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A diffusion-like theory for real time end-to-end distance of a long polymer chain in dilute solution is formulated. We give a detailed analytical expression for the end-to-end distance auto-correlation function of a long chain polymer in…

Soft Condensed Matter · Physics 2018-02-28 Moumita Ganguly , Aniruddha Chakraborty

Semiflexible macromolecules in dilute solution under very good solvent conditions are modeled by self-avoiding walks on the simple cubic lattice ($d=3$ dimensions) and square lattice ($d=2$ dimensions), varying chain stiffness by an energy…

Soft Condensed Matter · Physics 2015-05-30 Hsiao-Ping Hsu , Kurt Binder

Although the stretching of polymers and biomolecules is important in numerous settings, their response when confined to two-dimensions is relatively poorly-studied. In this paper, we derive closed-form analytical expressions for the…

Soft Condensed Matter · Physics 2013-05-28 Sara Iliafar , Dmitri Vezenov , Anand Jagota

We calculate the mean end-to-end distance ($R$) of a self-avoiding polymer encapsulated in an infinitely long cylinder with radius $D$. A self-consistent perturbation theory is used to calculate $R$ as a function of $D$ for impenetrable…

Soft Condensed Matter · Physics 2016-08-31 G. Morrison , D. Thirumalai

In this brief report, we revisit analytical calculation [Mishra, {\it et al.}, Physica A {\bf 323} (2003) 453 and Mishra, NewYork Sci. J. {\bf{3(1)}} (2010) 32.] of the persistent length of a semiflexible homopolymer chain in %the extremely…

Statistical Mechanics · Physics 2013-06-27 Pramod Kumar Mishra

We present a study of the bend angle distribution of semiflexible polymers of short and intermediate lengths within the wormlike chain model. This enables us to calculate the elastic response of a stiff molecule to a bending moment. Our…

Soft Condensed Matter · Physics 2015-06-12 Anirban Polley , Joseph Samuel , Supurna Sinha

The Fourier-Bessel expansion of a function on a circular disc yields a simple series representation for the end-to-end probability distribution function w(R,phi) encountered in a planar persistent random walk, where the direction taken in a…

Soft Condensed Matter · Physics 2015-06-24 Christian Bracher

The freely rotating chain is one of the classic discrete models of a polymer in dilute solution. It consists of a broken line of N straight segments of fixed length such that the angle between adjacent segments is constant and the N-1…

Probability · Mathematics 2017-11-15 Philip Kilanowski , Peter March , Marko Samara

An analytic expression is derived for the distribution $G(\vec{R})$ of the end-to-end distance $\vec{R}$ of semiflexible polymers in external potentials to elucidate the effect of confinement on the mechanical and statistical properties of…

Soft Condensed Matter · Physics 2015-06-25 Patrick Levi , Klaus Mecke

When the local intrinsic stiffness of a polymer chain varies over a wide range, one can observe both a crossover from rigid-rod-like behavior to (almost) Gaussian random coils and a further crossover towards self-avoiding walks in good…

Soft Condensed Matter · Physics 2015-03-17 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

We study the distribution function of the three dimensional wormlike chain with a fixed orientation of one chain end using the exact representation of the distribution function in terms of the Green's function of the quantum rigid rotator…

Soft Condensed Matter · Physics 2009-11-11 F. F. Semeriyanov , S. Stepanow

In this paper, we present a new approach to the Kratky-Porod Model (KP) of semiflexible polymers. Our solution to the model is based on the definition of a generating function which we use to study the statistical mechanics of semiflexible…

Statistical Mechanics · Physics 2007-05-23 Marcelo Marucho , Leonardo Loureiro , Gustavo A. Carri

Bending of worm-like polymers carries an energy penalty which results in the appearance of a persistence length l such that the polymer is straight on length scales smaller than l and bends only on length scales larger than this length.…

Soft Condensed Matter · Physics 2008-01-22 S. M. Rappaport , S. Medalion , Y. Rabin

Polymer models describing the statistics of biomolecules under confinement have applications to a wide range of single molecule experimental techniques and give insight into biologically relevant processes {\em{in vivo}}. In this paper, we…

Biological Physics · Physics 2023-09-18 Joel Gard , Greg Morrison

We study theoretically the entropic elasticity of a semi-flexible polymer, such as DNA, confined to two dimensions. Using the worm-like-chain model we obtain an exact analytical expression for the partition function of the polymer pulled at…

Soft Condensed Matter · Physics 2009-11-11 Ashok Prasad , Yuko Hori , Jane' Kondev

We describe a simple meanfield variational approach to study a number of properties of intrinsically stiff chains which are appropriate models for a large class of biopolymers. We present the calculation of the distribution of end-to-end…

Soft Condensed Matter · Physics 2008-02-03 D. Thirumalai , B. -Y. Ha

We perform simulations for long hard-sphere polymer chains using a recently developed binary-tree based Monte Carlo method. Systems in two to five dimensions with free and periodic boundary conditions and up to $10^7$ repeat units are…

Soft Condensed Matter · Physics 2023-12-01 Stefan Schnabel , Wolfhard Janke

Single-chain elasticity of polyethylene at $\theta$ point up to 90% of stretching with respect to its contour length is computed by Monte-Carlo simulation of an atomistic model in continuous space. The elasticity law together with the…

Soft Condensed Matter · Physics 2009-11-07 John T. Titantah , Carlo Pierleoni , Jean-Paul Ryckaert

We introduce a new correlated percolation model on the $d$-dimensional lattice $\mathbb{Z}^d$ called the random length worms model. Assume given a probability distribution on the set of positive integers (the length distribution) and $v \in…

Probability · Mathematics 2022-06-30 Balázs Ráth , Sándor Rokob

Motivated by renewed interest in the physics of branched polymers, we present here a complete characterization of the connectivity and spatial properties of $2$ and $3$-dimensional single-chain conformations of randomly branching polymers…

Soft Condensed Matter · Physics 2020-03-23 Irene Adroher-Benítez , Angelo Rosa