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Using the quasi-exact density-matrix renormalization-group method we calculate the solvation forces in two-dimensional Ising films of thickness L subject to identical algebraically decaying boundary fields with various decay exponents p. At…

Statistical Mechanics · Physics 2015-05-27 A. Drzewinski , A. Maciolek , A. Barasinski

We argue that in a fluid, or magnet, confined by adsorbing walls which favour liquid, or (+) phase, the solvation (Casimir) force in the vicinity of the critical point is strongly influenced by capillary condensation which occurs below the…

Statistical Mechanics · Physics 2009-10-31 A. Drzewinski , A. Maciolek , R. Evans

We consider a simple fluid confined between two parallel walls (substrates), separated by a distance L. The walls exert competing surface fields so that one wall is attractive and may be completely wet by liquid (it is solvophilic) while…

Soft Condensed Matter · Physics 2014-09-01 Maria C. Stewart , Robert Evans

Understanding the force between charged surfaces immersed in an electrolyte solution is a classic problem in soft matter and liquid-state theory. Recent experiments showed that the force decays exponentially but the characteristic decay…

Soft Condensed Matter · Physics 2018-09-26 Alpha A. Lee , Jean-Pierre Hansen , Olivier Bernard , Benjamin Rotenberg

The effective interaction between two planar walls immersed in a fluid is investigated by use of Density Functional Theory in the super-critical region of the phase diagram. A hard core Yukawa model of fluid is studied with special…

Statistical Mechanics · Physics 2017-04-05 Pietro Anzini , Alberto Parola

The density profile and Gibbs adsorption of a near-critical fluid confined between two identical planar walls is studied by means of Monte Carlo simulation and by density functional theory for a Lennard-Jones fluid. By reducing the strength…

Statistical Mechanics · Physics 2016-08-31 A. Maciolek , R. Evans , N. B. Wilding

We consider a model fluid with long-ranged, dispersion interparticle potentials confined between competing parallel walls. One wall is solvophilic and would be completely wet at bulk liquid-gas coexistence while the other is solvophobic and…

Soft Condensed Matter · Physics 2015-06-05 M. C. Stewart , R. Evans

We present the results of molecular dynamics computer simulations of a binary Lennard-Jones liquid confined between two parallel rough walls. These walls are realized by frozen amorphous configurations of the same liquid and therefore the…

Condensed Matter · Physics 2009-09-29 Peter Scheidler , Walter Kob , Kurt Binder

The properties of a fluid, or Ising magnet, confined in a $L \times \infty$ geometry with opposing surface fields at the walls are studied by density matrix renormalization techniques. In particular we focus on the effect of gravity on the…

Statistical Mechanics · Physics 2009-10-30 Enrico Carlon , Andrzej Drzewinski

When massless excitations are limited or modified by the presence of material bodies one observes a force acting between them generally called Casimir force. Such excitations are present in any fluid system close to its true bulk critical…

Statistical Mechanics · Physics 2016-10-05 Daniel M Dantchev , Vassil M Vassilev , Peter A Djondjorov

Using general scaling arguments combined with mean-field theory we investigate the critical ($T \simeq T_c$) and off-critical ($T\ne T_c$) behavior of the Casimir forces in fluid films of thickness $L$ governed by dispersion forces and…

Statistical Mechanics · Physics 2008-11-26 Daniel Dantchev , Frank Schlesener , S. Dietrich

The confinement of long-ranged critical fluctuations in the vicinity of second-order phase transitions in fluids generates critical Casimir forces acting on confining surfaces or among particles immersed in a critical solvent. This is…

Statistical Mechanics · Physics 2015-06-17 O. A. Vasilyev , S. Dietrich

We present both analytical and numerical results for the behaviour of the Casimir force in a Ginzburg-Landau type model of a film of a simple fluid or binary liquid mixture in which the confining surfaces are strongly adsorbing but…

Statistical Mechanics · Physics 2018-11-06 Daniel Dantchev , Vassil Vassilev , Peter Djondjorov

We study the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance $L$ from each other confining a non-polar simple fluid or a binary liquid mixture.…

Statistical Mechanics · Physics 2015-07-20 Galin Valchev , Daniel Dantchev

When masless excitations are limited or modified by the presence of material bodies one observes a force atcing between them generally called Casimir force. Such excitations are present in any fluid system close to its true bulk critical…

Statistical Mechanics · Physics 2016-04-27 Daniel M. Dantchev , Vassil M. Vassilev , Peter A. Djondjorov

Recent experiments have measured the critical Casimir force acting on a colloid immersed in a binary liquid mixture near its continuous demixing phase transition and exposed to a chemically structured substrate. Motivated by these…

Statistical Mechanics · Physics 2013-11-27 Francesco Parisen Toldin , Matthias Tröndle , S. Dietrich

The solvation force for the 2D Ising strip is calculated via exact diagonalization of the transfer matrix in two cases: the symmetric case corresponds to identical surface fields, and the antisymmetric case to exactly opposite surface…

Statistical Mechanics · Physics 2009-11-13 P. Nowakowski , M. Napiórkowski

We consider d=2 Ising strip with surface fields acting on boundary spins. Using the properties of the transfer matrix spectrum we identify two pseudotransition temperatures and show that they satisfy similar scaling relations as expected…

Statistical Mechanics · Physics 2015-05-13 Piotr Nowakowski , Marek Napiórkowski

Exploiting the mapping between a binary mixture and the Ising model we have analyzed the critical fluctuations by means of the density-matrix renormalization group technique. The calculations have been carried out for a two-dimensional…

Statistical Mechanics · Physics 2015-02-11 Małgorzata Zubaszewska , Andrej Gendiar , Tomasz Masłowski

Motivated by recent experiments with confined binary liquid mixtures near their continous demixing phase transition we study the critical behavior of a system, which belongs to the Ising universality class, for the film geometry with one…

Soft Condensed Matter · Physics 2017-08-23 F. Parisen Toldin , S. Dietrich
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