Related papers: Fluctuation induced effects in confined electrolyt…
It has been established for a long time that the long range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance $H$ is screened by an intervening electrolyte. Here we show how this…
The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many phenomena originated from ion correlation. An important…
We numerically study a two-dimensional granular gas of rigid disks where an external driving force is applied to each particle in such a way that the system is driven into a steady state by balancing the energy input and the dissipation due…
The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically…
Electromagnetic fluctuation-induced forces between atoms and surfaces are generally known as Casimir-Polder interactions. The exact knowledge of these forces is rapidly becoming important in modern experimental set-ups and for technological…
We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…
We study the problem of charge regulation and its effects on electrostatic interactions between dissociable charge groups immersed in a univalent electrolyte, within a family of one dimensional exactly solvable models. We consider the case…
The Casimir Effect is a physical manifestation of quantum fluctuations of the electromagnetic vacuum. When two metal plates are placed closely together, typically much less than a micron, the long wavelength modes between them are frozen…
Two thin conducting, electrically neutral, parallel plates forming an isolated system in vacuum exert attracting force on each other, whose origin is the quantum electrodynamical interaction. This theoretical hypothesis, known as Casimir…
We generalize the predictions for attractions between over-all neutral surfaces induced by charge fluctuations/correlations to non-uniform systems that include dielectric discontinuities, as is the case for mixed charged lipid membranes in…
A small polarizable object (an atom, molecule or nanoparticle), placed above a medium with flowing dc current in it, is considered. It is shown that the dc current can have a strong effect on the force exerted on the particle. The…
The interaction of compact objects with an infinitely extended mirror plane due to quantum fluctuations of a scalar or electromagnetic field that scatters off the objects is studied. The mirror plane is assumed to obey either Dirichlet or…
We investigate electro-osmosis in aqueous solutions of polyelectrolytes using mean-field equations. A solution of positively charged polyelectrolytes is confined between two negatively charged planar surfaces, and an electric field is…
The charge states of ions in dense plasmas fluctuate due to collisional ionization and recombination. Here we show how, by modifying the ion interaction potential, these fluctuations can mediate energy exchange between the plasma electrons…
A weakly charged flexible polyelectrolyte chain in a neutral spherical cavity is analyzed using self-consistent field theory (SCFT) within an explicit solvent model. Assuming the radial symmetry for the system, it is found that the…
We calculate the effective fluctuation induced force between spherical or disk-like colloids trapped at a flat, fluid interface mediated by thermally excited capillary waves. This Casimir type force is determined by the partition function…
While techniques to compute thermal fluctuation induced, or pseudo-Casimir, forces in equilibrium systems are well established, the same is not true for non-equilibrium cases. We present a general formalism that allows us to unambiguously…
Electron confinement within a small volume is intriguing as a realization of the particle-in-a-box system, which appears in every quantum mechanics textbook. While the electron confinement is readily imaginable in solid-state systems, it…
We consider an electrolyte solution confined by semipermeable membranes in contact with a salt-free solvent. Membranes are uncharged, but since small counter-ions leak-out into infinite salt-free reservoirs, we observe a distance-dependent…
The position of a colloidal particle trapped in an external field thermally fluctuates at equilibrium. As is well known, the ambient fluid is not a simple heat bath and the particle mass appears to increase, which influences the mean square…