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Glass-forming liquids display strong fluctuations -- dynamical heterogeneities -- near their glass transition. By numerically simulating a binary Weeks-Chandler-Andersen liquid and varying both temperature and timescale, we investigate the…

Disordered Systems and Neural Networks · Physics 2011-08-15 Azita Parsaeian , Horacio E. Castillo

We numerically obtain the first quantitative demonstration that development of spatial correlations of mobility as temperature is lowered is responsible for the ``decoupling'' of transport properties of supercooled liquids. This result…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier

We present results from density functional theory and computer simulations that unambiguously predict the occurrence of first-order freezing transitions for a large class of ultrasoft model systems into cluster crystals. The clusters…

Soft Condensed Matter · Physics 2009-11-11 Bianca M. Mladek , Dieter Gottwald , Gerhard Kahl , Martin Neumann , Christos N. Likos

The motion of the structure determining components is highly collective, both in amorphous solids and in undercooled liquids. This has been deduced from experimental low temperature data in the tunneling regime as well as from the vanishing…

Disordered Systems and Neural Networks · Physics 2009-11-07 H. R. Schober

Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting…

Soft Condensed Matter · Physics 2010-09-15 Simon Lang , Vitalie Botan , Martin Oettel , David Hajnal , Thomas Franosch , Rolf Schilling

The application of amorphous chalcogenide alloys as data-storage media relies on their ability to undergo an extremely fast (10-100 ns) crystallisation once heated at sufficiently high temperature. However, the peculiar features that make…

Disordered Systems and Neural Networks · Physics 2015-06-05 Gabriele C. Sosso , Joerg Behler , Marco Bernasconi

Relations between the thermodynamics and dynamics of supercooled liquids approaching a glass transition have been proposed over many years. The potential energy surface of model liquids has been increasingly studied since it provides a…

We use molecular dynamics simulation to study the relationship between structure and dynamics in supercooled binary Lennard--Jones nanoparticles over a range of particle sizes. The glass transition temperature of the nanoparticles is found…

Soft Condensed Matter · Physics 2025-05-15 Weikai Qi , Shreya Tiwary , Richard K. Bowles

We intend to understand cosmological structure formation within the framework of superfluid models of dark matter with finite temperatures. Of particular interest is the evolution of small-scale structures where the pressure and superfluid…

Cosmology and Nongalactic Astrophysics · Physics 2020-10-28 S. T. H. Hartman , H. A. Winther , D. F. Mota

We image local structural rearrangements in soft colloidal glasses under small periodic perturbations induced by thermal cycling. Local structural entropy $S_{2}$ positively correlates with observed rearrangements in colloidal glasses. The…

Soft Condensed Matter · Physics 2016-06-13 Xiunan Yang , Rui Liu , Mingcheng Yang , Wei-Hua Wang , Ke Chen

For several atomistic models of glass formers, at conditions below their glassy dynamics onset temperatures, ${T_\mathrm{o}}$, we use importance sampling of trajectory space to study the structure, statistics and dynamics of excitations…

Statistical Mechanics · Physics 2014-05-08 Aaron S. Keys , Lester O. Hedges , Juan P. Garrahan , Sharon C. Glotzer , David Chandler

An overview of theoretical results and experimental data on the thermodynamics, structure and dynamics of the heterophase glass-forming liquids is presented. The theoretical approach is based on the mesoscopic heterophase fluctuations model…

Soft Condensed Matter · Physics 2015-01-13 A. S. Bakai

The glass transition remains one of the great unsolved mysteries of contemporary condensed matter physics. When crystallization is bypassed by rapid cooling, a supercooled liquid, retaining amorphous particle arrangment, results. The…

Materials Science · Physics 2016-10-12 Nicholas B. Weingartner , Zohar Nussinov

The nucleation and growth of clusters in a progressively cooled vapor is studied. The chemical-potential of the vapor increases, resulting in a rapidly increasing nucleation rate. The growth of the newly created clusters depletes monomers,…

Materials Science · Physics 2008-10-21 Yossi Farjoun

To understand the electronic shell- and supershell-structure in large metal clusters we have performed self-consistent calculations in the homogeneous, spherical jellium model for a variety of different materials. A scaling analysis of the…

Condensed Matter · Physics 2009-10-28 Erik Koch

The relationship between spatially heterogeneous dynamics (SHD) and jamming is studied in a glass-forming binary Lennard-Jones system via molecular dynamics simulations. It has been suggested that the probability distribution of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Naida Lacevic , Sharon C. Glotzer

Particle systems interacting with a soft repulsion, at thermal equilibrium and under some circumstances, are known to form cluster crystals, i.e. periodic arrangements of particle aggregates. We study here how these states are modified by…

Statistical Mechanics · Physics 2018-11-28 Lorenzo Caprini , Emilio Hernandez-Garcia , Cristobal Lopez

The mode-coupling theory of the glass transition treats the dynamics of supercooled liquids in terms of two-point density correlation functions. Here we consider a generalized, hierarchical formulation of schematic mode-coupling equations…

Statistical Mechanics · Physics 2014-11-27 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

We show that the various crossovers between dynamical regimes observed in experiments and simulations of supercooled liquids can be explained in simple terms from the existence and statistical properties of dynamical heterogeneities. We…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier , Juan P. Garrahan

By employing a simplified nonlinear memory function proposed recently by the present author, a universal equation for a collective-intermediate scattering function derived based on the time-convolutionless mode-coupling theory is…

Statistical Mechanics · Physics 2020-05-20 Michio Tokuyama