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Related papers: Dual structures in PZN-xPT ferroelectric relaxors

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PbZrxTi1-xO3 (PZT) is one of the technologically most important ferroelectric materials. Bulk single-domain single crystals of PZT have never been synthesized for a significant compositional range across the solid-solution phase diagram.…

Materials Science · Physics 2007-05-23 Ionela Vrejoiu , Gwenael Le Rhun , Lucian Pintilie , Dietrich Hesse , Marin Alexe , Ulrich Goesele

Artificial PbTiO$_{3}$/SrTiO$_{3}$ superlattices were constructed using off-axis RF magnetron sputtering. X-ray diffraction and piezoelectric atomic force microscopy were used to study the evolution of the ferroelectric polarization as the…

Materials Science · Physics 2009-11-11 M. Dawber , C. Lichtensteiger , M. Cantoni , M. Veithen , P. Ghosez , K. Johnston , K. M. Rabe , J. -M. Triscone

In this review we address some of the experimental challenges found in the x-ray diffraction characterization of the low-symmetry phases recently discovered in the PZT, PZN-PT and PMN-PT piezoelectric systems around their morphotropic phase…

Materials Science · Physics 2007-05-23 B. Noheda , D. E. Cox , G. Shirane

Theoretical {\em ab initio} and experimental methods were used to investigate the $x$Bi(Zn,Ti)O$_3$-(1-$x$)PbTiO$_3$ (BZT-PT) solid solution. We find that hybridization between Zn 4$p$ and O 2$p$ orbitals allows the formation of short,…

We present here the comprehensive X-ray diffraction (XRD) and dielectric measurement of (1-x)Bi(Zn1/2Ti1/2)O3-xPbTiO3 (BZT-xPT) piezoceramics with x=0.65, 0.70, 0.75 and 0.80. Powder X-ray diffraction data reveals the tetragonal structure…

Materials Science · Physics 2013-11-19 Jyoti Sharma , Rishikesh Pandey , Akhilesh Kumar Singh

Introducing structural and/or chemical heterogeneity into otherwise ordered crystals can dramatically alter material properties. Lead-based relaxor ferroelectrics are a prototypical example, with decades of investigation having connected…

We investigate the low temperature behaviour of Pb(In$_{1/2}$Nb$_{1/2}$)O$_{3}$-Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-PbTiO$_{3}$ using dielectric permittivity measurements. We compare single crystal plates measured in the [001] and [111]…

Materials Science · Physics 2018-02-19 Philippa M. Shepley , Laura A. Stoica , Yang Li , Gavin Burnell , Andrew J. Bell

The issues related to the structure refinement of Pb(ZrxTi1-x)O3 (PZT) solid solutions are discussed. Particular attention is paid on the modelling of the co-existing phases in the vicinity of the morphotropic phase boundary (MPB), where…

Materials Science · Physics 2007-05-23 Johannes Frantti

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very…

We have fabricated n-layer graphene field effect transistors on epitaxial ferroelectric Pb(Zr_0.2Ti_0.8)O_3 (PZT) thin films. At low gate voltages, PZT behaves as a high-k dielectric with k up to 100. An unusual resistance hysteresis occurs…

Mesoscale and Nanoscale Physics · Physics 2010-07-28 X. Hong , J. Hoffman , A. Posadas , K. Zou , C. H. Ahn , J. Zhu

High pressure x-ray diffraction (XRD) measurements on RMnO3 (R=Dy, Ho and Lu) reveals that varying structural changes occurs for different R ions. Large lattice changes (orthorhombic strain) occur in DyMnO3 and HoMnO3 while the Jahn-Teller…

Strongly Correlated Electrons · Physics 2014-04-01 T. Wu , T. A. Tyson , H. Chen , P. Gao , T. Yu , Z. Chen , Z. Liu , K. H. Ahn , X. Wang , S. -W. Cheong

Broadband dielectric spectroscopy from Hz up to the infrared (IR) range and temperature interval 10-300 K was carried out for xBaZrO3-(1-x)BaTiO3 (BZT-x, x = 0.6, 0.7, 0.8) solid solution ceramics and compared with similar studies for x =…

Materials Science · Physics 2013-12-12 J. Petzelt , D. Nuzhnyy , M. Savinov , V. Bovtun , M. Kempa , T. Ostapchuk , J. Hlinka , G. Canu , V. Buscaglia

We have carried out the powder x-ray diffraction and dielectric studies on multiferroic particulate composite xNi0.9Zn0.1Fe2O4/(1-x)PbZr0.52Ti0.48O3 with x=0.15, 0.30, 0.45, 0.60, 0.75 and 0.90 to explore the structural and ferroelectric…

Materials Science · Physics 2014-02-20 Rishikesh Pandey , Braj Raj Meena , Akhilesh Kumar Singh

Ferroelectric and dielectric properties of polydomain (twinned) single-crystal Pb(Zr1-xTix)O3 thin films are described with the aid of a nonlinear thermodynamic theory, which has been developed recently for epitaxial ferroelectric films…

Materials Science · Physics 2009-11-10 V. G. Kukhar , N. A. Pertsev , H. Kohlstedt , R. Waser

We have investigated the out-of-plane lattice relaxation related to the ferroelectric transitions in epitaxial BaTiO$_3$ (BTO) films using synchrotron X-ray diffraction. Under either compressive strain or tensile strain, there is evidence…

Materials Science · Physics 2007-05-23 Feizhou He , Barrett O. Wells

Dielectric, anelastic and ^139La NMR relaxation measurements have been made on the relaxor ferroelectric Pb(1-3x/2)La(x)Zr(0.2)Ti(0.8)O(3) (PLZT) with x = 0.22. The dielectric susceptibility exihibits the frequency dispersive maximum due to…

Materials Science · Physics 2010-07-23 F. Cordero , M. Corti , F. Craciun , C. Galassi , D. Piazza , F. Tabak

The synthesis and structural analysis of Mo/B periodical multilayer X-ray mirrors (PMMs) for beyond extreme ultraviolet (BEUV) optics was performed. The PMMs were deposited by a combination of pulsed DC and radio frequency (RF) magnetron…

Applied Physics · Physics 2020-11-13 Oleksiy V. Penkov , Igor A. Kopylets , Valeriy V. Kondratenko , Mahdi Khadem

High energy resolution neutron spin-echo spectroscopy has been used to measure intrinsic width of diffuse scattering discovered earlier in relaxor ferroelectric crystals. The anisotropic and transverse components of the scattering have been…

Materials Science · Physics 2017-09-13 Sergey Vakhrushev , Alexandre Ivanov , Jiri Kulda

Ab initio phonon calculations for the nonpolar reference structures of the (001), (110), and (111) PbZrO_3/PbTiO_3 [1:1] superlattices are presented. The unstable polar modes in the tetragonal (001) and (110) structures are confined in…

Materials Science · Physics 2009-11-07 Claudia Bungaro , K. M. Rabe

X-ray analysis of ferroelectric thin layers of Ba1/2Sr1/2TiO3 with different thickness reveals the presence of internal strain gradients across the film thickness and allows us to propose a functional form for the internal strain profile.…

Materials Science · Physics 2009-11-10 G. Catalan , B. Noheda , J. McAneney , L. Sinnamon , J. M. Gregg