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Suspensions of hard colloidal particles frequently serve as model systems in studies on fundamental aspects of phase transitions. But often colloidal particles that are considered as ``hard'' are in fact weakly charged. If the colloids are…

Soft Condensed Matter · Physics 2014-03-24 Sven Dorosz , Nikhilesh Shegokar , Tanja Schilling , Martin Oettel

When a Coulombic fluid is confined between two parallel charged plates, an exact relation links the difference of ionic densities at contact with the plates, to the surface charges of these boundaries. It no longer applies when the…

Statistical Mechanics · Physics 2015-10-28 Juan Pablo Mallarino , Gabriel Tellez , Emmanuel Trizac

Nonmagnetic spheres confined in a ferrofluid layer (magnetic holes) present dipolar interactions when an external magnetic field is exerted. The interaction potential of a microsphere pair is derived analytically, with a precise care for…

Soft Condensed Matter · Physics 2009-11-10 Renaud Toussaint , Jørgen Akselvoll , Eirik G. Flekkøy , Geir Helgesen , Arne T. Skjeltorp

We use a new approach to derive dielectric mixing rules for macroscopically homogeneous and isotropic multicomponent mixtures of anisotropic inhomogeneous dielectric particles. Two factors of anisotropy are taken into account, the shape of…

Materials Science · Physics 2015-05-13 M. Ya. Sushko

We study charged nanoparticles adsorbed onto surfactant bilayers using small-angle scattering of synchrotron radiation. The in-plane interaction of the particles is well described by a DLVO component (measured independently in solution) and…

The properties of a system of charged particles on a 2D lattice, subject to an anisotropic Jahn-Teller-type interaction and 3D Coulomb repulsion are investigated. In the mean-field approximation without Coulomb interaction, the system…

Strongly Correlated Electrons · Physics 2008-11-19 T. Mertelj , V. V. Kabanov , D. Mihailovic

Like-charged macroions attract each other as a result of strong electrostatic correlations in the presence of multivalent counterions or at low temperatures. We investigate the effective electrostatic interaction between i) two like-charged…

Soft Condensed Matter · Physics 2007-05-23 Ali Naji , Roland R. Netz

This paper builds on two previous works, Lindgren et al. J. Comp. Phys. 371, 712-731 (2018) and Quan et al. arXiv:1807.05384 (2018), to devise a new method to solve the problem of calculating electrostatic interactions in a system composed…

Soft Condensed Matter · Physics 2019-02-20 Eric B. Lindgren , Chaoyu Quan , Benjamin Stamm

We derive and introduce anisotropic effective pair potentials to coarse-grain solutions of semiflexible rings polymers of various lengths. The system has been recently investigated by means of full monomer-resolved computer simulations,…

Soft Condensed Matter · Physics 2015-07-21 Peter Poier , Christos N. Likos , Angel J. Moreno , Ronald Blaak

The implications of soft `patchy' interactions on the orientational disorder-order transition of strongly elongated colloidal rods and flat disks is studied within a simple Onsager-van der Waals density functional theory. The theory…

Soft Condensed Matter · Physics 2015-06-17 H. H. Wensink , E. Trizac

In biomimetic and biological systems, interactions between surfaces are often mediated by adhesive molecules, nanoparticles, or colloids dispersed in the surrounding solution. We present here a general, statistical-mechanical model for two…

Soft Condensed Matter · Physics 2009-11-13 Bartosz Rozycki , Reinhard Lipowsky , Thomas R. Weikl

The electrostatic interaction between pairs of spherical or macroscopically long, parallel cylindrical colloids trapped at fluid interfaces is studied theoretically for the case of small inter-particle separations. Starting from the…

Soft Condensed Matter · Physics 2018-11-30 Arghya Majee , Markus Bier , S. Dietrich

We consider a one-dimensional model allowing analytical derivation of the effective interactions between two charged colloids. We evaluate exactly the partition function for an electroneutral salt-free suspension with dielectric jumps at…

Soft Condensed Matter · Physics 2021-04-23 Lucas Varela , Gabriel Tellez , Emmanuel Trizac

We explore structural correlations of strongly asymmetric mixtures of binary charged colloids within the primitive model of electrolytes considering large charge and size ratios of 10 and higher. Using computer simulations with explicit…

Soft Condensed Matter · Physics 2022-07-13 Elshad Allahyarov , Hartmut Löwen , Alan Denton

The structural and thermodynamic properties of mixtures of colloidal spheres and non-adsorbing polymer chains are studied within a novel general two-component macromolecular liquid state approach applicable for all size asymmetry ratios.…

Soft Condensed Matter · Physics 2009-11-07 M. Fuchs , K. S. Schweizer

We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular we use a simplified model to elucidate the effects of rotational…

Soft Condensed Matter · Physics 2010-09-09 Chi-Lun Lee , Sio-Kit Ng

Anisotropic colloidal particles constitute an important class of building blocks for self-assembly directed by electrical fields. The aggregation of these building blocks is driven by induced dipole moments, which arise from an interplay…

Soft Condensed Matter · Physics 2018-09-10 Ming Han , Huanxin Wu , Erik Luijten

Using molecular dynamics simulations, it is demonstrated that monovalent counterions can induce aggregation of similarly charged rod-like polyelectrolyte chains. The critical value of the linear charge density for aggregation is shown to be…

Soft Condensed Matter · Physics 2014-05-06 Anoop Varghese , R. Rajesh , Satyavani Vemparala

Within the framework of a discrete Gaussian model, we present analytical results for the interaction induced by a lamellar phase between small embedded colloids. We consider the two limits of particles strongly adherent to the adjacent…

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