Generalization of Gibbs Entropy and Thermodynamic Relation
Statistical Mechanics
2025-12-23 v16
Abstract
In this paper, we extend Gibbs's approach of quasi-equilibrium thermodynamic processes, and calculate the microscopic expression of entropy for general non-equilibrium thermodynamic processes. Also, we analyze the formal structure of thermodynamic relation in non-equilibrium thermodynamic processes.
Cite
@article{arxiv.1007.3684,
title = {Generalization of Gibbs Entropy and Thermodynamic Relation},
author = {Jun Chul Park},
journal= {arXiv preprint arXiv:1007.3684},
year = {2025}
}
Comments
Typographical errors in equation (28), (29) and (30) are corrected