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The extension of equilibrium thermodynamics to non-equilibrium systems is based on the assumption of "local equilibrium," followed by the assumption that an entropy-density function may be defined, and that this entropy-density would have…

Chemical Physics · Physics 2018-03-12 Arieh Ben-Naim

This is a study of composition rule and temperature definition for nonextensive systems containing different $q$ subsystems. The physical meaning of the multiplier $\beta$ associated with the energy expectation in the optimization of…

Statistical Mechanics · Physics 2016-08-16 Qiuping A. Wang , Laurent Nivanen , Alain Le Méhauté

Non-equilibrium and equilibrium thermodynamics of an interacting component in a special-relativistic multi-component system is discussed by use of an entropy identity. The special case of the corresponding free component is considered.…

General Relativity and Quantum Cosmology · Physics 2018-06-06 Wolfgang Muschik

Entropy might be a not well defined concept if the system can undergo transformations involving stationary nonequilibria. It might be analogous to the heat content (once called ``caloric'') in transformations that are not isochoric (i.e.…

Statistical Mechanics · Physics 2007-05-23 Giovanni Gallavotti

We study stochastic thermodynamics for a quantum system of interest whose dynamics are described by a completely positive trace-preserving (CPTP) map as a result of its interaction with a thermal bath. We define CPTP maps with equilibrium…

Quantum Physics · Physics 2017-11-15 Felipe Barra , Cristóbal Lledó

The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…

Statistical Mechanics · Physics 2015-12-03 Ian J. Ford

The nonextensive thermodynamic relations are expressed under the assumption of temperature duality, endowing the "physical temperature" and the "Lagrange temperature" in different physical sense. Based on this assumption, two sets of…

Statistical Mechanics · Physics 2016-10-18 Yahui Zheng , Jiulin Du

The Lesche stability condition for the Shannon entropy [B. Lesche, J. Stat. Phys. 27, 419 (1982)], represents a fundamental test, for its experimental robustness, for systems obeying the Maxwell-Boltzmann statistical mechanics. Of course,…

Statistical Mechanics · Physics 2009-11-10 G. Kaniadakis , A. M. Scarfone

Phenomenological nonequilibrium thermodynamics describes how fluxes of conserved quantities such as matter, energy and charge flow from outer reservoirs across a system, and how they irreversibly degrade from one form to another. Stochastic…

Statistical Mechanics · Physics 2016-11-15 Matteo Polettini , Gregory Bulnes Cuetara , Massimiliano Esposito

By assuming an appropriate energy composition law between two systems governed by the same non-extensive entropy, we revisit the definitions of temperature and pressure, arising from the zeroth principle of thermodynamics, in a manner…

Statistical Mechanics · Physics 2015-05-18 A. M. Scarfone

Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

The aim of the present paper is to present a careful and accessible discussion of the formal aspects of Boltzmann-Gibbs and Tsallis entropies. We begin with a brief overview of Boltzmann-Gibbs entropy, highlighting its main properties and…

Statistical Mechanics · Physics 2025-10-23 Kelvin dos Santos Alves , Rogerio Teixeira Cavalcanti

We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…

Statistical Mechanics · Physics 2007-11-07 Fariel Shafee

We discuss conditional Renyi and Tsallis entropies for bipartite quantum systems of finite dimension. We investigate the relation between the positivity of conditional entropies and entanglement properties. It is in particular shown that…

Quantum Physics · Physics 2009-11-07 Karl Gerd H. Vollbrecht , Michael M. Wolf

Quantum thermodynamics with open systems is often based on the quantum optical weak-coupling master equation or on operational repeated interaction models, whereas early works on thermalisation and on decoherence theory were mostly…

Quantum Physics · Physics 2025-06-27 Michael Gaida , Giulio Gasbarri , Stefan Nimmrichter

Recently, in their attempt to construct steady state thermodynamics (SST), Komatsu, Nakagwa, Sasa, and Tasaki found an extension of the Clausius relation to nonequilibrium steady states in classical stochastic processes. Here we derive a…

Statistical Mechanics · Physics 2015-05-28 Keiji Saito , Hal Tasaki

We consider a situation where an $N$-level system (NLS) is coupled successively to two heat baths with different temperatures without being necessarily thermalized and approaches a steady state. For this situation we apply a general…

Statistical Mechanics · Physics 2021-08-09 Heinz-Jürgen Schmidt , Jochen Gemmer

We investigate a kinetic model of a system in contact with several thermal reservoirs at different temperatures $T_\alpha$. Our system is a spatially uniform dilute gas whose internal dynamics is described by the nonlinear Boltzmann…

Mathematical Physics · Physics 2014-06-17 Eric A. Carlen , Joel L. Lebowitz , Clement Mouhot

Using the stochastic thermodynamics, we determine the entropy production and the dynamic heat capacity of systems subject to a sinusoidally time dependent temperature, in which case the systems are permanently out of thermodynamic…

Statistical Mechanics · Physics 2019-06-26 Carlos E. Fiore , Mário J. de Oliveira

An axiomatic foundation regarding the entropy for complex systems is established. Missing from decades of research was the requirement that entropy must measure the uncertainty at the informational scale of the maximizing distribution,…

Statistical Mechanics · Physics 2026-05-29 Kenric P. Nelson