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We generalize the inverse patchy colloid model that was originally developed for heterogeneously charged particles with two identical polar patches and an oppositely charged equator to a model that can have a considerably richer surface…

Soft Condensed Matter · Physics 2015-10-28 Monika Stipsitz , Gerhard Kahl , Emanuela Bianchi

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

We apply general variational techniques to the problem of the counterion distribution around highly charged objects where strong condensation of counterions takes place. Within a field-theoretic formulation using a fluctuating electrostatic…

Soft Condensed Matter · Physics 2009-11-07 Roland R. Netz , Henri Orland

The method of screening and renormalization is used to include the Coulomb interaction between the charged particles in the momentum-space description of three- and four-body nuclear reactions. The necessity for the renormalization of the…

Nuclear Theory · Physics 2015-05-18 A. Deltuva

An approach is proposed which allows to self-consistently calculate the structural and thermodynamic properties of highly charged aqueous colloidal suspensions. The method is based on the renormalized Jellium model with the background…

Soft Condensed Matter · Physics 2009-10-27 Thiago E. Colla , Yan Levin , E. Trizac

By using the Debye screened potential a generalized version of Newton's Shell Theorem is developed and analytical equations are derived to calculate i) the potential of a charged sphere surrounded by electrolyte, ii) the potential of two…

Soft Condensed Matter · Physics 2020-02-11 István P. Sugár

We derive a Debye-H\"uckel-like model of the electric ion-ion interaction for non-constant dielectric susceptibility, which does not depend on any kind of charging process due to its foundation in the general framework of non-equilibrium…

Chemical Physics · Physics 2025-02-24 Wolfgang Dreyer , Rüdiger Müller

In this thesis, the electrostatic interaction between two chemically identical colloids, both carrying constant surface potential is studied in the limit of short inter-particle separation at the interface of two immiscible fluids. Using an…

Soft Condensed Matter · Physics 2020-01-01 Rick Bebon

Inhomogeneous charge distributions have important repercussions on electrostatic interactions in systems of charged particles but are often difficult to examine theoretically. We investigate how electrostatic interactions are influenced by…

Soft Condensed Matter · Physics 2013-02-25 Anze Losdorfer Bozic , Rudolf Podgornik

The Debye-H\"uckel equation is a fundamental physical model in chemical thermodynamics that describes the free energy (chemical potential, activity) of an ion in electrolyte solutions at variable salt concentration, temperature, and…

Chemical Physics · Physics 2018-11-14 Chin-Lung Li , Jinn-Liang Liu

In charge-stabilized colloidal suspensions, highly charged macroions, dressed by strongly correlated counterions, carry an effective charge that can be substantially reduced (renormalized) from the bare charge. Interactions between dressed…

Soft Condensed Matter · Physics 2011-06-28 Ben Lu , Alan R. Denton

We develop a thermodynamic description of particles held at a fixed surface potential. This system is of particular interest in view of the continuing controversy over the possibility of a fluid-fluid phase separation in aqueous colloidal…

Soft Condensed Matter · Physics 2009-11-10 Yan Levin , Emmanuel Trizac , Lyderic Bocquet

We study charge regulation of colloidal particles inside aqueous electrolyte solutions. To stabilize colloidal suspension against precipitation, colloidal particles are synthesized with either acidic or basic groups on their surface. In…

Soft Condensed Matter · Physics 2020-09-16 Amin Bakhshandeh , Derek Frydel , Yan Levin

Debye-Huckel (DH) theory is extended to treat two-component size- and charge-asymmetric primitive models, focussing primarily on the 1:1 additive hard-sphere electrolyte with, say, negative ion diameters, a--, larger than the positive ion…

Statistical Mechanics · Physics 2009-11-07 Daniel M. Zuckerman , Michael E. Fisher , Stefan Bekiranov

The pair correlation function of charge stabilized colloidal particles under strongly sheared conditions is studied using the analytical intermediate asymptotics method recently developed in [L. Banetta and A. Zaccone, Phys. Rev. E 99,…

Soft Condensed Matter · Physics 2021-02-04 Luca Banetta , Alessio Zaccone

Suspensions of hard colloidal particles frequently serve as model systems in studies on fundamental aspects of phase transitions. But often colloidal particles that are considered as ``hard'' are in fact weakly charged. If the colloids are…

Soft Condensed Matter · Physics 2014-03-24 Sven Dorosz , Nikhilesh Shegokar , Tanja Schilling , Martin Oettel

We investigate the electrostatic contribution to the persistence length of a semiflexible polymer chain whose segments interact via a screened Debye-H\" uckel dipolar interaction potential. We derive the expressions for the renormalized…

Soft Condensed Matter · Physics 2009-11-10 R. Podgornik

We theoretically study the polarizability and the interactions of neutral complexes consisting of a semi-flexible polyelectrolyte adsorbed onto an oppositely charged spherical colloid. In the systems we studied, the bending energy of the…

Soft Condensed Matter · Physics 2009-11-07 J. Dzubiella , A. G. Moreira , P. A. Pincus

The present review summarizes and assesses recent theoretical and experimental advances, with special emphasis on the effective interaction between charge-stabilized colloids, in the bulk or in confined geometries, and on the ambiguities of…

Soft Condensed Matter · Physics 2015-06-24 J. -P. Hansen , H. Lowen

The analytical solution of the recently proposed ideal chain polymer mean-spherical approximation (Yu.Kalyuzhnyi, Mol.Phys., 94, 735(1998)) is presented for the multicomponent mixture of charged hard-sphere linear chain flexible molecules.…

Condensed Matter · Physics 2009-11-07 Yu. V. Kalyuzhnyi , P. T. Cummings