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Molecular excited vibrational states are metastable states and we incorporate their finite lifetimes into the theory of vibrational energy transfer between weakly interacting molecules, i.e., at internuclear distances at which they do not…

Chemical Physics · Physics 2019-07-24 Lorenz S. Cederbaum

Vibronic coupling effects usually manifest themselves in molecules and crystals rather than in an unbound atoms. We theoretically demonstrate the existence of vibronic states in a moving two-level atom exposed to a strong electromagnetic…

Quantum Physics · Physics 2020-10-28 Andrei Ivanov , Evgeniy Perlin

The conductance through a molecular device including electron-electron and electron-phonon interactions is calculated using the Numerical Renormalization Group method. At low temperatures and weak electron-phonon coupling the properties of…

Strongly Correlated Electrons · Physics 2007-05-23 P. S. Cornaglia , H. Ness , D. R. Grempel

We study the electronic transport through a spin-1 molecule in which mechanical stretching produces a magnetic anisotropy. In this type of device, a vibron mode along the stretching axis will couple naturally to the molecular spin. We…

Strongly Correlated Electrons · Physics 2012-07-31 David A. Ruiz-Tijerina , Pablo S. Cornaglia , C. A. Balseiro , Sergio E. Ulloa

The effect of electron-phonon coupling on the current noise in a molecular junction is investigated within a simple model. The model comprises a 1-level bridge representing a molecular level that connects between two free electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan , Mark A. Ratner

Coherent electronic transport in single-molecule junctions is investigated in the Coulomb blockade regime. Both the transmission phase and probability are calculated for junctions with various contact symmetries. A dramatic suppression of…

Mesoscale and Nanoscale Physics · Physics 2010-11-15 J. P. Bergfield , Ph. Jacquod , C. A. Stafford

Several experiments have demonstrated the existence of an electro-mechanical effect in many biological tissues and hydrogels, and its actual influence on growth, migration, and pattern formation. Here, to model these interactions and…

Soft Condensed Matter · Physics 2020-07-07 Yangkun Du , Yipin Su , Chaofeng Lu , Weiqiu Chen , Michel Destrade

We investigate electronic transport through two types of conjugated molecules. Mechanically controlled break-junctions are used to couple thiol endgroups of single molecules to two gold electrodes. Current-voltage characteristics (IVs) of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Reichert , R. Ochs , D. Beckmann , H. B. Weber , M. Mayor , H. v. Loehneysen

We investigate chemical bond formation and conductance in a molecular C60-junction under finite bias voltage using first-principles calculations based on density functional theory and nonequilibrium Green's functions (DFT-NEGF). At the…

Mesoscale and Nanoscale Physics · Physics 2013-02-04 Søren Ulstrup , Thomas Frederiksen , Mads Brandbyge

We investigate the steady-state electronic transport through a suspended dimer molecule coupled to leads. When strongly coupled to a vibrational mode, the electron transport is enhanced at the phonon resonant frequency and higher-order…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 D. H. Santamore , Neill Lambert , Franco Nori

We present a qualitative model for a fundamental process in molecular electronics: the change in conductance upon bond breaking. In our model a diatomic molecule is attached to spin-polarized contacts. Employing a Hubbard Hamiltonian,…

Materials Science · Physics 2008-06-24 Ali Goker , Francois Goyer , Matthias Ernzerhof

Partially magnetized plasmas in ExB configurations - where the electric and magnetic fields are mutually perpendicular - exhibit a cross-field transport behavior, which is widely believed to be dominantly governed by complex…

Plasma Physics · Physics 2025-04-04 Maryam Reza , Farbod Faraji , Aaron Knoll , Benedict Rose

Within the frame of quantum dissipation theory, we develop a new hierarchical equations of motion theory, combined with the small polaron transformation. We fully investigate the electron transport of a single attractive impurity system…

Mesoscale and Nanoscale Physics · Physics 2013-06-04 Feng Jiang , Shikuan Wang , Hang Xie , Yonghong Yan , YiJing Yan

A crucial factor determining charge transport in organic semiconductors is the electronic coupling between the molecular constituents, which is heavily influenced by the relative arrangement of the molecules. This renders quinacridone, with…

Materials Science · Physics 2019-10-16 Christian Winkler , Andreas Jeindl , Florian Mayer , Oliver T. Hofmann , Ralf Tonner , Egbert Zojer

Characterization of the structural and electron transport properties of single chiral molecules provides critical insights into the interplay between their electronic structure and electrochemical environments, providing broader…

Chemical Physics · Physics 2024-09-26 Yueqing Shi , Liya Bi , Zihao Wang , Kangkai Liang , Ji-Kun Li , Xiao-Ye Wang , Wan-Lu Li , Shaowei Li

This article investigates entanglement of the motional states of massive coupled oscillators. The specific realization of an idealized diatomic molecule in one-dimension is considered, but the techniques developed apply to any massive…

Quantum Physics · Physics 2015-03-13 N. L. Harshman , W. F. Flynn

We present a simple model of electrical transport through a metal-molecule-metal nanojunction that includes charging effects as well as aspects of the electronic structure of the molecule. The interplay of a large charging energy and an…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Matthias H. Hettler , Herbert Schoeller , Wolfgang Wenzel

In atoms spin-orbit coupling (SOC) cannot raise the angular momentum above a maximum value or lower it below a minimum. Here we show that this need not be the case in materials built from nanoscale structures including multi-nuclear…

Strongly Correlated Electrons · Physics 2017-03-15 A. L. Khosla , A. C. Jacko , J. Merino , B. J. Powell

Transport properties of asymmetric molecular structure are studied within the kinetic equation approach, taking into consideration the electron interaction in the self-consistent manner (SCF procedure). The device is made of a molecule…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Kamil Walczak

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…