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In this paper, we investigated the electronic structure of some endohedral fullerenes containing rare earth nitride and the stability of their benzyne-adducts by PM7, the semiempirical Hatree-Fock method.

Chemical Physics · Physics 2014-05-01 Kye-Ryong Sin , Sun-Gyong Ko , Kwang-Yong Ri , Song-Jin Im

The thermodynamic stability of structural isomers of $\mathrm{C}_{24}$, $\mathrm{C}_{26}$, $\mathrm{C}_{28}$ and $\mathrm{C}_{32}$, including fullerenes, is studied using density functional and quantum Monte Carlo methods. The energetic…

Atomic and Molecular Clusters · Physics 2009-10-31 P. R. C. Kent , M. D. Towler , R. J. Needs , G. Rajagopal

The stability of Ne@C$_{60}$ and He@C$_{60}$ is discussed in the context of a spherical model where the carbon atoms are smeared out into a uniform shell. The electronic properties of the sixty $\pi$ electrons together with those of the…

chem-ph · Physics 2008-02-03 Dennis P. Clougherty

We report a computational study of the stability and infrared (IR) vibrational spectra of neutral and singly ionised fullerene cages containing between 44 and 70 carbon atoms. The stability is characterised in terms of the standard enthalpy…

Astrophysics of Galaxies · Physics 2019-02-20 Alessandra Candian , Marina Gomes Rachid , Heather MacIsaac , Viktor N. Staroverov , Els Peeters , Jan Cami

In this study, based on density functional theory (DFT), we propose a new branch of pseudo-fullerenes which contain triple bonds with sp hybridization. We should call these new nanostructures fullerynes, according to IUPAC. We present four…

Materials Science · Physics 2020-03-24 Mohammad Qasemnazhand , Farhad Khoeini , Farah Marsusi

A family of unusually stable boron cages was identified and examined using first-principles local density functional method. The structure of the fullerenes is similar to that of the B12 icosahedron and consists of six crossing…

Materials Science · Physics 2021-09-21 Nevill Gonzalez Szwacki

Based on the third allotropic form of carbon (Fullerenes) through theoretical study have been predicted structures described as non-classical fullerenes. We have studied novel allotropic carbon structures with a closed cage configuration…

Materials Science · Physics 2017-05-24 Christian A. Celaya , Jesús Muñiz , Luis Enrique Sansores

A comprehensive study on the relative structural stability of various nanostructures of carbon clusters (including fullerenes, cages, onions, icosahedral clusters, bucky-diamond clusters, spherically bulk terminated clusters, and clusters…

Materials Science · Physics 2008-07-22 Ming Yu , Indira Chaudhuri , C. Leahy , C. S. Jayanthi , S. Y. Wu

Recently, Lagos et al. (Nature Nanotechnology 4, 149 (2009)) reported the discovery of the smallest possible silver square cross-section nanotube. A natural question is whether similar carbon nanotubes can exist. In this work we report ab…

Chemical Physics · Physics 2010-10-06 P A S Autreto , S B Legoas , M Z S Flores , D S Galvao

Two-dimensional alloys of carbon and nitrogen represent an urgent interest due to prospective applications in nanomechanical and optoelectronic devices. Stability of these chemical structures must be understood as a function of their…

Materials Science · Physics 2015-02-09 Vitaly V. Chaban , Oleg V. Prezhdo

This is a brief review of recent theoretical efforts to understand persistence in nonequilibrium systems. Some of the recent experimental results are also briefly mentioned. I also discuss recent generalizations of persistence in various…

Statistical Mechanics · Physics 2007-05-23 Satya N. Majumdar

In this paper we give a comprehensive account of several recent results on the stability of nontrivial soliton structures for some well-known non periodic dispersive models. We will focus on the simpler case of the generalized Korteweg-de…

Analysis of PDEs · Mathematics 2015-10-13 Claudio Muñoz

The formation of ZnO nanorings and nanohelices with large polar surfaces observed in experiments [Nano Lett. 3, 1625 (2003); J. Am. Chem. Soc. 126, 6703 (2004)] is shown to be a result of the competition between elastic energy, spontaneous…

Materials Science · Physics 2007-05-23 Z. C. Tu , Q. X. Li , X. Hu

A description of neutral and multiply charged fullerenes is proposed based on a stabilized jellium (structureless pseudopotential) approximation for the ionic background and the local density approximation for the sigma and pi valence…

Mesoscale and Nanoscale Physics · Physics 2019-11-11 Constantine Yannouleas , Uzi Landman

Endohedrally doped Si20 fullerenes appear as appealing building blocks for nanoscale materials. We investigate their structural stability with an unbiased and systematic global geometry optimization method within density-functional theory.…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Alex Willand , Matthias Gramzow , S. Alireza Ghasemi , Luigi Genovese , Thierry Deutsch , Karsten Reuter , Stefan Goedecker

Both even- and odd-numbered neutral carbon clusters Cn (n = 2-10) are systematically studied using the energy minimization method and the modified Brenner potential for the carbon-carbon interactions. Many stable configurations were found…

Materials Science · Physics 2009-11-13 D. P. Kosimov , A. A. Dzhurakhalov , F. M. Peeters

Some mathematical errors of the paper commented upon [W.-M. Suen, Phys. Rev. D 40, (1989) 315] are corrected.

General Relativity and Quantum Cosmology · Physics 2009-11-07 H. -J. Schmidt

A configuration space approach is developed to uncover generic stability peculiarities for the lowest energy neutral and charged exciton complexes (biexciton and trion) in quasi-one-dimensional semiconductors. Trions are shown to be more…

Mesoscale and Nanoscale Physics · Physics 2015-12-07 I. V. Bondarev

We have made a systematic theoretical study to determine which are the most stable structures for substitutional nitrogen defects in carbon nanotubes, by making total energy calculations via DFT. These calculations were made for a (5,5) and…

Other Condensed Matter · Physics 2007-05-23 Mariana Rossi , Adalberto Fazzio , Antonio J. R. da Silva

We obtain new results on the stability of discrete dark solitons bifurcating from the anti-continuum limit of the discrete nonlinear Schrodinger equation, following the analysis of our previous paper [Physica D 212, 1-19 (2005)]. We derive…

Pattern Formation and Solitons · Physics 2008-02-13 D. E. Pelinovsky , P. G. Kevrekidis
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