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A new variational technique is developed to investigate the polaronic features of the Holstein Molecular Crystal Model. It is based on a linear superposition of Bloch states that describe large and small polaron wave functions. It is shown…

Materials Science · Physics 2009-10-31 V. Cataudella , G. De Filippis , G. Iadonisi

We explore polaronic quantum transport in three-dimensional models of disordered organic crystals with strong coupling between electronic and vibrational degrees of freedom. By studying the polaron dynamics in a static disorder environment,…

Materials Science · Physics 2015-06-03 Frank Ortmann , Stephan Roche

The nonlocal electron-phonon couplings in organic semiconductors responsible for the fluctuation of intermolecular transfer integrals has been the center of interest recently. Several irreconcilable scenarios coexist for the description of…

Materials Science · Physics 2021-08-04 Weitang Li , Jiajun Ren , Zhigang Shuai

When mid-infrared light interacts with nanoscale polar dielectric structures optical phonon propagation cannot be ignored, leading to a rich nonlocal phenomenology which we have only recently started to uncover. In properly crafted…

Mesoscale and Nanoscale Physics · Physics 2021-08-10 Christopher R. Gubbin , Simone De Liberato

Polarons are quasi-particles made from electrons interacting with vibrations in crystal lattices. They derive their name from the strong electron-vibration polar interaction in ionic systems, that induces associated spectroscopic and…

Polaron formation following optical absorption is a key process that defines the photophysical properties of many semiconducting transition metal oxides, which comprise an important class of materials with potential optoelectronic and…

Materials Science · Physics 2022-11-11 Jacob L. Shelton , Kathryn E. Knowles

The effect of a solid-vacuum interface on the properties of a strongly coupled electron-phonon system is analyzed using dynamical mean-field theory to solve the Holstein model in a semi-infinite cubic lattice. Polaron formation is found to…

Strongly Correlated Electrons · Physics 2015-05-13 Reza Nourafkan , Massimo Capone , Nasser Nafari

The possibility of superconducting pairing of electrons in doped graphene due to in-plane and out-of-plane phonons is studied. Quadratic coupling of electrons with out-of-plane phonons is considered in details, taking into account both…

Mesoscale and Nanoscale Physics · Physics 2010-05-27 Yu. E. Lozovik , A. A. Sokolik

A simple approach to the many-polaron problem for both weak and intermediate electron-phonon coupling and valid for densities much smaller than those typical of metals is presented. Within the model the total energy, the collective modes…

Condensed Matter · Physics 2009-10-31 G. De Filippis , V. Cataudella , G. Iadonisi

From density functional calculations, we show that localized states stemming from defects or topological disorder exhibit an anomalously large electron-phonon coupling. We provide a simple analysis to explain the observation and perform a…

Disordered Systems and Neural Networks · Physics 2009-11-10 Raymond Atta-Fynn , Parthapratim Biswas , D. A. Drabold

Small polaron formation in transition metal oxides, like the prototypical material rutile TiO$_2$, remains a puzzle and a challenge to simple theoretical treatment. In our combined experimental and theoretical study, we examine this problem…

Materials Science · Physics 2017-12-06 Grigory Kolesov , Boris A. Kolesov , Efthimios Kaxiras

Polaron spectral functions are computed for highly doped graphene-on-substrate and other atomically thin graphitic systems using the diagrammatic Monte Carlo technique. The specific aim is to investigate the effects of interaction on…

Strongly Correlated Electrons · Physics 2012-11-30 J. P. Hague

Positional polymorphism in solids refers to locally disordered unit cells that, on average, reproduce the high-symmetry structures observed in diffraction experiments. Standard theories of electron-phonon interactions fail to describe the…

We relate the phase separation observed in many crystals with pronounced electron correlations to the regions of negative electron compressibility. They were found in several models describing strong electron correlations. At low…

Strongly Correlated Electrons · Physics 2022-10-25 Alexei Sherman

We present the first numerically exact study of self-trapped, a.k.a. soliton, states of electrons that form in materials with strong quadratic coupling to the phonon coordinates. Previous studies failed to observe predictions based on the…

Strongly Correlated Electrons · Physics 2024-10-08 Zhongjin Zhang , Anatoly Kuklov , Nikolay Prokof'ev , Boris Svistunov

Polarons, quasiparticles arising from electron-phonon coupling, are crucial in understanding material properties such as high-temperature superconductivity and colossal magnetoresistance. However, scarce studies have been performed to…

The three band p-d model of strongly correlated electrons interacting with optical phonon via diagonal and off-diagonal electron-phonon interaction is considered within cluster perturbation theory. At first step the exact diagonalization of…

Strongly Correlated Electrons · Physics 2015-11-04 I. A. Makarov , E. I. Shneyder , P. A. Kozlov , S. G. Ovchinnikov

We present a novel approach to electron-lattice interaction beyond the linear-coupling regime. Based on the solution of a Holstein-Peierls-type model, we derive explicit analytical expressions for the eigenvalue spectrum of the Hamiltonian,…

Materials Science · Physics 2018-12-13 Pablo García Risueño , Dmitrii Nabok , Qiang Fu , Claudia Draxl

We have developed a first-principles method to calculate the electron-phonon coupling for specific modes and q-points in the Brillouin Zone for crystalline organic semiconductors. Using the obtained coupling strengths, we propose an…

To investigate the possibility whether electron-phonon coupling can enhance orbital fluctuations in iron-based superconductors, we develop an ab initio method to construct the effective low-energy models including the phonon-related terms.…

Superconductivity · Physics 2014-01-20 Yusuke Nomura , Kazuma Nakamura , Ryotaro Arita