Related papers: Fluctuation induced effects in confined electrolyt…
The notion of fluctuation-induced forces is generalized to the cases where the fluctuations have nonequilibrium origin. It is shown that a net force is exerted on a single flat plate that restricts scale-free fluctuations of a scalar field…
The charge distribution at the interface between two electrolytes is studied for the case of non-vanishing ion fluxes. The analysis is an extension of the established Verwey-Niessen theory to non-equilibrium situations. Applying matched…
We discuss non-equilibrium extensions of the Casimir force (due to electromagnetic fluctuations), where the objects as well as the environment are held at different temperatures. While the formalism we develop is quite general, we focus on…
We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…
One of the most intriguing manifestations of quantum zero-point fluctuations are the van der Waals and Casimir forces, often associated with vacuum fluctuations of the electromagnetic field. Here we study generalized fluctuation potentials…
We propose a definitive test of whether plates involved in Casimir experiments should be modeled with ballistic or diffusive electrons--a prominent controversy highlighted by a number of conflicting experiments. The unambiguous test we…
Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…
We investigate the effect of polydispersity on fluctuation-induced interactions between colloids trapped at a fluid interface. Using the scattering-matrix formalism, we calculate the interaction energy in two- and three-body systems under…
Surfaces are able to control physical-chemical processes in multi-component solution systems and, as such, find application in a wide range of technological devices. Understanding the structure, dynamics and thermodynamics of non-ideal…
The results of molecular dynamics simulations of the properties of water in an aqueous ionic solution close to an interface with a model metallic electrode are described. In the simulations the electrode behaves as an ideally polarizable…
We investigate the effect of quenched surface disorder on effective interactions between two planar surfaces immersed in fluids which are near criticality and belong to the Ising bulk universality class. We consider the case that, in the…
We present new results on the ionization by electron impacts in a dense plasma. We are interested in the density effect known as the ionization potential depression and in its role in atomic structure. Rather than using the well-known…
Applying an electric field to an aqueous colloidal dispersion establishes a complex interplay of forces among the highly mobile simple ions, the more highly charged but less mobile colloidal spheres, and the surrounding water. This…
We are interested in rationalizing the phenomenon of like-charge attraction between charged bodies, such as a pair of colloids, in the strong coupling regime. The two colloids are modelled as uniformly charged parallel plates, neutralized…
We evaluate the exponentially rare fluctuations of the ionic current for a dilute electrolyte by means of macroscopic fluctuation theory. We consider the fluctuating hydrodynamics of a fluid electrolyte described by a stochastic…
We describe the ``electrolubrication'' occurring in liquid mixtures confined between two charged surfaces. For a mixture of two liquids, the effective viscosity decreases markedly in the presence of a field. The origin of this reduction is…
The impact of agglomeration of magnetic nanoparticles on the Casimir pressure is investigated in the configuration of two material plates and a layer of ferrofluid confined between them. Both cases of similar and dissimilar plates are…
We study the response of a model micro-electrochemical cell to a large ac voltage of frequency comparable to the inverse cell relaxation time. To bring out the basic physics, we consider the simplest possible model of a symmetric binary…
In the presence of an external field, the imposition of specific boundary conditions can lead to interesting new manifestations of the Casimir effect. In particular, it is shown here that even a single conducting plate may experience a…
In recent years, the theoretical description of electrical noise and fluctuation-induced effects in electrolytes has gained a renewed interest, enabled by stochastic field theories like stochastic density functional theory (SDFT). Such…