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Related papers: Characterization of the S = 9 excited state in Fe8…

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High-frequency ($f$ = 190 GHz) electron paramagnetic resonance (EPR) at magnetic fields up to 12 T as well as Q-band ($f$ = 34.1 GHz) EPR were performed on single crystals of the molecular wheel CsFe$_8$. In this molecule, eight Fe(III)…

Mesoscale and Nanoscale Physics · Physics 2010-09-14 Jan Dreiser , Oliver Waldmann , Graham Carver , Christopher Dobe , Hans-Ulrich Güdel , Høgni Weihe , Anne-Laure Barra

We report the electronic structure and magnetic ordering of the single molecule magnet [Mn$_{10}$O$_{4}$(2,2'-biphenoxide)$_{4}$Br$_{12}$]$^{4-}$ based on first-principles all-electron density-functional calculations. We find that two of…

Materials Science · Physics 2009-11-07 Jens Kortus , Tunna Baruah , N. Bernstein , Mark R. Pederson

We report results of a multi-frequency (0.8-60 GHz) electron spin resonance study of the spin dynamics in the quasi-2D square lattice antiferromagnet Ba$_2$MnGe$_2$O$_7$ both in antiferromagnetically ordered and paramagnetic phases. We…

Strongly Correlated Electrons · Physics 2024-01-02 V. N. Glazkov , Yu. V. Krasnikova , I. K. Rodygina , H. -A. Krug von Nidda , T. Masuda

The impurity-induced antiferromagnetic ordering of the doped Haldane magnet Pb(Ni{1-x}Mg{x})2V2O8 (0 < x <0.06) was studied by electron spin resonance (ESR) on ceramic samples in the frequency range 9-110 GHz. Below the N\'{e}el temperature…

Strongly Correlated Electrons · Physics 2009-11-07 A. I. Smirnov , V. N. Glazkov , H. -A. Krug von Nidda , A. Loidl , L. N. Demianets , A. Ya. Shapiro

Magnetic nanoparticles of gamma-Fe2O3 coated by organic molecules and suspended in liquid and solid matrices, as well as a non-diluted magnetic fluid have been studied by electron magnetic resonance (EMR) at 77-380 K. Slightly asymmetric…

Materials Science · Physics 2009-11-11 N. Noginova , F. Chen , T. Weaver , E. P. Giannelis , A. B. Bourlinos , V. A. Atsarkin

To understand the effect of molecular environment on the electronic and magnetic properties of the single-molecule magnet (SMM) Mn$_{12}$, we explore two possible means for adding extra electrons to molecule. We explore both substitution of…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson

We show that the dynamic magnetic susceptibility and the superparamagnetic blocking temperature of an Fe8 single molecule magnet oscillate as a function of the magnetic field Hx applied along its hard magnetic axis. These oscillations are…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 E. Burzurí , F. Luis , O. Montero , B. Barbara , R. Ballou , S. Maegawa

A remarkably large magnetic anisotropy energy of 305 K is computed by quantum chemistry methods for divalent Fe$^{2+}$ $d^6$ substitutes at Li-ion sites with $D_{6h}$ point-group symmetry within the solid-state matrix of Li$_3$N. This is…

Most experimental data on the single-molecule magnet Mn$_{12}$ acetate have been successfully explained by the assumption that the Mn$_{12}$ acetate has an effective ground-state spin of S=10. However, the effect of the low-lying excited…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson , C. Stephen Hellberg

We introduce a new representation of an integer spin $S$ via bosonic operators which is useful in describing the paramagnetic phase and transitions to magnetically ordered phases in magnetic systems with large single-ion easy-plane…

Strongly Correlated Electrons · Physics 2012-06-01 Alexey V Sizanov , Arseny V Syromyatnikov

We present pump-probe measurements on the single-molecule magnet Fe_8 with microwave pulses having a length of several nanoseconds. The microwave radiation in the experiments is located in the frequency range between 104 GHz and 118 GHz.…

Mesoscale and Nanoscale Physics · Physics 2008-02-05 S. Bahr , K. Petukhov , V. Mosser , W. Wernsdorfer

The elastic resonance scattering protons decayed from $^{11}$B to the ground state of $^{10}$Be were measured using the thick-target technique in inverse kinematics at the Heavy Ion Research Facility in Lanzhou (HIRFL). The obtained…

We have performed high-field magnetization and ESR measurements on Ba$_3$CoSb$_2$O$_9$ single crystals, as a representative two-dimensional spin-1/2 Heisenberg antiferromagnet on a uniform triangular lattice, and have determined all the…

Strongly Correlated Electrons · Physics 2015-06-15 Takuya Susuki , Nobuyuki Kurita , Takuya Tanaka , Hiroyuki Nojiri , Akira Matsuo , Koichi Kindo , Hidekazu Tanaka

We compare the magnetic and electronic configuration of single Mn atoms in molecular beam epitaxy (MBE) grown Bi$_2$Se$_3$ thin films, focusing on electron paramagnetic (ferromagnetic) resonance (EPR and FMR, respectively) and…

Fe$_5$SiB$_2$ has been synthesized and magnetic measurements have been carried out, revealing that M$_{\text{sat}}$ = 0.92 MA/m at T = 300 K. The M vs T curve shows a broad peak around T = 160 K. The anisotropy constant, K$_1$, estimated at…

We present high-frequency high-field electron paramagnetic resonance (EPR) measurements on the dodecanuclear manganese complex Mn12-bromoacetate (Mn12-BrAc). The crystal-field parameters are found to be identical to those of the original…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 K. Petukhov , S. Hill , N. E. Chakov , G. Christou , K. Abboud

We present general expressions for the magnetic transition rates in beam Electron Paramagnetic Resonance (EPR) experiments of anisotropic spin systems in the solid state. The expressions apply to general spin centers and arbitrary…

Mesoscale and Nanoscale Physics · Physics 2015-01-14 Joscha Nehrkorn , Alexander Schnegg , Karsten Holldack , Stefan Stoll

NiCl$_2$-4SC(NH$_2$)$_2$ (DTN) is a quantum S=1 chain system with strong easy-pane anisotropy and a new candidate for the Bose-Einstein condensation of the spin degrees of freedom. ESR studies of magnetic excitations in DTN in fields up to…

Strongly Correlated Electrons · Physics 2012-08-27 S. A. Zvyagin , J. Wosnitza , C. D. Batista , M. Tsukamoto , N. Kawashima , J. Krzystek , V. S. Zapf , M. Jaime , N. F. Oliveira, , A. Paduan-Filho

A detailed multifrequency high field - high frequency EPR (95-285 GHz) study has been performed on the single-molecule magnet of formula [Fe8O2(OH)12(tacn)6]Br8 9H2O, where tacn=1,4,7-triazacyclononane. Polycrystalline powder spectra have…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Anne Laure Barra , Dante Gatteschi , Roberta Sessoli

The intermediate valence of Ce in CeCo$_5$ challenges standard density functional theory (DFT) and static DFT+$U$ approaches, which fail to capture its magnetic properties. By combining DFT+$U$ with exact diagonalization of the Anderson…

Strongly Correlated Electrons · Physics 2026-04-21 Alexander B. Shick , Evgenia A. Tereshina-Chitrova
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