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Very recently, the validity of the concept of negative temperature has been challenged by several authors since they consider Boltzmann's entropy (that allows negative temperatures) inconsistent from a mathematical and statistical point of…

Statistical Mechanics · Physics 2016-12-21 Pierfrancesco Buonsante , Roberto Franzosi , Augusto Smerzi

We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the…

Quantum Physics · Physics 2021-08-25 Heinz-Jürgen Schmidt , Jürgen Schnack , Jochen Gemmer

The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , S. Martinez , F. Pennini , A. Plastino

Some existing approaches to modeling the thermodynamics of moist air make approximations that break $\textit{thermodynamic consistency}$, such that the resulting thermodynamics do not obey the 1st and 2nd laws or have other inconsistencies.…

Atmospheric and Oceanic Physics · Physics 2022-09-05 Christopher Eldred , Mark Taylor , Oksana Guba

Do negative absolute temperatures matter physics and specifically Statistical Physics? We provide evidence that we can certainly answer positively to this vexata quaestio. The great majority of models investigated by statistical mechanics…

Statistical Mechanics · Physics 2021-07-07 Marco Baldovin , Stefano Iubini , Roberto Livi , Angelo Vulpiani

We use rigorous nonequilibrium thermodynamic arguments to establish that (i) the nonequilibrium entropy S(T_{0}) of any system is bounded below by the experimentally (calorimetrically) determined entropy S_{expt}(T_{0}), (ii)…

Chemical Physics · Physics 2013-04-23 P. D. Gujrati

The population dynamics and stability of ecosystems of interacting species is studied from the perspective of non-equilibrium thermodynamics by assuming that species, through their biotic and abiotic interactions, are units of entropy…

Biological Physics · Physics 2007-05-23 Karo Michaelian

Assuming time-scale separation, a simple and unified theory of thermodynamics and stochastic thermodynamics is constructed for small classical systems strongly interacting with its environment in a controllable fashion. The total…

Statistical Mechanics · Physics 2022-08-16 Mingnan Ding , Zhanchun Tu , Xiangjun Xing

The second law of thermodynamics in nonextensive statistical mechanics is discussed in the quantum regime. Making use of the convexity property of the generalized relative entropy associated with the Tsallis entropy indexed by q, Clausius'…

Statistical Mechanics · Physics 2009-11-10 Sumiyoshi Abe , A. K. Rajagopal

It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…

Statistical Mechanics · Physics 2015-05-14 J. M. Deutsch

A new approach to non-extensive thermodynamical systems with non-additive energy and entropy is proposed. The main idea of the paper is based on the statistical matching of the thermodynamical systems with the additive multi-step Markov…

Data Analysis, Statistics and Probability · Physics 2007-05-23 S. S. Apostolov , Z. A. Mayzelis , O. V. Usatenko , V. A. Yampol'skii

Mutual equilibrium in long-range interacting systems which involve nonadditive energy, is effectively described in terms of entropy with a nonadditive composition rule. As an example, long range Ising model is considered. The generality of…

Statistical Mechanics · Physics 2016-08-31 Ramandeep S. Johal

For transitive shifts of finite type, and more generally for shifts with specification, it is well-known that every equilibrium state for a Holder continuous potential has positive entropy as long as the shift has positive topological…

Dynamical Systems · Mathematics 2018-10-31 Vaughn Climenhaga , Van Cyr

This work deals with the physical system governed by a Hamiltonian operator, in two-dimensional space, of spinless charged particles subject to a perpendicular magnetic field B, coupled with a harmonic potential in the context of…

Statistical Mechanics · Physics 2025-04-30 Bienvenu Gnim Adewi , Isiaka Aremua , Laure Gouba

The generalized Gibbs free energy and enthalpy is derived in the framework of nonextensive thermodynamics by using the so-called physical temperature and the physical pressure. Some thermodynamical relations are studied by considering the…

Statistical Mechanics · Physics 2015-08-10 Lina Gu , Jiulin Du

Static spherically symmetric perfect-fluid solutions of Einstein's equations play a central role in relativistic astrophysics and stellar structure theory. While many exact solutions satisfy Einstein's equations mathematically, only a…

General Relativity and Quantum Cosmology · Physics 2026-05-22 Dina Demissenova , Nurzada Beissen , Kuantay Boshkayev , Hernando Quevedo

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

The present paper studies continuity of generalized entropy functions and relative entropies defined using the notion of a deformed logarithmic function. In particular, two distinct definitions of relative entropy are discussed. As an…

Mathematical Physics · Physics 2007-05-23 Jan Naudts

We define a thermostatic system to be a convex space of states together with a concave function sending each state to its entropy, which is an extended real number. This definition applies to classical thermodynamics, classical statistical…

Mathematical Physics · Physics 2023-02-13 John C. Baez , Owen Lynch , Joe Moeller

The linear stability of the homogeneous equilibrium of non-relativistic fluids with mass flux and special relativistic fluids with the absolute value of the energy vector as internal energy is investigated. It is proved that the equilibrium…

Nuclear Theory · Physics 2011-07-14 P. Ván