures the I-U characteristics of the junction is controlled by the…

Superconductivity · Physics 2022-12-13 T. Liu , A. V. Andreev , B. Z. Spivak

We investigate the origin of asymmetry in the measured current-voltage (I-V) characteristics of molecules with no inherent spatial asymmetry. We establish that such molecules can exhibit asymmetric I-V characteristics due to unequal…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Avik W. Ghosh , Ferdows Zahid , Prashant S. Damle , Supriyo Datta

Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 C. Kergueris , J. -P. Bourgoin , S. Palacin , D. Esteve , C. Urbina , M. Magoga , C. Joachim

By use of the multi-Josephson junction model, we investigate voltage-biased I-V characteristics. Differently from the case of the single junction, I-V characteristics show a complicated behavior due to inter-layer couplings among…

Superconductivity · Physics 2009-10-31 S. Sakamoto , H. Matsumoto , T. Koyama , M. Machida

Extensive studies on thin films indicated a generic cubic current-voltage $I-V$ dependence as a salient feature of charge transport by tunneling. A quick glance at $I-V$ data for molecular junctions suggests a qualitatively similar…

Chemical Physics · Physics 2015-09-21 Ioan Baldea

The evolution of electron conductance in the presence of inelastic effects is studied as an atomic gold contact is formed evolving from a low-conductance regime (tunneling) to a high-conductance regime (contact). In order to characterize…

Mesoscale and Nanoscale Physics · Physics 2007-06-25 Thomas Frederiksen , Nicolas Lorente , Magnus Paulsson , Mads Brandbyge

The nonlinearities of current-voltage characteristics (IVC) of superconducting niobium point contacts for voltages of the order of the characteristic phonon frequencies are investigated. It is shown that in limiting by dirty contacts…

Superconductivity · Physics 2016-04-28 I. K. Yanson , N. L. Bobrov , L. F. Rybal'chenko , V. V. Fisun

We calculate non-perturbatively the inelastic effects on the conductance through a conjugated molecular wire-metal heterojunction, including realistic electron-phonon coupling. We show that at sub-band-gap energies the current is dominated…

Materials Science · Physics 2009-10-31 H. Ness , A. J. Fisher

The proposed protocol is an attempt to meet the experimentalists' legitimate desire of reliably and easily extracting microscopic parameters from current-voltage measurements on molecular junctions. It applies to junctions wherein charge…

Mesoscale and Nanoscale Physics · Physics 2024-02-27 Ioan Baldea

We develop a theory of nonreciprocal current-voltage (I-U) characteristics in noncentrosymmetric superconductor-normal metal-superconductor junctions. We show that at small voltages the nonreciprocal features of the I-U characteristics can…

Superconductivity · Physics 2023-09-12 T. Liu , M. Smith , A. V. Andreev , B. Z. Spivak

We describe a first-principles method for calculating electronic structure, vibrational modes and frequencies, electron-phonon couplings, and inelastic electron transport properties of an atomic-scale device bridging two metallic contacts…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Thomas Frederiksen , Magnus Paulsson , Mads Brandbyge , Antti-Pekka Jauho

In a recent Letter [Appl. Phys. Lett. 87, 103104 (2005)], Yoshida et al. report that nonlinearities in current-voltage curves of gold quantum point contacts occur as a result of a shortening of the distance between electrodes at finite…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 J. Bürki , C. A. Stafford , D. L. Stein

The effect of electron-phonon coupling on the current noise in a molecular junction is investigated within a simple model. The model comprises a 1-level bridge representing a molecular level that connects between two free electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan , Mark A. Ratner

Electronic transport properties of Au nano-structure are investigated using both experimental and theoretical analysis. Experimentally, stable Au nanowires were created using mechanically controllable break junction in air, and simultaneous…

Computational Physics · Physics 2009-11-07 H. Mehrez , Alex Wlasenko , Brian Larade , Jeremy Taylor , Peter Grutter , Hong Guo
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