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A general nonequilibrium thermodynamic theory is developed for time-dependent Langevin dynamics, starting from the common definition of nonequilibrium Gibbs entropy. It is shown that the notations appearing in the First and the Second Law…

Statistical Mechanics · Physics 2009-04-15 Hao Ge

The definitions of the temperature in the nonextensive statistical thermodynamics based on Tsallis entropy are analyzed. A definition of pressure is proposed for nonadditive systems by using a nonadditive effective volume. The…

Data Analysis, Statistics and Probability · Physics 2009-11-10 Qiuping A. Wang , Laurent Nivanen , Alain Le Mehaute , Michel Pezeril

Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · Physics 2008-02-03 J. Kumicak , X. de Hemptinne

The microscopic foundation of the generalized equilibrium statistical mechanics based on the Tsallis entropy is given by using the Gibbs idea of statistical ensembles of the classical and quantum mechanics. The equilibrium distribution…

Statistical Mechanics · Physics 2007-05-23 A. S. Parvan

We consider nonequilibrium systems with complex dynamics in stationary states with large fluctuations of intensive quantities (e.g. the temperature, chemical potential, or energy dissipation) on long time scales. Depending on the…

Statistical Mechanics · Physics 2009-11-07 C. Beck , E. G. D. Cohen

The statistical mechanics of a cloud of particles interacting via their gravitational potentials is an old problem which encounters some issues when the traditional Boltzmann-Gibbs statistics is applied. In this article, we consider the…

Statistical Mechanics · Physics 2018-04-10 Lenin Escamilla-Herrera , Christine Gruber , Viridiana Pineda , Hernando Quevedo

We study the one-dimensional Ising model with long-range interactions in the context of Tsallis non-extensive statistics by computing numerically the number of states with a given energy. We find that the internal energy, magnetization,…

Statistical Mechanics · Physics 2016-08-31 R. Salazar , R. Toral

We show how to construct non-equilibrium thermodynamics for systems too small to be considered thermodynamically in a traditional sense. Through the use of a non-equilibrium ensemble of many replicas of the system which can be viewed as a…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi , D. Bedeaux , S. Kjelstrup

Alternative definitions are given of basic concepts of generalized thermostatistics. In particular, generalizations of Shannon's entropy, of the Boltzmann-Gibbs distribution, and of relative entropy are considered. Particular choices made…

Statistical Mechanics · Physics 2007-05-23 Jan Naudts

There is a conception that Boltzmann-Gibbs statistics cannot yield the long tail distribution. This is the justification for the intensive research of nonextensive entropies (i.e. Tsallis entropy and others). Here the error that caused this…

Information Theory · Computer Science 2009-06-30 Oded Kafri

We derive analogues of the Jarzynski equality and Crooks relation to characterise the nonequilibrium work associated with changes in the spring constant of an overdamped oscillator in a quadratically varying spatial temperature profile. The…

Statistical Mechanics · Physics 2015-09-30 Ian J. Ford , Robert W. Eyre

In the present paper are considered the self-similarity scaling postulates in order to extend the Thermodynamics to the study of one special class of nonextensive systems: the pseudoextensive, those with exponential behavior for the…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez , F. Guzman

Starting from microscopic mechanics, we derive thermodynamic relations for heat conducting nonequilibrium steady states. The extended Clausius relation enables one to experimentally determine nonequilibrium entropy to the second order in…

Statistical Mechanics · Physics 2009-11-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

We show that finite systems whose Hamiltonians obey a generalized homogeneity relation rigorously follow the nonextensive thermostatistics of Tsallis. In the thermodynamical limit, however, our results indicate that the Boltzmann-Gibbs…

Statistical Mechanics · Physics 2016-08-31 Artur B. Adib , Andre A. Moreira , Jose S. Andrade , Murilo P. Almeida

The problem of temperature in nonextensive statistical mechanics is studied. Considering the first law of thermodynamics and a "quasi-reversible process", it is shown that the Tsallis entropy becomes the Clausius entropy if the inverse of…

Statistical Mechanics · Physics 2009-11-11 Sumiyoshi Abe

In this paper, we extend Gibbs's approach of quasi-equilibrium thermodynamic processes, and calculate the microscopic expression of entropy for general non-equilibrium thermodynamic processes. Also, we analyze the formal structure of…

Statistical Mechanics · Physics 2025-12-23 Jun Chul Park

Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi

With the help of a general expression of the entropies in extensive and nonextensive systems, some important relations between thermodynamics and statistical mechanics are revealed through the views of thermodynamics and statistic physics.…

Statistical Mechanics · Physics 2009-11-13 Zhifu Huang , Congjie Ou , A. Le Mehaute , Qiuping A. Wang , Jincan Chen

The generalized Gibbs-Duhem equation is obtained for systems with long-range interactions in $d$ spatial dimensions. We consider that particles in the system interact through a slowly decaying pair potential of the form $1/r^\nu$ with…

Statistical Mechanics · Physics 2013-11-18 Ivan Latella , Agustín Pérez-Madrid

A previous analysis of scaling, bounds, and inequalities for the non-interacting functionals of thermal density functional theory is extended to the full interacting functionals. The results are obtained from analysis of the related…

Statistical Mechanics · Physics 2016-12-14 James W. Dufty , S. B. Trickey