Related papers: The Slowly Formed Guiselin Brush
Generalized-ensemble simulations enable the study of complex adsorption scenarios of a coarse-grained model polymer near an attractive nanostring, representing an ultrathin nanowire. We perform canonical and microcanonical statistical…
When a solid plate is withdrawn from a partially wetting liquid, a liquid layer dewets the moving substrate. High-speed imaging reveals alternating thin and thick regions in the entrained layer in the transverse direction at steady state.…
When a hydrophilic and deformable porous material is immersed in a bath, it may absorb the solvent and expand by several times its volume, thus forming a highly soft and porous hydrogel. A stress applied on the soft hydrogel surface deforms…
Hypothesis: Slippery Omniphobic Covalently Attached Liquids (SOCAL) have been proposed for making omnirepellent thin films of self-assembled dimethylsiloxane polymer brushes grafted from silica surfaces. Smooth and flat at very small scale,…
We provide an analytical description of the line broadening of HI absorbers in the Lyman-alpha forest resulting from Doppler broadening and Jeans smoothing. We demonstrate that our relation captures the dependence of the line-width on…
The structure of flexible polymers endgrafted in cylindrical pores of diameter D is studied as a function of chain length N and grafting density \sigma, assuming good solvent conditions. A phenomenological scaling theory, describing the…
We show the impact that scalar structures deformation and mixing has on the fate of plumes of waterborne contaminant transported through a chemically heterogeneous, partially adsorbing porous medium. Via pore-scale simulations, we follow…
We report on an experimental study of adsorption isotherme of nitrogen onto porous silicon with non interconnected pores open at one or at both ends in order to check for the first time the old (1938) but always current idea based on…
Standard models of sequential adsorption are implicitly formulated in a {\em scale invariant} form, by assuming adsorption on an infinite surface, with no characteristic length scales. In real situations, however, involving complex…
Combining direct computations with invariance arguments, Taylor's constitutive equation for an emulsion can be extrapolated to high shear rates. We show that the resulting expression is consistent with the rigorous limits of small drop…
Dewetting of ultra-thin polymer films near the glass transition exhibits unexpected front morphologies [G. Reiter, Phys. Rev. Lett., 87, 186101 (2001)]. We present here the first theoretical attempt to understand these features, focusing on…
We consider a class of models for nonlinearly elastic surfaces in this work. We have in mind thin, highly deformable structures modeled directly as two-dimensional nonlinearly elastic continua, accounting for finite membrane and bending…
This paper is concerned with the inhomogeneous incompressible Euler system. We establish a Duchon--Robert type approximation theorem for the distribution describing the local energy flux of bounded solutions. The velocity field is assumed…
A phase diagram for a surface-interacting long flexible polymer chain in a two-dimensional poor solvent where the possibility of collapse exists is determined using exact enumeration method. A model of a self-attracting self avoiding walk…
We studied polyelectrolyte adsorption on a repulsive charged surface by scaling analysis. At low ionic strength and low surface charge density in which a single polyelectrolyte is able to be adsorbed onto the surface, different regimes in…
We are concerned with a model describing the motion of two compressible, immiscible fluids with density-dependent viscosity in the whole $\mathbb R^3$. The phases of the flow may have different pressure and viscosity laws and are separated…
Consider a sequence of Gibbsian line ensembles, whose lowest labeled curves (i.e., the edge) have tight one-point marginals. Then, given certain technical assumptions on the nature of the Gibbs property and underlying random walk measure,…
Polymer gels behave as soft viscoelastic solids and exhibit a generic nonlinear mechanical response characterized by pronounced stiffening prior to irreversible failure, most often through macroscopic fractures. Here, we aim at capturing…
We investigate the effect of polydispersity on the properties of curved linear brushes in good solvent and for molten brushes. To this end, we extend the strong stretching theory for polydisperse brushes to curved geometries and investigate…
The numerical analysis of elastic wave propagation in unbounded media may be difficult due to spurious waves reflected at the model artificial boundaries. This point is critical for the analysis of wave propagation in heterogeneous or…