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The transition from a liquid to a glass in colloidal suspensions of particles interacting through a hard core plus an attractive square-well potential is studied within the mode-coupling-theory framework. When the width of the attractive…

Soft Condensed Matter · Physics 2007-05-23 K. Dawson , G. Foffi , M. Fuchs , W. Gotze , F. Sciortino , M. Sperl , P. Tartaglia , Th. Voigtmann , E. Zaccarelli

The correlation functions near higher-order glass-transition singularities are discussed for a schematic two-component model within the mode-coupling theory for ideal glass-transitions. The correlators decay in leading order like…

Soft Condensed Matter · Physics 2007-05-23 Matthias Sperl

We consider second-order phase transitions in which the order parameter is a replicated overlap matrix. We focus on a tricritical point that occurs in a variety of mean-field models and that, more generically, describes higher order…

Disordered Systems and Neural Networks · Physics 2024-05-27 Luca Leuzzi , Tommaso Rizzo

Concentrated colloidal suspensions are a well-tested model system which has a glass transition. Colloids are suspensions of small solid particles in a liquid, and exhibit glassy behavior when the particle concentration is high; the…

Soft Condensed Matter · Physics 2010-10-01 Luca Cipelletti , Eric R. Weeks

We discuss the nonlinear rheology of dense colloidal dispersions at the glass transition. A first principles approach starting with interacting Brownian particles in given arbitrary homogeneous (incompressible) flow neglecting hydrodynamic…

Soft Condensed Matter · Physics 2009-11-13 D. Hajnal , O. Henrich , J. J. Crassous , M. Siebenbuerger , M. Drechsler , M. Ballauff , M. Fuchs

Within the framework of mode-coupling theory, we present a simple model for describing dense assemblies of active (self-propelled) spherical colloidal particles. For isotropic suspensions, we demonstrate that the glass transition is shifted…

Soft Condensed Matter · Physics 2014-03-10 T. F. F. Farage , J. M. Brader

The evolution of an initially prepared distribution of micron sized colloidal particles, trapped at a fluid interface and under the action of their mutual capillary attraction, is analyzed by using Brownian dynamics simulations. At a…

Soft Condensed Matter · Physics 2011-11-29 J. Bleibel , A. Dominguez , M. Oettel , S. Dietrich

We derive a mode-coupling theory for the slow dynamics of fluids confined in disordered porous media represented by spherical particles randomly placed in space. Its equations display the usual nonlinear structure met in this theoretical…

Soft Condensed Matter · Physics 2007-05-23 V. Krakoviack

Using fast confocal microscopy we image the three-dimensional dynamics of particles in a yielded hard-sphere colloidal glass under steady shear. The structural relaxation, observed in regions with uniform shear, is nearly isotropic but is…

Soft Condensed Matter · Physics 2009-11-11 R. Besseling , Eric R. Weeks , A. B. Schofield , W. C. K. Poon

Soft colloids allow to explore high density states well beyond random close packing. An important open question is whether softness controls the dynamics under these dense conditions. While experimental works reported conflicting results,…

Soft Condensed Matter · Physics 2021-06-08 Nicoletta Gnan , Emanuela Zaccarelli

Transitions in structural heterogeneity of colloidal depletion gels formed through short-range attractive interactions are correlated with their dynamical arrest. The system is a density and refractive index matched suspension of 0.20…

Soft Condensed Matter · Physics 2009-11-11 C. J. Dibble , M. Kogan , M. J. Solomon

We calculate the ideal-glass-transition line for adhesive hard spheres in the temperature-volume-fraction plane within the framework of the mode-coupling theory. We find two intersecting lines, controlled by the hard-core and the adhesive…

Soft Condensed Matter · Physics 2019-08-17 L. Fabbian , W. Goetze , F. Sciortino , P. Tartaglia , F. Thiery

Amorphous solids relax via slow molecular rearrangement induced by thermal fluctuations or applied stress. Although microscopic structural signatures predicting these structural relaxations have long been sought, a physically motivated…

Soft Condensed Matter · Physics 2024-08-12 Ratimanasee Sahu , Mohit Sharma , Peter Schall , Sarika Maitra Bhattacharyya , Vijayakumar Chikkadi

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of…

Soft Condensed Matter · Physics 2016-03-04 Bo Zhang , Xiang Cheng

We examine the dynamics of two-dimensional colloidal systems using numerical simulations of a system with a drive applied to a thin region in the middle of the sample to produce a local shear. For a monodisperse colloidal assembly, we find…

Soft Condensed Matter · Physics 2015-06-11 A. Libal , B. M. Csiki , C. J. Olson Reichhardt , C. Reichhardt

We explore the glassy dynamics of soft colloids using microgels and charged particles interacting by steric and screened Coulomb interactions, respectively. In the supercooled regime, the structural relaxation time $\tau_\alpha$ of both…

The nonlinear rheological properties of dense suspensions are discussed within simplified models, suggested by a recent first principles approach to the model of Brownian particles in a constant-velocity-gradient solvent flow. Shear…

Soft Condensed Matter · Physics 2015-06-24 Matthias Fuchs , Michael E. Cates

We use computer simulations to study the dynamics of a physical gel at high densities where gelation and the glass transition interfere. We report and provide detailed physical understanding of complex relaxation patterns for time…

Soft Condensed Matter · Physics 2010-05-07 Pinaki Chaudhuri , Ludovic Berthier , Pablo I. Hurtado , Walter Kob

We study the coupling between the structural dynamics and rheological response of charged colloidal monolayers at water/oil interfaces, driven into steady shear by a microdisk rotating at a controlled angular velocity. The flow causes…

Soft Condensed Matter · Physics 2015-09-14 Ivo Buttinoni , Zachary A. Zell , Todd M. Squires , Lucio Isa

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades…