Related papers: Solid-solid volume collapse transitions are zeroth…
We present a non-linear elastic model of a coherent transition with discontinuous volume change in an isotropic solid. The model reproduces the anomalous thermodynamics typical of coherent equilibrium including intrinsic hysteresis (for a…
Solid-solid collapse transition in open framework structures is ubiquitous in nature. The real difficulty in understanding detailed microscopic aspects of such transitions in molecular systems arises from the interplay between different…
A class of isotropic and scale invariant strain energy functions is given for which the corresponding spherically symmetric elastic motion includes bodies whose diameter becomes infinite with time or collapses to zero in finite time,…
It is difficult to derive the solid--fluid transition from microscopic models. We introduce particle systems whose potentials do not decay with distance and calculate their partition function exactly using a method similar to that for…
While classical theory of phase transitions deals with systems where shape variation is energetically neutral, the account of rigidity can lead to the emergence of new thermodynamic features. One of them is a special type of critical points…
The pressure-temperature phase diagram of a one-component system, with particles interacting through a spherically symmetric pair potential in two dimensions is studied. The interaction consists of a hard core plus an additional repulsion…
It is known by now that amorphous solids at zero temperature do not possess a nonlinear elasticity theory: besides the shear modulus which exists, all the higher order coefficients do not exist in the thermodynamic limit. Here we show that…
We present a pedagogical review of the swelling thermodynamics and phase transitions of polymer gels. In particular, we discuss how features of the volume phase transition of the gel's osmotic equilibrium is analogous to other transitions…
The nature of the globule-coil transition of surface-confined polymers has been an issue of debate. Here this 2D collapse transition is studied through a partially directed lattice model. In the general case of polymers with positive…
We analyze thermodynamic models for fluid systems in equilibrium based on a virial expansion of the internal energy in terms of the volume density. We prove that the models, formulated for finite-size systems with $N$ particles, are exactly…
We study a lattice-gas model of penetrable particles on a square-lattice substrate with same-site and nearest-neighbor interactions. Penetrability implies that the number of particles occupying a single lattice site is unlimited and the…
In this paper we present a new thermodynamically consistent phase transition model describing the evolution of a liquid substance, e.g., water, in a rigid container $\Omega$ when we freeze the container. Since the density $\varrho_{2}$ of…
We study zero-range processes which are known to exhibit a condensation transition, where above a critical density a non-zero fraction of all particles accumulates on a single lattice site. This phenomenon has been a subject of recent…
The evolution of the aging process of glassy materials quenched from temperatures above their glass transition temperature $T_g$, when plotting the relaxed enthalpy versus the decrease in volume, leads to a slope comparable to the…
We study the non-equilibrium dynamics of the zero temperature Mott insulator- superfluid quantum phase transition in a lattice of weakly coupled Bose-Einstein condensates. We show that crossing the critical point from the insulating to the…
Lamellar or smectic phases often have an intricate intralamellar structure that remains scarcely understood from a microscopic viewpoint. In this work, we use molecular dynamics simulations to study the effect of volume exclusion and…
This study introduces a modeling approach aimed at elucidating the pivotal role of symmetry in phase transitions, focusing specifically on the isotropic-nematic (I-N) transition characteristic of liquid crystal systems. By leveraging…
The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…
The present work is an endeavour to determine analytically features of the stationary measure of a non-integrable zero-range process, and to investigate the possible existence of phase transitions for such a nonequilibrium model. The rates…
Phase transition in spherically symmetric collapse of a massless scalar field is studied in 4-d Einstein gravity. A class of exact solutions that show the evolution of a constant incoming energy flux turned on at a point in the past null…