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Collective diffusion coefficient in a two-dimensional lattice gas on a nonhomogeneous substrate is investigated using variational approach. Particles reside at adsorption sites with different well depths potentials and jump randomly between…

Statistical Mechanics · Physics 2009-11-13 F Krzyzewski , Magdalena A. Zaluska-Kotur

A quantitative relationship between the diffusion coefficient $D$ of a tagged particle in a liquid and the entropy $S$ of that liquid has long been sought, as it would allow entropy to be inferred directly from diffusion measurements and…

Statistical Mechanics · Physics 2025-09-25 Nayana Venkatareddy , Mohd Moid , Prabal K. Maiti , Biman Bagchi

The shear viscosities, long-time self-diffusion coefficients, and sedimentation velocities in monodisperse and bidisperse hard-sphere colloidal suspensions are simulated for volume fractions up to 0.40 using multiparticle collision dynamics…

Soft Condensed Matter · Physics 2026-03-02 Michael P. Howard

The particle diffusion in a fluid is a classical topic that dates back to more than one century ago. However, a full solution to this issue still lacks. In this work the velocity autocorrelation function and the diffusion constant are…

Fluid Dynamics · Physics 2016-08-03 Hanqing Zhao , Hong Zhao

Theoretical calculations for colloidal charge-stabilized and hard sphere suspensions show that hydrodynamic interactions yield a qualitatively different particle concentration dependence of the short-time self-diffusion coefficient. The…

Soft Condensed Matter · Physics 2009-10-31 E. Overbeck , Ch. Sinn , M. Watzlawek

The collective dynamics in liquid water is an active research topic experimentally, theoretically and via simulations. Here, ab initio molecular dynamics simulations are reported in heavy and ordinary water at temperature 323.15 K, or…

Soft Condensed Matter · Physics 2016-03-24 T. Bryk , A. P. Seitsonen

The role of particle shape in evaporation-induced auto-stratification in dispersed colloidal suspensions is explored with molecular dynamics simulations of mixtures of solid spheres, aspherical particles, and hollow spheres. A unified…

Soft Condensed Matter · Physics 2025-02-25 Binghan Liu , Gary S. Grest , Shengfeng Cheng

Active fluids comprise a variety of systems composed of elements immersed in a fluid environment which can convert some form of energy into directed motion; as such they are intrinsically out-of-equilibrium in the absence of any external…

Soft Condensed Matter · Physics 2019-06-26 Andrea Scagliarini , Ignacio Pagonabarraga

The diffusivity of tagged particles is demonstrated to be heterogeneous on time scales comparable to or less than the structural relaxation time %taking place at the interparticle distance in a highly supercooled liquid via 3D molecular…

Soft Condensed Matter · Physics 2009-10-31 Ryoichi Yamamoto , Akira Onuki

Under partial confinement, the motion of colloidal particles is restricted to a plane but their dynamics is influenced by hydrodynamic interactions mediated by the unconfined, three--dimensional flow of the embedding fluid. We demonstrate…

Soft Condensed Matter · Physics 2013-05-17 J. Bleibel , A. Dominguez , F. Günther , J. Harting , M. Oettel

We consider the hydrodynamic effect of small particles on the dynamics of a much larger particle moving normal to a planar wall in a highly bidisperse dilute colloidal suspension of spheres. The gap $h_0$ between the large particle and the…

Soft Condensed Matter · Physics 2009-11-13 S. Bhattacharya , J. Blawzdziewicz

We present results on tagged particle diffusion in a meso-scale lattice model for sheared amorphous material in athermal quasi-static conditions. We find a short time diffusive regime and a long time diffusive regime whose diffusion…

Soft Condensed Matter · Physics 2018-10-10 Botond Tyukodi , Craig E Maloney , Damien Vandembroucq

When an ensemble of particles interact hydrodynamically, they generically display large-scale transient structures such as swirls in sedimenting particles [1], or colloidal strings in sheared suspensions [2]. Understanding these…

Soft Condensed Matter · Physics 2013-01-24 Nicolas Desreumaux , Jean-Baptiste Caussin , Raphael Jeanneret , Eric Lauga , Denis Bartolo

Molecular dynamics (MD) simulations are used to determine the diffusion coefficients, electrophoretic mobilities and electrical conductivity of a charged colloidal suspension in the salt-free regime as a function of the colloid charge. The…

Soft Condensed Matter · Physics 2010-12-16 Sorin Bastea

We investigate the behavior of a one-dimensional diatomic fluid under a shock wave excitation. We find that the properties of the resulting shock wave are in striking contrast with those predicted by hydrodynamic and kinetic approaches,…

Statistical Mechanics · Physics 2009-11-11 Pablo I. Hurtado

It is intuitive that the diffusivity of an isolated particle differs from those in a monodisperse suspension, in which hydrodynamic interactions between the particles are operative. Batchelor (1976,1983) calculated how hydrodynamic…

Fluid Dynamics · Physics 2019-07-12 Navaneeth K. Marath , John S. Wettlaufer

The self-diffusion constant D is expressed in terms of transitions among the local minima of the potential (inherent structure, IS) and their correlations. The formulae are evaluated and tested against simulation in the supercooled,…

Statistical Mechanics · Physics 2009-10-31 T. Keyes , J. Chowdhary

A theory is presented for lambda_C, the coefficient of the first-order correction in the density of the collective diffusion coefficient, for protein spheres interacting by electrostatic and adhesive forces. An extensive numerical analysis…

Soft Condensed Matter · Physics 2009-11-13 Peter Prinsen , Theo Odijk

Tracking of individual particle and studying their motion serves as a direct means to understand the dynamics in crowded and complex environments. In this study, the dynamics of tracer particles in the matrix of dense soft-colloidal…

Soft Condensed Matter · Physics 2023-06-28 Jimpaul Samukcham , Lenin S. Shagolsem

We have developed a microfluidic tool to measure the diffusion coefficient $D$ of solutes in an aqueous solution, by following the temporal relaxation of an initially steep concentration gradient in a microchannel. Our chip exploits…

Soft Condensed Matter · Physics 2022-08-23 Hoang-Thanh Nguyen , Anne Bouchaudy , Jean-Baptiste Salmon