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Results of magnetization and neutron diffraction measurements of the manganese vanadate system Mn$_5$(VO$_4$)$_2$(OH)$_4$ are reported. The crystal structure of this compound contains triangular [Mn$_3$O$_{13}$] building blocks that produce…

Strongly Correlated Electrons · Physics 2018-09-07 V. O. Garlea , M. A. McGuire , L. D. Sanjeewa , D. M. Pajerowski , F. Ye , J. W. Kolis

Van der Waals magnet VI$_3$ demonstrates intriguing magnetic properties that render it great for use in various applications. However, its microscopic magnetic structure has not been determined yet. Here, we report neutron diffraction and…

Strongly Correlated Electrons · Physics 2021-08-19 Yiqing Hao , Yiqing Gu , Yimeng Gu , Erxi Feng , Huibo Cao , Songxue Chi , Hua Wu , Jun Zhao

The metal-insulator transition of the Magneli phase Ti4O7 is studied by means of augmented spherical wave (ASW) electronic structure calculations as based on density functional theory and the local density approximation. The results show…

Strongly Correlated Electrons · Physics 2009-11-10 V. Eyert , U. Schwingenschloegl , U. Eckern

In the search for new spin textures based on singular magnetic objects like Bloch-points or vortices, spinel compounds emerge as an interesting playground due to the interplay between magnetic anisotropy and complex interactions that extend…

Strongly Correlated Electrons · Physics 2026-05-20 K. Beauvois , J. Robert , M. Songvilay , J. Ollivier , B. Fåk , E. Ressouche , N. Qureshi , R. Ballou , S. Petit , S. Lenne , P. Manuel , S. DeBrion , P. Strobel , V. Simonet

Spinel Li$_x$Mn$_2$O$_4$ is a key cathode material that is used extensively in commercial Li-ion batteries. A challenge with this material has been that the capacity of the battery fades with cycling, an effect that can be traced to the…

Motivated by recent interest in quasi-one-dimensional compound CaV2O4, we study the ground states of a spin-orbital chain characterized by an Ising-like orbital Hamiltonian and frustrated interactions between S=1 spins. The on-site…

Strongly Correlated Electrons · Physics 2010-07-13 Gia-Wei Chern , Natalia Perkins

Recent years have seen a vast increase in research into van der Waals magnetic materials. In many of these systems, magnetism is introduced via light 3\textit{d}-transition metal elements, combined with chalcogenides or halogens. Despite…

The electronic structure and magnetism in the sodium nickelate NaNiO_2 in the low-temperature phase is studied from density-functional calculations using the linear muffin-tin orbitals method. An antiferromagnetic solution with a magnetic…

Strongly Correlated Electrons · Physics 2009-11-10 H. Meskine , S. Satpathy

Using the multiband $d-p$ model and unrestricted Hartree-Fock approximation we investigate the electronic structure and spin-orbital order in three-dimensional MnO$_3$ lattice such as realized in LaMnO$_3$. The orbital order is induced and…

Strongly Correlated Electrons · Physics 2019-04-04 Krzysztof Rościszewski , Andrzej M. Oleś

The magnetic and structural properties of single crystal Fe$_{1-x}$Co$_x$V$_2$O$_{4}$ samples have been investigated by performing specific heat, susceptibility, neutron diffraction, and X-ray diffraction measurements. As the orbital-active…

Materials Science · Physics 2017-09-07 R. Sinclair , J. Ma , H. B. Cao , T. Hong , M. Matsuda , Z. L. Dun , H. D. Zhou

The crossover from localized- to itinerant-electron behavior is associated with many intriguing phenomena in condensed-matter physics. In this paper, we investigate the crossover from localized to itinerant regimes in the spinel system…

Strongly Correlated Electrons · Physics 2015-07-20 J. Ma , J. H. Lee , S. E. Hahn , Tao Hong , H. B. Cao , A. A. Aczel , Z. L. Dun , M. B. Stone , W. Tian , Y. Qiu , J. R. D. Copley , H. D. Zhou , R. S. Fishman , M. Matsuda

Compositionally tunable vanadium oxyhydrides Sr2VO4-xHx (x = 0 - 1) without considerable anion vacancy were synthesized by high-pressure solid state reaction. The crystal structures and their properties were characterized by powder neutron…

We have studied magnetic correlations in several compositions of stripe-ordered La2-xSrxNiO4. In this paper we show how polarized-neutron scattering has helped uncover important features of the magnetic ordering and spin dynamics. In…

Strongly Correlated Electrons · Physics 2009-11-10 A. T. Boothroyd , P. G. Freeman , D. Prabhakaran , M. Enderle , J. Kulda

The magnetic, dielectric and structural properties of type-I multiferroic KNiPO$_4$ have been investigated by neutron powder diffraction, magnetization, dielectric and high temperature synchrotron-XRD measurements. Below the N\'{e}el…

Strongly Correlated Electrons · Physics 2022-07-15 Alexandre Pages , Jian-Rui Soh , Marjaneh Jafari Fesharaki , Henrik M. Ronnow , Hossein Ahmadvand

Magnetism in doped transition metal dichalcogenide monolayers and van der Waals interfaced materials have motivated the search for sustainable magnetic states at the nanoscale with the prospect of building devices for spintronics…

Materials Science · Physics 2025-08-05 Rohin Sharma , Diem Thi-Xuan Dang , Lilia M. Woods

This work is devoted to the logical proof of the Goodenough and Khomskii idea of the existence of spin-orbit transitions in transition magnetic crystals. In agreement with the basics of the Landau theory of phase transitions the…

Strongly Correlated Electrons · Physics 2012-07-05 Khisa Sh. Borlakov , Albert Kh. Borlakov

We develop a microscopic theory for the charge ordering (CO) transitions in the spinels AlV$_2$O$_4$ and LiV$_2$O$_4$ (under pressure). The high degeneracy of CO states is lifted by a coupling to the rhombohedral lattice deformations which…

Strongly Correlated Electrons · Physics 2007-05-23 Y. Z. Zhang , P. Fulde , P. Thalmeier , A. Yaresko

We present two examples of the real materials, which show orbital-selective behavior. In both compounds a part of the electrons is localized on the molecular orbitals, which lead to a significant reduction of the magnetic moment on the…

Materials Science · Physics 2015-12-09 Sergey V. Streltsov

Using the multi-band $d-p$ model and unrestricted Hartree-Fock approximation we investigate the electronic structure and spin-orbital order in three-dimensional VO$_3$ lattice. The main aim of this investigation is testing if simple $d-p$…

Strongly Correlated Electrons · Physics 2018-08-14 Krzysztof Rościszewski , Andrzej M. Oleś

The ferrimagnetic spinel Mn3O4 exhibits large and anisotropic changes in electronic and structural properties in response to an applied magnetic field. These changes are thought to result from the field-dependent tuning---via strong…

Strongly Correlated Electrons · Physics 2016-06-22 T. Byrum , S. L. Gleason , A. Thaler , G. J. MacDougall , S. L. Cooper